JP2004095959A - Nitride semiconductor light emitting element - Google Patents

Nitride semiconductor light emitting element Download PDF

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Publication number
JP2004095959A
JP2004095959A JP2002256884A JP2002256884A JP2004095959A JP 2004095959 A JP2004095959 A JP 2004095959A JP 2002256884 A JP2002256884 A JP 2002256884A JP 2002256884 A JP2002256884 A JP 2002256884A JP 2004095959 A JP2004095959 A JP 2004095959A
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nitride semiconductor
light emitting
semiconductor layer
layer
type
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JP2004095959A5 (en
JP4211329B2 (en
Inventor
Takahiko Sakamoto
坂本 貴彦
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Nichia Chemical Industries Ltd
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Nichia Chemical Industries Ltd
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Priority to JP2002256884A priority Critical patent/JP4211329B2/en
Application filed by Nichia Chemical Industries Ltd filed Critical Nichia Chemical Industries Ltd
Priority to KR1020087019079A priority patent/KR101052139B1/en
Priority to KR1020057001748A priority patent/KR100891403B1/en
Priority to CN200710166947A priority patent/CN100595937C/en
Priority to EP03766716A priority patent/EP1553640A4/en
Priority to EP10184721.8A priority patent/EP2290715B1/en
Priority to KR1020087019080A priority patent/KR101095753B1/en
Priority to PCT/JP2003/009836 priority patent/WO2004013916A1/en
Priority to CNB2007101669499A priority patent/CN100552997C/en
Priority to CN200710166948A priority patent/CN100595938C/en
Priority to AU2003252359A priority patent/AU2003252359A1/en
Priority to CNB038185342A priority patent/CN100358163C/en
Priority to US10/522,887 priority patent/US7511311B2/en
Publication of JP2004095959A publication Critical patent/JP2004095959A/en
Publication of JP2004095959A5 publication Critical patent/JP2004095959A5/ja
Priority to US12/155,841 priority patent/US8035118B2/en
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Publication of JP4211329B2 publication Critical patent/JP4211329B2/en
Priority to US13/271,100 priority patent/US8330179B2/en
Priority to US13/711,444 priority patent/US8742438B2/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/01Chemical elements
    • H01L2924/01015Phosphorus [P]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/01Chemical elements
    • H01L2924/01045Rhodium [Rh]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/01Chemical elements
    • H01L2924/01074Tungsten [W]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/01Chemical elements
    • H01L2924/01078Platinum [Pt]

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a structure of a nitride semiconductor light emitting element that can prevent short-circuiting on the side. <P>SOLUTION: The nitride semiconductor light emitting element is provided with a light emitting layer made of nitride semiconductor between an n-type nitride semiconductor layer and a p-type nitride semiconductor layer. A trapezoidal conoidal laminated body is formed including the p-type nitride semiconductor layer and the light emitting layer, and the laminated body is buried in a metallic member so that its side is insulated. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は窒化物半導体発光素子に関する。
【0002】
【従来の技術】
近年、GaN系化合物半導体を用いて発光素子が、青色系の発光が可能の発光素子として広く用いられるようになって来ている。このGaN系化合物半導体発光素子は、絶縁基板であるサファイア基板の上にGaN系化合物半導体層を成長させて構成している関係上、同一面側にp型電極とn型電極とを形成する必要があった(例えば、特許文献1参照)。この同一面側にp型電極とn型電極とを形成した窒化物半導体発光素子は、n型電極を形成するためにp型半導体層と発光層の一部を除去する必要があるので、必然的に発光領域の面積が小さくなるという問題があった。
【0003】
そこで、最近では、サファイア基板の上に必要なGaN系化合物半導体層を成長させて、その上に反り防止層を形成した後、サファイア基板を研磨により除去する方法が提案されている(例えば、特許文献2参照)。この特許文献2に開示された方法によれば、両面に電極(一方の面にn型電極、他方の面にp型電極)が形成された窒化物半導体発光素子を作成することが可能である。
【0004】
【特許文献1】
特開平8−330629号公報(図1〜図3)
【特許文献2】
特開2001−313422号公報(第6頁右欄8行〜第7頁左欄42行、図8,図9)
【0005】
【発明が解決しようとする課題】
しかしながら、特許文献2に開示された方法は、個々の素子に分割した際に切断面(分割後の素子の側面)でp側の層とn側の層とが短絡しやすいという問題があった。
そこで、本発明は、側面における短絡を防止することができる窒化物半導体発光素子の構造及びその製造方法を提供することを目的とする。
【0006】
【課題を解決するための手段】
以上の目的を達成するために、本発明に係る第1の窒化物半導体発光素子は、n型窒化物半導体層とp型窒化物半導体層の間に、窒化物半導体からなる発光層を有してなる窒化物半導体発光素子において、
少なくとも上記p型窒化物半導体層と上記発光層を含むように台形錐形状の積層体が形成され、該積層体は側面が絶縁されるように金属部材に埋め込まれたことを特徴とする。
また、本発明に係る第2の窒化物半導体発光素子は、n型窒化物半導体層とp型窒化物半導体層の間に、窒化物半導体からなる発光層を有してなる窒化物半導体発光素子において、
少なくとも上記p型窒化物半導体層と上記発光層を含むように台形錐形状の積層体が形成されて、その積層体が該積層体の表面に沿って対向するように設けられた金属部材により保持されたことを特徴とする。
以上のように構成された窒化物半導体発光素子において、上記積層体は側面が絶縁されるように金属部材に埋め込まれていて、切断時又は切断後に積層体の側面が損傷を受けることがないので、信頼性を向上させることができる。
また、本発明に係る窒化物半導体発光素子は、両側に電極を形成することができるので、一方の面に正負の電極を設けた従来の窒化物半導体発光素子に比較して発光領域を大きくとることができる。
【0007】
本発明に係る第1と第2の窒化物半導体素子では、上記金属部材の上記積層体の反対側に位置する面が、平坦な面であることが好ましい。
このようにすると、素子を実装する際に、実装基板にその平坦な面を対向させて実装することにより容易に実装することが可能になる。
また、上記第1と第2の窒化物半導体素子では、上記n型窒化物半導体層の対向する2つの面のうちの上記積層体の反対側に位置する面に透明電極を形成するようにして、該透明電極を介して光を出射するようにしてもよい。
このようにすると発光層全体に均一に電流を注入することができ、均一な発光が可能になる。この場合、上記透明電極は透光性が高くかつ抵抗値を低くできるITOであることが好ましい。
【0008】
また、本発明の第1と第2の窒化物半導体発光素子において、上記p型窒化物半導体層とオーミック接触するように上記積層体と上記金属部材の間に形成されるp型電極は、Rhを含むことが好ましく、これにより電極の剥離を防止できる。
【0009】
さらに、本発明の第1と第2の窒化物半導体発光素子において、上記積層体は上記n型窒化物半導体層の一部を含んで構成されていてもよいし、上記n型窒化物半導体層の全てを含むように構成されていてもよい。
【0010】
また、本発明の第1と第2の窒化物半導体発光素子において、より確実に発光領域の形状を保持するために、上記金属部材の厚さは50μm以上であることが好ましい。
【0011】
また、本発明の第1と第2の窒化物半導体発光素子においては、上記積層体を複数個備えていてもよく、複数の積層体を用いて発光素子を構成することにより、大面積の発光素子を構成できる。
さらに、上記積層体を複数個備えた発光素子では、上記複数の積層体は、共通のn型窒化物半導体層の上に設けられていてもよいし、各積層体ごとに分離されていてもよい。
【0012】
また、本発明の第1と第2の窒化物半導体発光素子において、上記金属部材は、Ti、Ag、Al、Ni、Pt、Au、Rh、Cu、W等からなる群から選択された金属又はその金属を少なくとも含む合金からなることが好ましい。
【0013】
また、本発明に係る発光素子の製造方法は、基板上にn型半導体層と発光層とp型半導体層を形成する第1工程と、上記p型半導体層と上記発光層とを含むように台形錐形状の発光領域を形成する第2工程と、上記発光領域を覆うように金属部材を形成する第3工程と、上記基板を除去する第4工程と、上記発光領域の間で金属部材を切断することにより、発光素子ごとに分離する第5工程とを含むことを特徴とする。
【0014】
また、本発明に係る発光素子の製造方法では、上記第3工程において、上記金属部材をメッキにより形成することが好ましい。
【0015】
【発明の実施の形態】
以下、図面を参照しながら本発明に係る実施の形態について説明する。
実施の形態1.
