JP2004529215A - 発泡性ポリマー組成物の発泡セル状粒子 - Google Patents
発泡性ポリマー組成物の発泡セル状粒子 Download PDFInfo
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- JP2004529215A JP2004529215A JP2002548013A JP2002548013A JP2004529215A JP 2004529215 A JP2004529215 A JP 2004529215A JP 2002548013 A JP2002548013 A JP 2002548013A JP 2002548013 A JP2002548013 A JP 2002548013A JP 2004529215 A JP2004529215 A JP 2004529215A
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- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- SPTHWAJJMLCAQF-UHFFFAOYSA-M ctk4f8481 Chemical compound [O-]O.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-M 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910001872 inorganic gas Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- DATIMHCCPUZBTD-UHFFFAOYSA-N pentane Chemical compound CCCCC.CCCCC DATIMHCCPUZBTD-UHFFFAOYSA-N 0.000 description 1
- 238000003359 percent control normalization Methods 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 150000004978 peroxycarbonates Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920013637 polyphenylene oxide polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- DLSMLZRPNPCXGY-UHFFFAOYSA-N tert-butylperoxy 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC(=O)OOOC(C)(C)C DLSMLZRPNPCXGY-UHFFFAOYSA-N 0.000 description 1
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/224—Surface treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/08—Copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25114000P | 2000-12-04 | 2000-12-04 | |
| US25420500P | 2000-12-08 | 2000-12-08 | |
| PCT/US2001/048289 WO2002046284A1 (en) | 2000-12-04 | 2001-11-30 | Foamed cellular particles of an expandable polymer composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004529215A true JP2004529215A (ja) | 2004-09-24 |
| JP2004529215A5 JP2004529215A5 (enExample) | 2005-12-22 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002548013A Pending JP2004529215A (ja) | 2000-12-04 | 2001-11-30 | 発泡性ポリマー組成物の発泡セル状粒子 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20020117769A1 (enExample) |
| EP (1) | EP1352022A4 (enExample) |
| JP (1) | JP2004529215A (enExample) |
| KR (1) | KR20030059827A (enExample) |
| CN (1) | CN1237099C (enExample) |
| AU (1) | AU2002230822A1 (enExample) |
| BR (1) | BR0115923A (enExample) |
| CA (1) | CA2430615A1 (enExample) |
| HU (1) | HUP0303866A3 (enExample) |
| MX (1) | MXPA03004908A (enExample) |
| NO (1) | NO20032500L (enExample) |
| PL (1) | PL363223A1 (enExample) |
| WO (1) | WO2002046284A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015048356A (ja) * | 2013-08-29 | 2015-03-16 | 積水化成品工業株式会社 | 発泡性スチレン系樹脂粒子、発泡粒子、発泡成形体及び発泡粒子の製造方法 |
| JP2017043011A (ja) * | 2015-08-27 | 2017-03-02 | 積水化成品工業株式会社 | 繊維強化複合発泡体の製造方法及びその方法に使用しうる熱可塑性樹脂発泡粒子 |
| JP2024516426A (ja) * | 2021-04-30 | 2024-04-15 | フォックス ヴェルション ゲーエムベーハー | 発泡プラスチック粒子の製造方法 |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10101432A1 (de) * | 2001-01-13 | 2002-07-18 | Basf Ag | Kohlenstoffpartikel enthaltende expandierbare Styrolpolymerisate |
| DE10219228A1 (de) | 2002-04-30 | 2003-11-13 | Symrise Gmbh & Co Kg | Aromapartikel |
| EP1654304A4 (en) * | 2003-08-15 | 2011-11-30 | Nova Chem Int Sa | METHOD FOR PRODUCING EXPANDABLE POLYMER PARTICLES AND FOAM BODIES THEREOF |
| FR2858977A1 (fr) | 2003-08-21 | 2005-02-25 | Bp Chem Int Ltd | Composition de polystyrene expansible, procede de fabrication d'objets en polystyrene expanse de moyenne densite, et perles pre-expansees en polystyrene de moyenne densite |
| BRPI0417963A (pt) * | 2003-12-22 | 2007-03-27 | Nova Chem Inc | recipiente termoplástico moldado, método para formar um recipiente para reter substáncias lìquidas e alimentìcias, artigo de fabricação, e, método para armazenar substáncias lìquidas e alimentìcias |
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| US8752348B2 (en) | 2005-02-25 | 2014-06-17 | Syntheon Inc. | Composite pre-formed construction articles |
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| DE102005015891A1 (de) * | 2005-04-06 | 2006-10-12 | Basf Ag | Verfahren zur Herstellung von Polystyrolschaumpartikeln hoher Dichte |
