JP2004339219A - 単環芳香族化合物の接触アルキル化法およびそこで使用するための組成物 - Google Patents

単環芳香族化合物の接触アルキル化法およびそこで使用するための組成物 Download PDF

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Publication number
JP2004339219A
JP2004339219A JP2004144689A JP2004144689A JP2004339219A JP 2004339219 A JP2004339219 A JP 2004339219A JP 2004144689 A JP2004144689 A JP 2004144689A JP 2004144689 A JP2004144689 A JP 2004144689A JP 2004339219 A JP2004339219 A JP 2004339219A
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Japan
Prior art keywords
mesoporous
monocyclic aromatic
catalyst
aromatic compound
zeo
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Pending
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JP2004144689A
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English (en)
Japanese (ja)
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JP2004339219A5 (enExample
Inventor
Iver Schmidt
イヴェル・シュミット
Claus Hviid Christensen
クラウス・ヴィド・クリステンセン
Christina Christensen
クリスチナ・クリステンセン
Kim Johannsen
キム・ヨハンセン
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Topsoe AS
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Haldor Topsoe AS
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Application filed by Haldor Topsoe AS filed Critical Haldor Topsoe AS
Publication of JP2004339219A publication Critical patent/JP2004339219A/ja
Publication of JP2004339219A5 publication Critical patent/JP2004339219A5/ja
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2004144689A 2003-05-17 2004-05-14 単環芳香族化合物の接触アルキル化法およびそこで使用するための組成物 Pending JP2004339219A (ja)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DKPA200300746 2003-05-17

Publications (2)

Publication Number Publication Date
JP2004339219A true JP2004339219A (ja) 2004-12-02
JP2004339219A5 JP2004339219A5 (enExample) 2007-05-17

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ID=33040863

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JP2004144689A Pending JP2004339219A (ja) 2003-05-17 2004-05-14 単環芳香族化合物の接触アルキル化法およびそこで使用するための組成物

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Country Link
US (1) US7285696B2 (enExample)
EP (1) EP1479663A1 (enExample)
JP (1) JP2004339219A (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015513459A (ja) * 2012-04-18 2015-05-14 ユーオーピー エルエルシー ゼオライト触媒を作製するための方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103121909B (zh) * 2011-11-18 2016-04-13 中国石油化工股份有限公司 乙醇与苯气相烷基化生产乙苯的方法
US11673845B2 (en) 2020-09-03 2023-06-13 Saudi Arabian Oil Company Aromatization of light hydrocarbons using metal-modified zeolite catalysts
US11465950B2 (en) * 2020-09-03 2022-10-11 Saudi Arabian Oil Company Aromatization of light hydrocarbons using metal-doped zeolite catalysts with enhanced mesoporosity
US11548842B1 (en) 2022-06-01 2023-01-10 Saudi Arabian Oil Company Conversion of light naphtha to enhanced value aromatics in an integrated reactor process

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6471827A (en) * 1987-09-02 1989-03-16 Mobil Oil Corp Alkylation of aromatics
JPH08103658A (ja) * 1994-06-16 1996-04-23 Enichem Sintesi Spa 芳香族化合物のアルキル化またはアルキル交換方法及びそれに用いる触媒組成物
JP2000309546A (ja) * 1999-04-28 2000-11-07 Mitsui Chemicals Inc 芳香族アルキル化物の製造方法およびその触媒
JP2001163699A (ja) * 1999-12-06 2001-06-19 Haldor Topsoe As ゼオライト単結晶の製造方法

Family Cites Families (12)

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US3751504A (en) 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US4016218A (en) 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
US4547605A (en) 1983-09-28 1985-10-15 Mobil Oil Corporation Catalyst for alkylation of aromatic hydrocarbons
IT1217525B (it) * 1988-05-06 1990-03-22 Enichem Sintesi Procedimento per la preparazione di cumene
US5118896A (en) * 1990-10-31 1992-06-02 Amoco Corporation Aromatic alkylation process using large macropore, small particle size, zeolite catalyst
US5118894A (en) 1991-07-18 1992-06-02 Mobil Oil Corporation Production of ethylbenzene
US5430211A (en) * 1993-10-29 1995-07-04 The Dow Chemical Company Process of preparing ethylbenzene or substituted derivatives thereof
WO1998003455A1 (en) 1996-07-19 1998-01-29 Asahi Kasei Kogyo Kabushiki Kaisha Process for preparing ethylbenzene
CA2262661C (en) 1996-08-20 2006-07-25 The Dow Chemical Company Process for the production of alkylated benzenes
CN1088050C (zh) 1996-09-06 2002-07-24 埃克森美孚化学专利公司 使用β－沸石的烷基化方法
DE19857314A1 (de) * 1997-12-12 2000-02-03 Sec Dep Of Science And Technol Stark saurer mensoporöser synergistischer Festkörper-Katalysator und Verwendung desselben
US6620402B2 (en) 1999-12-06 2003-09-16 Haldor Topsoe A.S Method of preparing zeolite single crystals with straight mesopores

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6471827A (en) * 1987-09-02 1989-03-16 Mobil Oil Corp Alkylation of aromatics
JPH08103658A (ja) * 1994-06-16 1996-04-23 Enichem Sintesi Spa 芳香族化合物のアルキル化またはアルキル交換方法及びそれに用いる触媒組成物
JP2000309546A (ja) * 1999-04-28 2000-11-07 Mitsui Chemicals Inc 芳香族アルキル化物の製造方法およびその触媒
JP2001163699A (ja) * 1999-12-06 2001-06-19 Haldor Topsoe As ゼオライト単結晶の製造方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015513459A (ja) * 2012-04-18 2015-05-14 ユーオーピー エルエルシー ゼオライト触媒を作製するための方法

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US7285696B2 (en) 2007-10-23
US20040254410A1 (en) 2004-12-16

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