本発明に係る実施の形態1の窒化物半導体発光素子は、図1に示すように、発光領域を構成する窒化物半導体層の一部が金属部材1に埋め込まれるように設けられ、その金属部材1によって、発光素子全体の形状が保持されている。
【0016】
本実施の形態1の窒化物半導体発光素子においては、n型窒化物半導体層11とp型窒化物半導体層13の間に発光層12を設けることによりダブルへテロ構造の発光領域が構成されており、そのp型窒化物半導体層と発光層とn型窒化物半導体層の一部は台形錐形状(裁頭錐体形状)に加工されている。すなわち、本発明は、少なくともp型窒化物半導体層と発光層が含まれるように台形錐形状の積層体が形成される。また、積層体2において、p型窒化物半導体層13上のほぼ全面にはp型オーミック電極22が形成され、p型オーミック電極22の周辺部と積層体2の傾斜した側面2a及びその側面2aに連続したn型窒化物半導体層11を覆うように絶縁層3が形成されている。
【0017】
そして、以上のように構成された積層体2が金属部材1に埋め込まれるようにして保持されている。尚、積層体2の側面は、絶縁層3を介して金属部材1に埋め込まれ、積層体2のp型オーミック電極22が形成された面はp型オーミック電極22を介して金属部材1に対向している。また、n型窒化物半導体層21の対向する2つの面のうちの積層体2の反対側に位置する面には透明電極21が形成され、その透明電極21の一部にはnパッド電極23が形成されている。
【0018】
以上のように構成された実施の形態1の窒化物半導体発光素子において、積層体2の発光層12で発光された光は、金属部材1の反対側から透明電極21を介して出射される。
【0019】
次に、本実施の形態1の窒化物半導体発光素子の製造方法について説明する。
本製造方法ではまず、図2に示すように、サファイア基板10の上に例えばバッファ層(図示せず)を介してn型窒化物半導体層11、発光層12及びp型窒化物半導体層13をその順番に成長させる。
次に、素子間において、n型窒化物半導体層が露出するまでエッチングすることにより、台形錐形状の積層体2を形成する(図3)。
この台形錐形状の積層体2は、例えば、マスクを所定の台形錐形状に形成しておいて、そのマスクを用いてエッチングすることによりそのマスクの形状に対応した台形錐形状に加工できる。
【0020】
具体的には、まず、図11(a)に示すように、p型窒化物半導体層13上に、断面が台形形状のマスクM1を形成する。このマスクM1は反応性イオンエッチングにより一定のレートでエッチング可能な材料を用いて形成する。
次に、反応性イオンエッチングにより、マスクM1の上からサファイア基板10上に形成された半導体層(p型窒化物半導体層13、発光層12及びn型窒化物半導体層11)エッチングする。このエッチング工程においては、半導体層とともにマスクM1そのものもエッチングにより少しづつ除去される。尚、図11(b)において、破線と実線の間のR1の符号を付した部分が除去された部分である。
このエッチングを積層部2の周りにn型窒化物半導体層11の表面が露出されるまで続ける(図11(c))。
このようにすると、マスクM1の形状に対応した台形錐形状の積層部2が形成される。
本方法では、マスク材料と窒化物半導体材料のRIEによるエッチング率を考慮して、マスクM1形状を設定することにより、所望の台形錐形状の積層部2を形成できる。
【0021】
上述の方法により積層体2を加工するエッチング手段としては、反応性イオンエッチングの他、反応性イオンビームエッチング、イオンミリング等のドライエッチングを用いることができる。
また、台形錐形状の積層部2の加工は、例えばウェットエッチングなどの等方性エッチング手段を用いて、アンダーカッティング(サイドエッチング)現象を利用するようにしてもよい。このアンダーカッティングを利用すると、台形錐形状の加工を簡単にできるが、加工精度は上述したドライエッチングを使用した方法に比較して劣る。
【0022】
また、積層体2の傾斜した側面2aの傾斜角(サファイア基板10の主面との為す角度)は、n型窒化物半導体層を介して出力される光の取り出し効率を高くするために、30度〜80度の範囲に設定されることが好ましくより好ましくは45度に設定する。
また、本発明において、裁頭錐体は、円錐台形錐体、角錐(四角錐、六角錐他)台形錐体等、種々の台形錐体が適用できる。
【0023】
以上のようにして、台形錐形状の積層部2を形成した後、積層部2の上底面(p型窒化物半導体層13の表面)のほぼ全面にp型オーミック電極22を形成する。
ここで、本明細書において、上底面とは、台形錐形状における互いに平行に対向する2つの面のうちの小さい方の面のことを言い、積層体2の底面という場合は、対向する2つの面のうちの大きい方の面のことを言う。
p型オーミック電極22は、Ni/Au、Ni/Pt、Pd/Ptからなる電極を用いることもできるが、本発明では、Rh/Au、Rh/Pt等のように、Rh層をp型窒化物半導体層13に接する層として形成した電極を用いることが好ましい。このように、Rhをp型窒化物半導体層13に接する第1層として形成すると、金属部材1を形成した後に、p型オーミック電極22がp型窒化物半導体層13から剥離するのを防止できる。
尚、(/)で表記した組み合わせは、(/)の前に記載した金属をp型窒化物半導体層13に接する第1層として形成し、その第1層の上に形成した第2層を(/)の後ろに記載した金属で形成したことを意味している。
【0024】
各積層体2のp型窒化物半導体層上にp型オーミック電極22を形成した後、図5に示すように、各p型オーミック電極22の中央部(周辺部を除いた部分をいう。)を除いて基板上全体を覆うように、絶縁膜3を形成する。
この絶縁膜3は、例えば、SiO、TiO、Al、Si、ZrO等の無機絶縁膜を用いて好適に形成することができるが、有機絶縁膜を用いて形成してもよい。
その後、必要に応じて複数の積層部2の間を接続する配線電極24を形成する(図6)。
次に、反射層24を形成する。この反射層24はAg、Pt、Rh、Al等の光反射性の高い材料を用いて形成される。尚、複数の積層部により1つの発光素子を構成する場合には、この反射層24が配線用の電極を兼ねるようにしても良い。特に、台形錐形状の積層体の側面が傾斜しており、これに対向するように反射層が設けられているので、光の利用効率が飛躍的に向上する。
尚、本発明では、絶縁膜3が反射層を兼ねるようにしてもよい。
反射層として用いることができる絶縁膜3の具体的な材料としては、SiO、TiO、Al、Ta、ZrO、Nb、Yが挙げられ、より好ましくは、これらの材料のなかから、2つの屈折率の異なる材料を組み合わせて交互に形成することにより多層構造の反射層を兼ねた絶縁膜3を形成する。例えば、TiO/SiO、を組み合わせて10〜20層積層することにより、多層構造の反射層を形成する。
