JP2001527135A - オレフィン重合用担持触媒系 - Google Patents

オレフィン重合用担持触媒系

Info

Publication number
JP2001527135A
JP2001527135A JP2000526552A JP2000526552A JP2001527135A JP 2001527135 A JP2001527135 A JP 2001527135A JP 2000526552 A JP2000526552 A JP 2000526552A JP 2000526552 A JP2000526552 A JP 2000526552A JP 2001527135 A JP2001527135 A JP 2001527135A
Authority
JP
Japan
Prior art keywords
dimethylsilanediylbis
methyl
zirconium dichloride
indenyl
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000526552A
Other languages
English (en)
Japanese (ja)
Other versions
JP2001527135A5 (https=
Inventor
フリッツェ，コルネリア
ボーネン，ハンス
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polypropylen GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polypropylen GmbH filed Critical Basell Polypropylen GmbH
Publication of JP2001527135A publication Critical patent/JP2001527135A/ja
Publication of JP2001527135A5 publication Critical patent/JP2001527135A5/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
JP2000526552A 1997-12-23 1998-12-10 オレフィン重合用担持触媒系 Pending JP2001527135A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19757540A DE19757540A1 (de) 1997-12-23 1997-12-23 Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
DE19757540.4 1997-12-23
PCT/EP1998/008050 WO1999033881A1 (de) 1997-12-23 1998-12-10 Geträgertes katalysatorsystem zur polymerisation von olefinen

Publications (2)

Publication Number Publication Date
JP2001527135A true JP2001527135A (ja) 2001-12-25
JP2001527135A5 JP2001527135A5 (https=) 2006-01-26

Family

ID=7853188

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000526552A Pending JP2001527135A (ja) 1997-12-23 1998-12-10 オレフィン重合用担持触媒系

Country Status (7)

Country Link
US (1) US7202190B1 (https=)
EP (1) EP1042371B1 (https=)
JP (1) JP2001527135A (https=)
BR (1) BR9814410A (https=)
DE (2) DE19757540A1 (https=)
ES (1) ES2210860T3 (https=)
WO (1) WO1999033881A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002534537A (ja) * 1998-12-30 2002-10-15 ビーピー ケミカルズ リミテッド 減少量の溶剤を用いる支持重合触媒の製造方法および重合方法
JP2019156896A (ja) * 2018-03-08 2019-09-19 日本ポリエチレン株式会社 オレフィン重合触媒及びオレフィン重合体の製造方法

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19828271A1 (de) * 1998-06-25 1999-12-30 Elenac Gmbh Verfahren zur Herstellung eines geträgerten Katalysatorsystems
WO2000020466A1 (de) * 1998-10-01 2000-04-13 Targor Gmbh Katalysatorsystem
DE19917985A1 (de) * 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
US6395847B2 (en) * 1999-11-19 2002-05-28 Exxonmobil Chemical Patents Inc. Supported organometallic catalysts and their use in olefin polymerization
WO2001036499A1 (en) * 1999-11-19 2001-05-25 Exxon Chemical Patents Inc. Preparation of supported polymerization catalysts
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
US6414095B1 (en) 2000-06-30 2002-07-02 Exxon Mobil Chemical Patents Inc. Metallocene compositions
US6399723B1 (en) 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6870016B1 (en) 2000-06-30 2005-03-22 Exxonmobil Chemical Patents Inc. Polymerization process and polymer composition
US6380330B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380334B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376408B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376411B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380124B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
AU2003257456A1 (en) 2002-07-15 2004-02-02 Basell Polyolefine Gmbh Preparation of supported catalyst systems
BRPI0418117B1 (pt) 2003-12-23 2015-10-13 Basell Polyolefine Gmbh preparação de cocatalisadores suportados
EP1650231A1 (en) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Polyolefins prepared from a metallocene and a new single site catalyst components in a single reactor
US7232869B2 (en) 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization

Family Cites Families (23)

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Publication number Priority date Publication date Assignee Title
JPS5964604A (ja) 1982-10-06 1984-04-12 Sumitomo Chem Co Ltd ポリオレフインの製造方法
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
ATE186918T1 (de) 1990-01-02 1999-12-15 Exxon Chemical Patents Inc Ionische metallocenkatalysatoren auf träger für olefinpolymerisation
DE69219206T2 (de) * 1991-05-31 1997-08-28 Mitsui Petrochemical Ind Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
DE69222700T2 (de) * 1991-07-11 1998-03-26 Idemitsu Kosan Co Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren
TW309523B (https=) 1991-11-30 1997-07-01 Hoechst Ag
JP3194438B2 (ja) * 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
TW294669B (https=) 1992-06-27 1997-01-01 Hoechst Ag
US5372980A (en) 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
DE4325824A1 (de) 1993-07-31 1995-02-02 Basf Ag Verfahren zur Herstellung von Homopolymerisaten des Ethylens oder Copolymerisaten des Ethylens
FI945959A7 (fi) 1993-12-21 1995-06-22 Targor Gmbh Metalloseenejä ja niiden käyttö katalyytteinä
FI945958L (fi) 1993-12-21 1995-06-22 Hoechst Ag Menetelmä polyolefiinien valmistamiseksi
EP0737694B1 (en) * 1993-12-28 2001-06-06 Idemitsu Kosan Company Limited Process for producing olefin polymer and ethylene polymer
BR9508487A (pt) * 1994-08-03 1997-12-30 Exxon Chemical Patents Inc Composição de catalisador iônico suportado
EP0707016B1 (en) * 1994-10-13 1997-09-24 Japan Polyolefins Co., Ltd. Catalyst component for producing polyolefin, catalyst for producing polyolefin comprising the catalyst component, and process for producing polyolefin in the presence of the catalyst
US5939347A (en) * 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
DE69611554T2 (de) 1995-02-20 2001-07-05 Tosoh Corp., Shinnanyo Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
IT1275777B1 (it) * 1995-07-06 1997-10-17 Enichem Spa Catalizzatore metallocenico per la (co)polimerizzazione delle olefine
PL326932A1 (en) * 1995-11-27 1998-11-09 Dow Chemical Co Supported catalyst containing an activator capable to form "captured" cations

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002534537A (ja) * 1998-12-30 2002-10-15 ビーピー ケミカルズ リミテッド 減少量の溶剤を用いる支持重合触媒の製造方法および重合方法
JP2019156896A (ja) * 2018-03-08 2019-09-19 日本ポリエチレン株式会社 オレフィン重合触媒及びオレフィン重合体の製造方法

Also Published As

Publication number Publication date
DE19757540A1 (de) 1999-06-24
US7202190B1 (en) 2007-04-10
DE59809824D1 (de) 2003-11-06
EP1042371B1 (de) 2003-10-01
ES2210860T3 (es) 2004-07-01
WO1999033881A1 (de) 1999-07-08
EP1042371A1 (de) 2000-10-11
BR9814410A (pt) 2000-10-10

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