| FR2885131B1 (fr) * | 2005-04-27 | 2008-03-07 | Arkema Sa | Structure cellulaire a base de polymere comprenant des nanotubes de carbone, son procede de preparation et ses applications |
| KR20070060454A (ko) * | 2005-12-08 | 2007-06-13 | 주식회사 레오 케미칼 | 발포폴리스티렌 코팅제의 제조방법 |
| CN101341024A (zh) * | 2005-12-22 | 2009-01-07 | 诺瓦化学公司 | 改进抗可发性聚合物农产品容器内熏蒸剂吸着的方法和相关容器 |
| CA2631717A1 (en) * | 2005-12-22 | 2007-07-12 | Nova Chemicals Inc. | Methods for improving resitance to fumigant sorption in a produce container |
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| WO2026151745A2 (en) | 2025-01-08 | 2026-07-16 | Henry Company, Llc | Lightweight drainage footing forms |
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Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US585410A (en) * | 1897-06-29 | Dish-tray | ||
| US2656334A (en) * | 1948-09-28 | 1953-10-20 | Koppers Co Inc | Catalytic polymerization process |
| US2848427A (en) * | 1953-06-01 | 1958-08-19 | Dow Chemical Co | Method of making celluloar plastic articles from vinyl aromatic resins |
| US3121132A (en) * | 1961-12-18 | 1964-02-11 | Koppers Co Inc | Stress relieving expandable plastic particles |
| US3243485A (en) * | 1963-07-09 | 1966-03-29 | Dow Chemical Co | Fabrication of foamed plastic articles |
| US3397258A (en) * | 1965-12-15 | 1968-08-13 | Sinclair Koppers Co | Process for extruding spherical expandable particles |
| US3673126A (en) * | 1967-11-13 | 1972-06-27 | Dow Chemical Co | Continuous process for making expandable thermoplastic resin compositions |
| US3817965A (en) * | 1968-02-27 | 1974-06-18 | Aquitaine Petrole | Polymerization of vinyl compounds in suspension |
| US3543485A (en) * | 1968-09-23 | 1970-12-01 | Universal Oil Prod Co | Centrifugal particle separator |
| US3607999A (en) * | 1969-06-19 | 1971-09-21 | Dow Chemical Co | Foam scrap recovery and apparatus |
| US3856904A (en) * | 1971-07-13 | 1974-12-24 | Dow Chemical Co | Process for making expanded synthetic resinous beads |
| US4344710A (en) * | 1980-06-10 | 1982-08-17 | Mobil Oil Corporation | Polymer foam extrusion system |
| IT1163386B (it) * | 1983-05-19 | 1987-04-08 | Montedison Spa | Procedimento per la produzione di granuli espandibili di polimeri termoplastici e relativa apparecchiatura |
| DE3620683C1 (de) * | 1986-06-20 | 1987-07-02 | Basf Ag | Treibmittelhaltige Styrolpolymerisate |
| JPS6377947A (ja) * | 1986-09-19 | 1988-04-08 | Mitsubishi Yuka Badische Co Ltd | スチレン・アクリロニトリル・ブタジエン系共重合体の発泡粒子の製造方法 |
| US5026736A (en) * | 1987-02-24 | 1991-06-25 | Astro-Valcour, Inc. | Moldable shrunken thermoplastic polymer foam beads |
| WO1990002151A1 (en) * | 1988-08-22 | 1990-03-08 | The Dow Chemical Company | Improved expandable and expanded alkenyl aromatic polymer particles and methods of making the same |
| US4911869A (en) * | 1988-10-11 | 1990-03-27 | Arco Chemical Technology, Inc. | Reimpregnation of plastic foam particles with CO2 |
| US5049328A (en) * | 1990-07-02 | 1991-09-17 | Arco Chemical Technology, Inc. | Purification, impregnation and foaming of polymer particles with carbon dioxide |
| KR930005841B1 (ko) * | 1990-10-27 | 1993-06-25 | 삼성전자 주식회사 | 마이크로_콤퓨터시스템의 키스캔회로 및 그 방법 |
| US5086078A (en) * | 1990-11-26 | 1992-02-04 | Basf Corporation | Process for making expanded polymeric product with low level of emission of blowing agent |
| US5115066A (en) * | 1990-11-26 | 1992-05-19 | Basf Corporation | Polystyrene having high degree of expandability, and formulation having a highly-expandable polymer therein |
| US5110524A (en) * | 1990-11-26 | 1992-05-05 | Basf Corporation | Process for making molded polymeric product with multipass expansion of polymer bead with low blowing agent content |
| US5112875A (en) * | 1990-11-26 | 1992-05-12 | Basf Corporation | Polystyrene having high degree of expandability, and formulation having a highly-expandable polymer therein |
| US5110836A (en) * | 1990-11-26 | 1992-05-05 | Basf Corporation | Time-efficient process for making expanded polymeric products with multipass expansion of polystyrene bead |
| US5110837A (en) * | 1990-11-26 | 1992-05-05 | Basf Corporation | Process for making molded polymeric product with multipass expansion of polymer bead with low blowing agent content |