【0025】
次に、例えば、メッキ等により金属部材1を全面に形成する(図7)。本発明において、この金属部材1は、後の工程でサファイア基板10を除去した後に発光素子の形状を保持することを第一義的な目的とするものであり、そのために厚く(好ましくは、50μm以上、より好ましくは、100〜200μmの範囲)形成する必要がある。
本発明において、金属部材1は、第1にこの目的を果たすことができればよく、そのためには、例えば、Ti、Ag、Al、Ni、Pt、Au、Rh、Cu、W等の種々の金属を用いることができる。
【0026】
また、本実施の形態1において、金属部材1は、反射膜24との密着性のよいことが要求される。また、反射膜24が形成されていない場合は、金属部材1は、絶縁膜3とp型オーミック電極22、とりわけ絶縁膜3との密着性が良いことが要求される。その場合、上述した材料により構成される絶縁膜3との密着性の良い材料として、Ti、W、Al、Niが挙げられる。
【0027】
また、金属部材1そのものを反射率の高い材料で形成することにより、反射層24を省略するようにしてもよい。そのような金属材料として、Ag、Al、Pt、Rhが挙げられる。
【0028】
また、本発明では、発光素子の形状を保持するという第一義的な機能のほか、光反射機能等を果たすために、金属部材1は、それぞれの機能を有する複数の層を積層した多層構造としてもよい。例えば、下地層として、発光した光に対する反射率が高くかつ絶縁膜3、p型オーミック電極22などとの密着性が良い第1金属膜を形成し、その上に厚く形成することが可能な第2金属膜を形成するようにして、金属部材1を構成することができる。
【0029】
また、本発明では、金属部材1は、比較的厚く形成する必要があるので、成膜速度の速い無電解メッキ、や電気メッキを用いて形成することが好ましい。
具体的には、Ni、Cu、Al、Au等の電気メッキ、Ni、Cu等の無電解メッキを用いることができる。
特に、無電解Niメッキは、Au、Cu、Agに比較して強度が高いためにウエハの反りを小さくできかつ電気接点が不用な点で好ましく、さらにNiはメッキ層の均一性、析出速度、ハンダ濡れ性、バンプ強度、耐食性の点においても優れた材料である。
【0030】
次に、図8に示すように、基板10の側からレーザを照射することによりサファイア基板10を除去する。この段階では、比較的厚い金属部材1が形成されているので、基板10を除去する方法としては、レーザ照射の他、研磨やエッチング等の種々の方法を用いることができる。
【0031】
そして、基板10が除去されて露出したn型窒化物半導体層11の表面に透明電極であるn型電極21を形成する(図9)。このn型電極21はW/Al、V/Al、W/Pt/Au、ZnO、ITO、Mo等により形成することができる。光の取り出し効率を高くするためには、ZnOやITOを用いることが好ましく、安価で入手しやすい材料であるという点で、ITOを用いることがさらに好ましい。
このITOを用いて透明電極21を形成する場合、抵抗値を下げるため、熱処理を施すことが好ましく、その好ましい熱処理温度は、100℃〜500℃であり、より好ましい熱処理温度は、200℃〜400℃である。
【0032】
次に、各積層体2に対応してそれぞれnパッド電極23を形成し、そのnパッド電極23の周辺部と透明電極21とを覆う絶縁膜4を形成する。
そして、ウエハを積層部の間で分割することにより個々の発光素子とする。
ここで、本発明では、個々の素子に分割する際の分割位置は、少なくとも積層体2の傾斜側面2aから離れた位置とし、その傾斜側面2aと分割後の素子の側面とが離れるようにする。
【0033】
以上のように構成された本発明に係る実施の形態1の窒化物半導体発光素子は、素子に分割する際の分割位置が積層体2の傾斜側面2aから離れているので、積層体2の傾斜側面2aのPN接合面が損傷を受けることがない。
また、素子に分割する際の分割位置が積層体2の傾斜側面2aから離れているので、金属部材1を切断する際の切断屑によるPN接合面の短絡を防止できる。
【0034】
また、本発明に係る実施の形態1の窒化物半導体発光素子では、積層体2の両側に電極を形成しているので、同一面側に電極を形成した素子のように一方の電極を形成するために発光層の一部を除去する必要はない。これにより、発光層の面積を小さくすることなく発光領域を確保できるので、発光効率を向上させることができる。
【0035】
また、本発明に係る実施の形態1の窒化物半導体発光素子では、積層体2の両側に電極を形成しているので、容易に発光層全体に電流を均一に流すことができ、発光層全体を均一にかつ効率よく発光させることができる。
特に、複数の積層部により1つの発光素子を構成するようにした場合には、比較的広い面積において、発光面内における均一性に優れた発光素子を提供できる。
【0036】
また、本実施の形態1の窒化物半導体発光素子においては、n型窒化物半導体層のほぼ全面に透明電極21を形成しているので、発光層全体に均一に電流を他注入することができ、発光層全体を均一に発光させることができる。
しかしながら、本発明はこれに限られるものではなく、透明電極21に代えてn型窒化物半導体層のほぼ全面に網目状(格子状)のn型電極を形成し、その格子の間から光を出力するようにしても良いし、n型窒化物半導体層の一部にn型電極を形成するようにしてもよい。
n型窒化物半導体はp型窒化物半導体に比較して抵抗値を小さくできることからn型窒化物半導体層内を電流が拡散しやすく、格子状のn型電極を用いた場合であっても、格子(電極が形成されていない部分の面積)を大きくでき、電極により光をあまり遮ることなく出射できる。また、n型窒化物半導体層の一部にn型電極を形成するようにした場合であっても、比較的広範囲の発光層に電流を注入することが可能である。
【0037】
変形例.
以上の実施の形態1では、n型窒化物半導体層11を厚さ方向に途中までエッチングすることにより、上記積層体を上記n型窒化物半導体層の少なくとも一部を含むように構成した。しかしながら、本発明はこれに限られるものではなく、図12に示すように、p型窒化物半導体層13と発光層12のみをエッチングするようにして積層部102aを形成するようにしても良いし、図13に示すように、p型窒化物半導体層13と発光層12をエッチングした後さらに連続してn型窒化物半導体層11をサファイア基板が露出するまでエッチングすることにより、p型窒化物半導体層13、発光層12及びn型窒化物半導体層11により積層部102bを形成するようにしてもよい。
【0038】
実施の形態2.
本発明に係る実施の形態2の窒化物半導体発光素子は、図14に示すように、1つ例に4つの積層体102aを配列した発光素子である。
すなわち、本実施の形態2の窒化物半導体発光素子は、図17に示すように、縦横4つずつ、合計16個の四角錐台形状の積層体102a(p型窒化物半導体層と発光層により構成)をn型窒化物半導体層11の一方の面に配列して比較的大面積の発光素子を構成している。
また、本実施の形態2の窒化物半導体発光素子において、n型窒化物半導体層11の他方の面の全面には、全ての積層体102aに共通の透明電極23がn型オーミック電極として形成され、その中央部に1つのnパッド電極23が形成されている。
また、本実施の形態2の窒化物半導体発光素子は、16個の積層体102aで1つの発光素子を構成するように、かつ分割位置が少なくとも積層体2の傾斜側面2aから離れた位置となるように積層部の間において分割されている。
【0039】
以上のように構成された実施の形態2の窒化物半導体発光素子は、素子に分割する際の分割位置が積層体2の傾斜側面2aから離れているので、積層体2の傾斜側面2aのPN接合面が損傷を受けることがなく、かつ金属部材1を切断する際の切断屑によるPN接合面の短絡も防止できる。
【0040】
また、本発明に係る実施の形態1の窒化物半導体発光素子では、実施の形態1の窒化物半導体発光素子と同様の理由で、発光効率を向上させることができ、発光層全体を均一にかつ効率よく発光させることができる。
【0041】
以上の実施の形態2の窒化物半導体発光素子では、n型窒化物半導体層11を含まずに、p型窒化物半導体層13と発光層12とが積層された積層体102aを用いて発光素子を構成した。しかしながら、本発明はこれに限られるものではなく、図15に示すように、n型窒化物半導体層11とp型窒化物半導体層13と発光層12とが積層された積層体102bを用いて構成してもよい。
【0042】
以上の実施の形態2の窒化物半導体発光素子では、1つの発光素子内では積層体ごとに分離することなく、発光素子間においてn型窒化物半導体層11が分離されるようにウエハ上に形成した後、n型窒化物半導体層11が分離された部分で素子ごとに分割するようにしてもよい(図16)。
【0043】
また、実施の形態2の窒化物半導体発光素子は、四角錐台形状の積層体102aを用いて構成したが、本発明はこれに限られるものではなく、円錐台形状の積層体102bを用いて構成するようにしてもよい(図18)。
【0044】
【発明の効果】
以上詳細に説明したように、本発明に係る窒化物半導体発光素子は、n型窒化物半導体層とp型窒化物半導体層の間に、窒化物半導体からなる発光層を有してなる窒化物半導体発光素子において、上記p型窒化物半導体層と上記発光層を含むように台形錐形状の積層体を形成し、該積層体を側面が絶縁されるように金属部材に埋め込んでいるので、切断時又は切断後に積層体の側面が損傷を受けることがない。したがって、本発明に係る窒化物半導体発光素子によれば、信頼性を向上させることができる。
【図面の簡単な説明】
【図1】本発明に係る実施の形態1の窒化物半導体発光素子の断面図である。
【図2】本発明に係る実施の形態1の窒化物半導体発光素子の製造方法において、サファイア基板上に半導体層を形成した後の断面図である。
【図3】実施の形態1の製造方法において、サファイア基板上に半導体層をエッチングして積層体を形成した後の断面図である。
【図4】実施の形態1の製造方法において、各積層体の上にp型電極を形成した後の断面図である。
【図5】実施の形態1の製造方法において、絶縁層3を形成した後の断面図である。
【図6】実施の形態1の製造方法において、反射層24を形成した後の断面図である。
【図7】実施の形態1の製造方法において、金属部材1を形成した後の断面図である。
【図8】実施の形態1の製造方法において、サファイア基板を剥離した後の断面図である。
【図9】実施の形態1の製造方法において、サファイア基板を剥離した後にn型窒化物半導体層の上に透明電極を形成した後の断面図である。
【図10】実施の形態1の製造方法において、透明電極を形成した後にnパッド電極と絶縁膜4を形成した後の断面図である。
【図11】実施の形態1の製造方法において、台形錐形状の積層体の形成方法を示す断面図である。
【図12】実施の形態1の変形例の窒化物半導体素子の断面図である。
【図13】実施の形態1の図12とは別の変形例の窒化物半導体素子の断面図である。
【図14】実施の形態2の窒化物半導体素子の断面図である。
【図15】実施の形態2の変形例1の窒化物半導体素子の断面図である。
【図16】実施の形態2の変形例2の窒化物半導体素子の断面図である。
【図17】実施の形態2の窒化物半導体素子の平面図である。
【図18】実施の形態2の変形例3の窒化物半導体素子の平面図である。
【符号の説明】
1…金属部材、
2…積層体、
2a…側面、
3…絶縁層、
10…サファイア基板、
11…n型窒化物半導体層、
12…発光層、
13…p型窒化物半導体層、
21…透明電極、
22…p型オーミック電極、
23…nパッド電極、
M1…マスク。
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a nitride semiconductor light emitting device.
[0002]
[Prior art]
In recent years, light-emitting elements using GaN-based compound semiconductors have been widely used as light-emitting elements that can emit blue light. In this GaN-based compound semiconductor light emitting device, a GaN-based compound semiconductor layer is grown on a sapphire substrate, which is an insulating substrate. Therefore, it is necessary to form a p-type electrode and an n-type electrode on the same surface side. (For example, see Patent Document 1). In the nitride semiconductor light emitting device in which the p-type electrode and the n-type electrode are formed on the same surface side, it is necessary to remove part of the p-type semiconductor layer and the light-emitting layer in order to form the n-type electrode. In particular, there is a problem that the area of the light emitting region is reduced.
[0003]
Therefore, recently, a method has been proposed in which a necessary GaN-based compound semiconductor layer is grown on a sapphire substrate, a warp prevention layer is formed thereon, and then the sapphire substrate is removed by polishing (for example, a patent) Reference 2). According to the method disclosed in Patent Document 2, it is possible to produce a nitride semiconductor light emitting device in which electrodes (an n-type electrode on one side and a p-type electrode on the other side) are formed on both sides. .
[0004]
[Patent Document 1]
JP-A-8-330629 (FIGS. 1 to 3)
[Patent Document 2]
JP 2001-313422 A (page 6, right column, line 8 to page 7, left column, line 42, FIGS. 8 and 9)
[0005]
[Problems to be solved by the invention]
However, the method disclosed in Patent Document 2 has a problem that the p-side layer and the n-side layer are easily short-circuited at the cut surface (side surface of the element after division) when divided into individual elements. .
Accordingly, an object of the present invention is to provide a structure of a nitride semiconductor light emitting device capable of preventing a short circuit on a side surface and a manufacturing method thereof.
[0006]
[Means for Solving the Problems]
In order to achieve the above object, a first nitride semiconductor light emitting device according to the present invention has a light emitting layer made of a nitride semiconductor between an n-type nitride semiconductor layer and a p-type nitride semiconductor layer. In the nitride semiconductor light emitting device obtained,
A trapezoidal cone-shaped stacked body is formed so as to include at least the p-type nitride semiconductor layer and the light emitting layer, and the stacked body is embedded in a metal member so that side surfaces are insulated.
The second nitride semiconductor light emitting device according to the present invention includes a light emitting layer made of a nitride semiconductor between an n-type nitride semiconductor layer and a p-type nitride semiconductor layer. In
A stack having a trapezoidal pyramid shape is formed so as to include at least the p-type nitride semiconductor layer and the light emitting layer, and the stack is held by a metal member provided so as to face along the surface of the stack. It is characterized by that.