| US5114640A (en) * | 1990-11-26 | 1992-05-19 | Basf Corporation | Time-efficient process for making expanded polymeric products with multipass expansion of polystyrene bead |
| US5267845A (en) * | 1992-05-13 | 1993-12-07 | Polysource, Inc. | Apparatus for manufacturing expandable polystyrene (EPS) pellets |
| US5240967A (en) * | 1993-02-17 | 1993-08-31 | Arco Chemical Technology, L.P. | Method for improving the expandability of styrenic polymer particles |
| DE4305697A1 (de) * | 1993-02-25 | 1994-09-01 | Basf Ag | Perlförmige, expandierbare Styrolpolymerisate mit verringertem Innenwassergehalt und Verfahren zu ihrer Herstellung |
| DE4308636A1 (de) * | 1993-03-18 | 1994-09-22 | Basf Ag | Verfahren zur Herstellung von perlförmigen expandierbaren Styrolpolymerisaten mit verbesserter Expandierbarkeit |
| DE19530765A1 (de) * | 1995-08-22 | 1997-02-27 | Basf Ag | Kontinuierliches Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| US6020388A (en) * | 1997-03-04 | 2000-02-01 | Tri-Technologies, Inc. | Methods for impregnating polymer beads |
| WO1999000236A1 (en) * | 1997-06-27 | 1999-01-07 | The Dow Chemical Company | Energy absorbing articles of extruded thermoplastic foams |
| US5977195A (en) * | 1997-08-01 | 1999-11-02 | Huntsman Corporation | Expandable thermoplastic polymer particles and method for making same |
| DE19749570A1 (de) * | 1997-11-10 | 1999-05-12 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| DE19819058C5 (de) * | 1998-04-29 | 2015-06-25 | Basf Se | Verfahren zur Herstellung von vorgeschäumten EPS-Partikeln mit grober Schaumstruktur aus teilchenförmigen, schwach angeschäumten, expandierten Styrolpolymerisaten |
| FR2780406B1 (fr) * | 1998-06-29 | 2000-08-25 | Bp Chem Int Ltd | Composition de polystyrene expansible, procede de preparation de la composition et materiaux expanses resultant de la composition |
| EP0987293A1 (en) * | 1998-09-16 | 2000-03-22 | Shell Internationale Researchmaatschappij B.V. | Porous polymer particles |
| ES2261142T3 (es) * | 2000-01-25 | 2006-11-16 | Basf Aktiengesellschaft | Procedimiento para la obtencion de polimeros de propileno en forma de particulas, expandibles. |
-
2001
- 2001-11-30 WO PCT/US2001/048289 patent/WO2002046284A1/en not_active Ceased
- 2001-11-30 KR KR10-2003-7007364A patent/KR20030059827A/ko not_active Ceased
- 2001-11-30 PL PL01363223A patent/PL363223A1/xx not_active Application Discontinuation
- 2001-11-30 HU HU0303866A patent/HUP0303866A3/hu unknown
- 2001-11-30 US US10/021,716 patent/US20020117769A1/en not_active Abandoned
- 2001-11-30 AU AU2002230822A patent/AU2002230822A1/en not_active Abandoned
- 2001-11-30 JP JP2002548013A patent/JP2004529215A/ja active Pending
- 2001-11-30 CA CA002430615A patent/CA2430615A1/en not_active Abandoned
- 2001-11-30 BR BR0115923-2A patent/BR0115923A/pt not_active IP Right Cessation
- 2001-11-30 CN CNB018199569A patent/CN1237099C/zh not_active Expired - Fee Related
- 2001-11-30 MX MXPA03004908A patent/MXPA03004908A/es unknown
- 2001-11-30 EP EP01991069A patent/EP1352022A4/en not_active Withdrawn
-
2003
- 2003-06-03 NO NO20032500A patent/NO20032500L/no not_active Application Discontinuation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015048356A (ja) * | 2013-08-29 | 2015-03-16 | 積水化成品工業株式会社 | 発泡性スチレン系樹脂粒子、発泡粒子、発泡成形体及び発泡粒子の製造方法 |
| JP2017043011A (ja) * | 2015-08-27 | 2017-03-02 | 積水化成品工業株式会社 | 繊維強化複合発泡体の製造方法及びその方法に使用しうる熱可塑性樹脂発泡粒子 |
| JP2024516426A (ja) * | 2021-04-30 | 2024-04-15 | フォックス ヴェルション ゲーエムベーハー | 発泡プラスチック粒子の製造方法 |
| JP7812577B2 (ja) | 2021-04-30 | 2026-02-10 | フォックス ヴェルション ゲーエムベーハー | 発泡プラスチック粒子の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2002230822A1 (en) | 2002-06-18 |
| EP1352022A4 (en) | 2004-03-24 |
| MXPA03004908A (es) | 2004-05-24 |
| NO20032500D0 (no) | 2003-06-03 |
| CN1478120A (zh) | 2004-02-25 |
| CA2430615A1 (en) | 2002-06-13 |
| EP1352022A1 (en) | 2003-10-15 |
| BR0115923A (pt) | 2004-01-20 |
| KR20030059827A (ko) | 2003-07-10 |
| HUP0303866A3 (en) | 2008-03-28 |
| HUP0303866A2 (hu) | 2004-03-01 |
| CN1237099C (zh) | 2006-01-18 |
| NO20032500L (no) | 2003-06-03 |
| US20020117769A1 (en) | 2002-08-29 |
| PL363223A1 (en) | 2004-11-15 |
| WO2002046284A1 (en) | 2002-06-13 |
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