In the nitride semiconductor light emitting device configured as described above, the stacked body is embedded in a metal member so that the side surface is insulated, and the side surface of the stacked body is not damaged during or after cutting. , Reliability can be improved.
In addition, since the nitride semiconductor light emitting device according to the present invention can be formed with electrodes on both sides, the light emitting region is larger than that of a conventional nitride semiconductor light emitting device in which positive and negative electrodes are provided on one surface. be able to.
[0007]
In the first and second nitride semiconductor elements according to the present invention, the surface of the metal member located on the opposite side of the stacked body is preferably a flat surface.
If it does in this way, when mounting an element, it will become possible to mount easily by mounting with the flat surface facing a mounting substrate.
In the first and second nitride semiconductor elements, a transparent electrode is formed on a surface of the two opposite surfaces of the n-type nitride semiconductor layer located on the opposite side of the stacked body. The light may be emitted through the transparent electrode.
In this way, current can be uniformly injected into the entire light emitting layer, and uniform light emission is possible. In this case, the transparent electrode is preferably made of ITO having high translucency and a low resistance value.
[0008]
In the first and second nitride semiconductor light emitting devices of the present invention, the p-type electrode formed between the stacked body and the metal member so as to be in ohmic contact with the p-type nitride semiconductor layer may be Rh. It is preferable to contain, and it can prevent peeling of an electrode by this.
[0009]
Furthermore, in the first and second nitride semiconductor light emitting devices of the present invention, the stacked body may include a part of the n-type nitride semiconductor layer, or the n-type nitride semiconductor layer. It may be configured to include all of the above.
[0010]
In the first and second nitride semiconductor light emitting devices of the present invention, the thickness of the metal member is preferably 50 μm or more in order to more reliably maintain the shape of the light emitting region.
[0011]
In the first and second nitride semiconductor light emitting devices of the present invention, a plurality of the stacked bodies may be provided, and a light emitting device is formed using the plurality of stacked bodies, thereby emitting a large area of light. An element can be configured.
Furthermore, in the light-emitting element including a plurality of the stacked bodies, the plurality of stacked bodies may be provided on a common n-type nitride semiconductor layer, or may be separated for each stacked body. Good.
[0012]
In the first and second nitride semiconductor light emitting devices of the present invention, the metal member may be a metal selected from the group consisting of Ti, Ag, Al, Ni, Pt, Au, Rh, Cu, W, or the like. It is preferably made of an alloy containing at least the metal.
[0013]
The method for manufacturing a light emitting device according to the present invention includes a first step of forming an n-type semiconductor layer, a light emitting layer, and a p type semiconductor layer on a substrate, and the p type semiconductor layer and the light emitting layer. A second step of forming a trapezoidal cone-shaped light emitting region; a third step of forming a metal member so as to cover the light emitting region; a fourth step of removing the substrate; and a metal member between the light emitting regions. And a fifth step of separating each light emitting element by cutting.
[0014]
In the method for manufacturing a light emitting element according to the present invention, it is preferable that the metal member is formed by plating in the third step.
[0015]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments according to the present invention will be described below with reference to the drawings.
Embodiment 1 FIG.
As shown in FIG. 1, the nitride semiconductor light emitting device according to the first embodiment of the present invention is provided so that a part of the nitride semiconductor layer constituting the light emitting region is embedded in the metal member 1, and the metal member. 1 holds the shape of the entire light emitting element.
[0016]
In the nitride semiconductor light emitting device of the first embodiment, the light emitting layer 12 is provided between the n-type nitride semiconductor layer 11 and the p-type nitride semiconductor layer 13 to form a light emitting region having a double hetero structure. A part of the p-type nitride semiconductor layer, the light emitting layer, and the n-type nitride semiconductor layer are processed into a trapezoidal cone shape (truncated cone shape). That is, in the present invention, the trapezoidal cone-shaped stacked body is formed so as to include at least the p-type nitride semiconductor layer and the light emitting layer. In the stacked body 2, a p-type ohmic electrode 22 is formed on almost the entire surface of the p-type nitride semiconductor layer 13, the peripheral portion of the p-type ohmic electrode 22, the inclined side surface 2 a of the stacked body 2, and the side surface 2 a thereof. An insulating layer 3 is formed to cover the continuous n-type nitride semiconductor layer 11.
[0017]
The laminate 2 configured as described above is held so as to be embedded in the metal member 1. The side surface of the laminate 2 is embedded in the metal member 1 through the insulating layer 3, and the surface of the laminate 2 on which the p-type ohmic electrode 22 is formed faces the metal member 1 through the p-type ohmic electrode 22. is doing. Further, a transparent electrode 21 is formed on a surface of the two opposite surfaces of the n-type nitride semiconductor layer 21 that is located on the opposite side of the stacked body 2, and an n-pad electrode 23 is formed on a part of the transparent electrode 21. Is formed.
[0018]
In the nitride semiconductor light emitting device of the first embodiment configured as described above, light emitted from the light emitting layer 12 of the multilayer body 2 is emitted from the opposite side of the metal member 1 through the transparent electrode 21.
[0019]
Next, a method for manufacturing the nitride semiconductor light emitting device of the first embodiment will be described.
In this manufacturing method, first, as shown in FIG. 2, an n-type nitride semiconductor layer 11, a light emitting layer 12, and a p-type nitride semiconductor layer 13 are formed on a sapphire substrate 10 via a buffer layer (not shown), for example. Grow in that order.
Next, a trapezoidal cone-shaped stacked body 2 is formed between the elements by etching until the n-type nitride semiconductor layer is exposed (FIG. 3).
The laminated body 2 having the trapezoidal cone shape can be processed into a trapezoidal cone shape corresponding to the shape of the mask by, for example, forming a mask in a predetermined trapezoidal cone shape and etching using the mask.
[0020]
Specifically, first, a mask M1 having a trapezoidal cross section is formed on the p-type nitride semiconductor layer 13 as shown in FIG. The mask M1 is formed using a material that can be etched at a constant rate by reactive ion etching.
Next, the semiconductor layers (p-type nitride semiconductor layer 13, light emitting layer 12, and n-type nitride semiconductor layer 11) formed on the sapphire substrate 10 are etched from above the mask M1 by reactive ion etching. In this etching step, the mask M1 itself together with the semiconductor layer is removed little by little by etching. In addition, in FIG.11 (b), it is the part from which the part which attached | subjected the code | symbol of R1 between a broken line and a continuous line was removed.
This etching is continued until the surface of the n-type nitride semiconductor layer 11 is exposed around the stacked portion 2 (FIG. 11C).
In this way, the trapezoidal cone-shaped laminated portion 2 corresponding to the shape of the mask M1 is formed.
In the present method, a desired trapezoidal cone-shaped stacked portion 2 can be formed by setting the shape of the mask M1 in consideration of the etching rate by RIE of the mask material and the nitride semiconductor material.
[0021]
As an etching means for processing the laminate 2 by the above-described method, dry etching such as reactive ion beam etching and ion milling can be used in addition to reactive ion etching.
Further, the processing of the trapezoidal cone-shaped laminated portion 2 may use an undercutting (side etching) phenomenon by using isotropic etching means such as wet etching. When this undercutting is used, the trapezoidal cone shape can be easily processed, but the processing accuracy is inferior to the method using dry etching described above.
[0022]
In addition, the inclination angle of the inclined side surface 2a of the stacked body 2 (angle formed with the main surface of the sapphire substrate 10) is 30 in order to increase the extraction efficiency of light output through the n-type nitride semiconductor layer. It is preferably set in the range of degrees to 80 degrees, more preferably set to 45 degrees.
In the present invention, as the truncated cone, various trapezoidal cones such as a truncated cone cone, a pyramid (square pyramid, hexagonal pyramid, etc.) trapezoidal cone, and the like can be applied.
[0023]
After forming the trapezoidal cone-shaped stacked portion 2 as described above, the p-type ohmic electrode 22 is formed on almost the entire upper surface of the stacked portion 2 (the surface of the p-type nitride semiconductor layer 13).
Here, in this specification, the upper bottom surface refers to the smaller one of the two surfaces facing each other in parallel with each other in the trapezoidal cone shape, and in the case of the bottom surface of the laminate 2, The larger of the faces.
As the p-type ohmic electrode 22, an electrode made of Ni / Au, Ni / Pt, or Pd / Pt can be used. However, in the present invention, the Rh layer is formed by p-type nitridation such as Rh / Au, Rh / Pt, etc. It is preferable to use an electrode formed as a layer in contact with the physical semiconductor layer 13. As described above, when Rh is formed as the first layer in contact with the p-type nitride semiconductor layer 13, it is possible to prevent the p-type ohmic electrode 22 from being separated from the p-type nitride semiconductor layer 13 after the metal member 1 is formed. .
The combination indicated by (/) is that the metal described before (/) is formed as the first layer in contact with the p-type nitride semiconductor layer 13, and the second layer formed on the first layer is formed. It means that it was made of the metal described after (/).
[0024]
After forming the p-type ohmic electrode 22 on the p-type nitride semiconductor layer of each stacked body 2, as shown in FIG. 5, the central portion of each p-type ohmic electrode 22 (refers to a portion excluding the peripheral portion). An insulating film 3 is formed so as to cover the entire surface of the substrate except for.
The insulating film 3 can be suitably formed using an inorganic insulating film such as SiO 2 , TiO 2 , Al 2 O 3 , Si 3 N 4 , ZrO 2, etc., but is formed using an organic insulating film. May be.
Thereafter, wiring electrodes 24 for connecting the plurality of stacked portions 2 are formed as necessary (FIG. 6).
Next, the reflective layer 24 is formed. The reflective layer 24 is formed using a highly light reflective material such as Ag, Pt, Rh, Al. In the case where one light emitting element is constituted by a plurality of stacked portions, the reflective layer 24 may also serve as an electrode for wiring. In particular, the side surface of the trapezoidal cone-shaped laminated body is inclined, and the reflective layer is provided so as to face this, so that the light use efficiency is dramatically improved.
In the present invention, the insulating film 3 may also serve as a reflective layer.
Specific examples of the insulating film 3 that can be used as the reflective layer include SiO 2 , TiO 2 , Al 2 O 3 , Ta 2 O 5 , ZrO 2 , Nb 2 O 5 , and Y 2 O 3 . More preferably, the insulating film 3 which also serves as a reflective layer having a multilayer structure is formed by alternately forming a combination of two materials having different refractive indexes from among these materials. For example, a reflective layer having a multilayer structure is formed by laminating 10 to 20 layers in combination of TiO 2 / SiO 2 .
[0025]
Next, for example, the metal member 1 is formed on the entire surface by plating or the like (FIG. 7). In the present invention, the metal member 1 is primarily intended to maintain the shape of the light emitting element after removing the sapphire substrate 10 in a later step, and is therefore thick (preferably 50 μm). As described above, it is more preferable to form the film in the range of 100 to 200 μm.
In the present invention, the metal member 1 only needs to fulfill this purpose first. For this purpose, for example, various metals such as Ti, Ag, Al, Ni, Pt, Au, Rh, Cu, and W are used. Can be used.
[0026]
In the first embodiment, the metal member 1 is required to have good adhesion with the reflective film 24. Further, when the reflective film 24 is not formed, the metal member 1 is required to have good adhesion between the insulating film 3 and the p-type ohmic electrode 22, particularly the insulating film 3. In that case, Ti, W, Al, and Ni are mentioned as materials having good adhesion to the insulating film 3 made of the above-described materials.
[0027]
Moreover, you may make it abbreviate | omit the reflection layer 24 by forming the metal member 1 itself with a material with a high reflectance. Examples of such a metal material include Ag, Al, Pt, and Rh.
[0028]
In the present invention, in addition to the primary function of maintaining the shape of the light emitting element, the metal member 1 has a multilayer structure in which a plurality of layers having respective functions are stacked in order to perform a light reflection function and the like. It is good. For example, a first metal film that has a high reflectivity with respect to emitted light and has good adhesion to the insulating film 3, the p-type ohmic electrode 22, and the like can be formed as a base layer and can be formed thick on the first metal film. The metal member 1 can be configured by forming two metal films.
[0029]
In the present invention, since the metal member 1 needs to be formed relatively thick, it is preferable to form the metal member 1 by using electroless plating or electroplating with a high film forming speed.
Specifically, electroplating such as Ni, Cu, Al and Au, and electroless plating such as Ni and Cu can be used.
In particular, the electroless Ni plating is preferable in that the strength of the electroless Ni plating is higher than that of Au, Cu, and Ag, so that the warpage of the wafer can be reduced and the electrical contact is unnecessary, and Ni is the uniformity of the plating layer, the deposition rate, It is an excellent material in terms of solder wettability, bump strength, and corrosion resistance.
[0030]
Next, as shown in FIG. 8, the sapphire substrate 10 is removed by irradiating a laser from the substrate 10 side. At this stage, since the relatively thick metal member 1 is formed, various methods such as polishing and etching can be used as a method for removing the substrate 10 in addition to laser irradiation.
[0031]
Then, an n-type electrode 21 which is a transparent electrode is formed on the surface of the n-type nitride semiconductor layer 11 exposed by removing the substrate 10 (FIG. 9). The n-type electrode 21 can be formed of W / Al, V / Al, W / Pt / Au, ZnO, ITO, Mo, or the like. In order to increase the light extraction efficiency, it is preferable to use ZnO or ITO, and it is more preferable to use ITO because it is an inexpensive and easily available material.
When the transparent electrode 21 is formed using this ITO, it is preferable to perform heat treatment in order to reduce the resistance value, and the preferable heat treatment temperature is 100 ° C to 500 ° C, and the more preferable heat treatment temperature is 200 ° C to 400 ° C. ° C.
[0032]
Next, the n pad electrode 23 is formed corresponding to each stacked body 2, and the insulating film 4 covering the peripheral portion of the n pad electrode 23 and the transparent electrode 21 is formed.
Then, the wafer is divided between the stacked portions to obtain individual light emitting elements.
Here, in the present invention, the division position when dividing into individual elements is at least a position away from the inclined side surface 2a of the multilayer body 2, and the inclined side surface 2a is separated from the side surface of the element after division. .
[0033]
In the nitride semiconductor light-emitting device according to the first embodiment of the present invention configured as described above, the division position when dividing the device is away from the inclined side surface 2a of the multilayer body 2, and thus the inclination of the multilayer body 2 The PN junction surface of the side surface 2a is not damaged.
Moreover, since the dividing position when dividing into elements is separated from the inclined side surface 2a of the multilayer body 2, it is possible to prevent a short circuit of the PN junction surface due to cutting waste when the metal member 1 is cut.
[0034]
Further, in the nitride semiconductor light emitting device according to the first embodiment of the present invention, since the electrodes are formed on both sides of the stacked body 2, one electrode is formed like the device in which the electrodes are formed on the same surface side. Therefore, it is not necessary to remove a part of the light emitting layer. Thereby, since the light emitting region can be secured without reducing the area of the light emitting layer, the light emission efficiency can be improved.
[0035]
Further, in the nitride semiconductor light emitting device according to the first embodiment of the present invention, since the electrodes are formed on both sides of the multilayer body 2, it is possible to easily flow a current uniformly over the entire light emitting layer, and the entire light emitting layer Can be emitted uniformly and efficiently.
In particular, in the case where one light emitting element is constituted by a plurality of stacked portions, a light emitting element excellent in uniformity within the light emitting surface can be provided in a relatively wide area.
[0036]
Further, in the nitride semiconductor light emitting device of the first embodiment, since the transparent electrode 21 is formed on almost the entire surface of the n-type nitride semiconductor layer, other current can be uniformly injected into the entire light emitting layer. The entire light emitting layer can emit light uniformly.
However, the present invention is not limited to this, and instead of the transparent electrode 21, a network-like (lattice-like) n-type electrode is formed on almost the entire surface of the n-type nitride semiconductor layer, and light is transmitted from between the lattices. An output may be made, or an n-type electrode may be formed on a part of the n-type nitride semiconductor layer.
Since an n-type nitride semiconductor can have a smaller resistance value than a p-type nitride semiconductor, current easily diffuses in the n-type nitride semiconductor layer, and even when a lattice-shaped n-type electrode is used, The grating (the area of the portion where no electrode is formed) can be increased, and light can be emitted without much blocking by the electrode. Further, even when an n-type electrode is formed on a part of the n-type nitride semiconductor layer, a current can be injected into a relatively wide range of light-emitting layers.
[0037]
Modified example.
In the first embodiment described above, the n-type nitride semiconductor layer 11 is etched halfway in the thickness direction so that the stacked body includes at least a part of the n-type nitride semiconductor layer. However, the present invention is not limited to this, and the stacked portion 102a may be formed by etching only the p-type nitride semiconductor layer 13 and the light emitting layer 12, as shown in FIG. As shown in FIG. 13, after the p-type nitride semiconductor layer 13 and the light emitting layer 12 are etched, the n-type nitride semiconductor layer 11 is continuously etched until the sapphire substrate is exposed. The stacked portion 102b may be formed by the semiconductor layer 13, the light emitting layer 12, and the n-type nitride semiconductor layer 11.
[0038]
Embodiment 2. FIG.
The nitride semiconductor light emitting device according to the second embodiment of the present invention is a light emitting device in which four stacked bodies 102a are arranged as an example, as shown in FIG.
That is, as shown in FIG. 17, the nitride semiconductor light emitting device of the second embodiment has a total of 16 quadrangular pyramid-shaped stacks 102a (four p-type nitride semiconductor layers and light emitting layers). Is arranged on one surface of the n-type nitride semiconductor layer 11 to constitute a light emitting device having a relatively large area.
In the nitride semiconductor light emitting device of the second embodiment, the transparent electrode 23 common to all the stacked bodies 102a is formed as an n-type ohmic electrode on the entire other surface of the n-type nitride semiconductor layer 11. One n-pad electrode 23 is formed at the center.
Further, in the nitride semiconductor light emitting device of the second embodiment, the 16 laminated bodies 102a constitute one light emitting element, and the division position is at least a position away from the inclined side surface 2a of the laminated body 2. In this way, it is divided between the stacked portions.
[0039]
Since the nitride semiconductor light emitting device of the second embodiment configured as described above is separated from the inclined side surface 2a of the stacked body 2 at the time of dividing into the elements, the PN of the inclined side surface 2a of the stacked body 2 The joint surface is not damaged, and the PN joint surface can be prevented from being short-circuited by cutting waste when the metal member 1 is cut.
[0040]
Moreover, in the nitride semiconductor light emitting device of the first embodiment according to the present invention, the luminous efficiency can be improved for the same reason as the nitride semiconductor light emitting device of the first embodiment, and the entire light emitting layer can be made uniform and Light can be emitted efficiently.
[0041]
The nitride semiconductor light emitting device of the second embodiment described above does not include the n-type nitride semiconductor layer 11, and uses the stacked body 102a in which the p-type nitride semiconductor layer 13 and the light emitting layer 12 are stacked. Configured. However, the present invention is not limited to this, and as illustrated in FIG. 15, a stacked body 102 b in which an n-type nitride semiconductor layer 11, a p-type nitride semiconductor layer 13, and a light emitting layer 12 are stacked is used. It may be configured.
[0042]
In the nitride semiconductor light emitting device of the second embodiment described above, the n-type nitride semiconductor layer 11 is formed on the wafer so as to be separated between the light emitting devices without being separated for each stacked body in one light emitting device. After that, the n-type nitride semiconductor layer 11 may be divided for each element at the separated portion (FIG. 16).
[0043]
In addition, the nitride semiconductor light emitting device of the second embodiment is configured using the quadrangular pyramid-shaped stacked body 102a, but the present invention is not limited to this, and the truncated cone-shaped stacked body 102b is used. You may make it comprise (FIG. 18).
[0044]
【The invention's effect】
As described above in detail, the nitride semiconductor light emitting device according to the present invention is a nitride having a light emitting layer made of a nitride semiconductor between an n-type nitride semiconductor layer and a p-type nitride semiconductor layer. In the semiconductor light emitting device, a trapezoidal cone-shaped laminate is formed so as to include the p-type nitride semiconductor layer and the light emitting layer, and the laminate is embedded in a metal member so that the side surface is insulated. The side surfaces of the laminate are not damaged when or after cutting. Therefore, according to the nitride semiconductor light emitting device according to the present invention, the reliability can be improved.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of a nitride semiconductor light-emitting element according to a first embodiment of the present invention.
2 is a cross-sectional view after forming a semiconductor layer on a sapphire substrate in the method for manufacturing a nitride semiconductor light-emitting element according to the first embodiment of the present invention. FIG.
3 is a cross-sectional view after forming a stacked body by etching a semiconductor layer on a sapphire substrate in the manufacturing method of Embodiment 1. FIG.
4 is a cross-sectional view after forming a p-type electrode on each stacked body in the manufacturing method of Embodiment 1. FIG.
5 is a cross-sectional view after forming an insulating layer 3 in the manufacturing method of Embodiment 1. FIG.
6 is a cross-sectional view after a reflective layer 24 is formed in the manufacturing method of Embodiment 1. FIG.
7 is a cross-sectional view after forming the metal member 1 in the manufacturing method of the first embodiment. FIG.
8 is a cross-sectional view after the sapphire substrate is peeled off in the manufacturing method of Embodiment 1. FIG.
9 is a cross-sectional view after forming a transparent electrode on an n-type nitride semiconductor layer after peeling off a sapphire substrate in the manufacturing method of Embodiment 1. FIG.
10 is a cross-sectional view after forming an n-pad electrode and an insulating film 4 after forming a transparent electrode in the manufacturing method of Embodiment 1. FIG.
11 is a cross-sectional view showing a method of forming a trapezoidal cone-shaped laminated body in the manufacturing method of Embodiment 1. FIG.
12 is a cross sectional view of a nitride semiconductor device according to a modification of the first embodiment. FIG.
13 is a cross-sectional view of a nitride semiconductor device according to a modification different from FIG. 12 of the first embodiment. FIG.
14 is a cross-sectional view of the nitride semiconductor device of the second embodiment. FIG.
15 is a cross sectional view of a nitride semiconductor device according to Modification 1 of Embodiment 2. FIG.
16 is a cross-sectional view of a nitride semiconductor device according to Modification 2 of Embodiment 2. FIG.
17 is a plan view of the nitride semiconductor device of the second embodiment. FIG.
18 is a plan view of a nitride semiconductor device according to Modification 3 of Embodiment 2. FIG.
[Explanation of symbols]
1 ... Metal member,
2 ... Laminated body,
2a ... side,
3 ... Insulating layer,
10 ... sapphire substrate,
11 ... n-type nitride semiconductor layer,
12 ... light emitting layer,
13 ... p-type nitride semiconductor layer,
21 ... Transparent electrode,
22 ... p-type ohmic electrode,
23 ... n pad electrode,
M1 ... Mask.

Claims (15)

n型窒化物半導体層とp型窒化物半導体層の間に、窒化物半導体からなる発光層を有してなる窒化物半導体発光素子において、
少なくとも上記p型窒化物半導体層と上記発光層を含むように台形錐形状の積層体が形成され、該積層体は側面が絶縁されるように金属部材に埋め込まれたことを特徴とする窒化物半導体発光素子。
In a nitride semiconductor light emitting device having a light emitting layer made of a nitride semiconductor between an n type nitride semiconductor layer and a p type nitride semiconductor layer,
A nitride having a trapezoidal pyramid shape formed so as to include at least the p-type nitride semiconductor layer and the light emitting layer, and the laminate is embedded in a metal member so that a side surface is insulated. Semiconductor light emitting device.
n型窒化物半導体層とp型窒化物半導体層の間に、窒化物半導体からなる発光層を有してなる窒化物半導体発光素子において、
少なくとも上記p型窒化物半導体層と上記発光層を含むように台形錐形状の積層体が形成されて、その積層体が該積層体の表面に沿って対向するように設けられた金属部材により保持されたことを特徴とする窒化物半導体発光素子。
In a nitride semiconductor light emitting device having a light emitting layer made of a nitride semiconductor between an n type nitride semiconductor layer and a p type nitride semiconductor layer,
A stack having a trapezoidal pyramid shape is formed so as to include at least the p-type nitride semiconductor layer and the light emitting layer, and the stack is held by a metal member provided so as to face along the surface of the stack. A nitride semiconductor light emitting device characterized by the above.
上記金属部材の上記積層体の反対側に位置する面が、平坦な面である請求項1又は2記載の窒化物半導体発光素子。The nitride semiconductor light-emitting element according to claim 1, wherein a surface of the metal member located on the opposite side of the laminate is a flat surface. 上記n型窒化物半導体層の対向する2つの面のうちの上記積層体の反対側に位置する面に透明電極が形成されている請求項1〜3のうちのいずれか1つに記載の窒化物半導体発光素子。The nitriding as described in any one of Claims 1-3 in which the transparent electrode is formed in the surface located in the other side of the said laminated body among the two surfaces which the said n-type nitride semiconductor layer opposes. Semiconductor light emitting device. 上記透明電極はITOである請求項4記載の窒化物半導体発光素子。The nitride semiconductor light emitting device according to claim 4, wherein the transparent electrode is ITO. 上記p型窒化物半導体層とオーミック接触するように上記積層体と上記金属部材の間に形成されたp型電極は、Rhを含む請求項1〜5のうちのいずれか1つに記載の窒化物半導体発光素子。6. The nitriding according to claim 1, wherein the p-type electrode formed between the stacked body and the metal member so as to be in ohmic contact with the p-type nitride semiconductor layer includes Rh. Semiconductor light emitting device. 上記積層体は上記n型窒化物半導体層の一部を含んで構成されている請求項1〜6のうちのいずれか1つに記載の窒化物半導体発光素子。The nitride semiconductor light emitting element according to claim 1, wherein the stacked body includes a part of the n-type nitride semiconductor layer. 上記積層体は上記n型窒化物半導体層の全てを含むように構成されている請求項1〜6のうちのいずれか1つに記載の窒化物半導体発光素子。The nitride semiconductor light emitting element according to claim 1, wherein the stacked body is configured to include all of the n-type nitride semiconductor layer. 上記金属部材の厚さは50μm以上である請求項1〜8のうちのいずれか1つに記載の窒化物半導体発光素子。The nitride semiconductor light-emitting element according to claim 1, wherein the metal member has a thickness of 50 μm or more. 上記積層体を複数個備えた請求項1〜9のうちのいずれか1つに記載の窒化物半導体発光素子。The nitride semiconductor light-emitting device according to claim 1, comprising a plurality of the stacked bodies. 上記複数の積層体は、共通のn型窒化物半導体層の上に設けられている請求項10記載の窒化物半導体発光素子。The nitride semiconductor light emitting element according to claim 10, wherein the plurality of stacked bodies are provided on a common n-type nitride semiconductor layer. 上記n型窒化物半導体は、各積層体ごとに分離されている請求項10記載の窒化物半導体発光素子。The nitride semiconductor light emitting device according to claim 10, wherein the n-type nitride semiconductor is separated for each stacked body. 上記金属部材は、Ti、Ag、Al、Ni、Pt、Au、Rh、Cu、W等からなる群から選択された金属又はその金属を少なくとも含む合金からなる請求項1〜12のうちのいずれか1つに記載の窒化物半導体発光素子。The metal member is made of a metal selected from the group consisting of Ti, Ag, Al, Ni, Pt, Au, Rh, Cu, W, or the like, or an alloy containing at least the metal. The nitride semiconductor light-emitting device according to one. 基板上にn型半導体層と発光層とp型半導体層を形成する第1工程と、
上記p型半導体層と上記発光層とを含むように台形錐形状の発光領域を形成する第2工程と、
上記発光領域を覆うように金属部材を形成する第3工程と、
上記基板を除去する第4工程と、
上記発光領域の間で金属部材を切断することにより、発光素子ごとに分離する第5工程とを含むことを特徴とする発光素子の製造方法。
A first step of forming an n-type semiconductor layer, a light emitting layer, and a p-type semiconductor layer on a substrate;
A second step of forming a trapezoidal cone-shaped light emitting region so as to include the p-type semiconductor layer and the light emitting layer;
A third step of forming a metal member so as to cover the light emitting region;
A fourth step of removing the substrate;
And a fifth step of separating each light emitting element by cutting a metal member between the light emitting regions.
上記第3工程において、上記金属部材をメッキにより形成する請求項14記載の発光素子の製造方法。The method for manufacturing a light-emitting element according to claim 14, wherein in the third step, the metal member is formed by plating.
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