JP2001213821A - 不飽和のアルデヒドおよび酸を製造するための高炭化水素空間速度プロセス - Google Patents
不飽和のアルデヒドおよび酸を製造するための高炭化水素空間速度プロセスInfo
- Publication number
- JP2001213821A JP2001213821A JP2000355843A JP2000355843A JP2001213821A JP 2001213821 A JP2001213821 A JP 2001213821A JP 2000355843 A JP2000355843 A JP 2000355843A JP 2000355843 A JP2000355843 A JP 2000355843A JP 2001213821 A JP2001213821 A JP 2001213821A
- Authority
- JP
- Japan
- Prior art keywords
- oxidation
- reactor
- temperature
- heat transfer
- contact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 164
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 164
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 150
- 238000000034 method Methods 0.000 title claims abstract description 57
- 230000008569 process Effects 0.000 title claims abstract description 54
- 239000002253 acid Substances 0.000 title description 10
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title description 3
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 360
- 230000003647 oxidation Effects 0.000 claims abstract description 351
- 239000003054 catalyst Substances 0.000 claims abstract description 270
- 239000000203 mixture Substances 0.000 claims abstract description 200
- 239000000376 reactant Substances 0.000 claims abstract description 175
- 239000007789 gas Substances 0.000 claims abstract description 143
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 84
- 239000001301 oxygen Substances 0.000 claims abstract description 84
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 84
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 53
- 230000003197 catalytic effect Effects 0.000 claims abstract description 42
- 230000035945 sensitivity Effects 0.000 claims abstract description 30
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 210
- 238000006243 chemical reaction Methods 0.000 claims description 183
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 94
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 94
- 239000000047 product Substances 0.000 claims description 76
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 59
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 57
- 239000000446 fuel Substances 0.000 claims description 44
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 36
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 34
- 239000011261 inert gas Substances 0.000 claims description 31
- 150000003839 salts Chemical class 0.000 claims description 18
- 230000001590 oxidative effect Effects 0.000 claims description 17
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 claims description 16
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 14
- 239000012467 final product Substances 0.000 claims description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical group [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 23
- 239000012808 vapor phase Substances 0.000 abstract description 2
- 230000003416 augmentation Effects 0.000 abstract 1
- 239000006096 absorbing agent Substances 0.000 description 26
- 239000012071 phase Substances 0.000 description 18
- 239000000126 substance Substances 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 16
- 239000000463 material Substances 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 150000001299 aldehydes Chemical class 0.000 description 8
- 239000001294 propane Substances 0.000 description 8
- 239000011833 salt mixture Substances 0.000 description 8
- 239000012535 impurity Substances 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- 238000011068 loading method Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- -1 parts Substances 0.000 description 3
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 239000004317 sodium nitrate Substances 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- 229930195735 unsaturated hydrocarbon Chemical class 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910000743 fusible alloy Inorganic materials 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229940127554 medical product Drugs 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
- B01J2208/023—Details
- B01J2208/024—Particulate material
- B01J2208/025—Two or more types of catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16707999P | 1999-11-23 | 1999-11-23 | |
| US60/167079 | 1999-11-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001213821A true JP2001213821A (ja) | 2001-08-07 |
| JP2001213821A5 JP2001213821A5 (enExample) | 2008-01-17 |
Family
ID=22605843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000355843A Pending JP2001213821A (ja) | 1999-11-23 | 2000-11-22 | 不飽和のアルデヒドおよび酸を製造するための高炭化水素空間速度プロセス |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US6620968B1 (enExample) |
| EP (1) | EP1106598A3 (enExample) |
| JP (1) | JP2001213821A (enExample) |
| KR (1) | KR100811510B1 (enExample) |
| CN (1) | CN1149184C (enExample) |
| BR (1) | BR0005544A (enExample) |
| TW (1) | TW581758B (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006521314A (ja) * | 2003-03-25 | 2006-09-21 | ビーエーエスエフ アクチェンゲゼルシャフト | アクロレインからアクリル酸への不均一系接触部分気相酸化法 |
| JP2008528683A (ja) * | 2005-02-01 | 2008-07-31 | エルジー・ケム・リミテッド | 不飽和脂肪酸の製造法 |
| JP4762899B2 (ja) * | 2003-09-01 | 2011-08-31 | エルジー・ケム・リミテッド | 固定層触媒部分酸化反応器における改善された熱制御システムによる不飽和アルデヒド及び不飽和酸の製造方法 |
| JP2014511343A (ja) * | 2010-12-22 | 2014-05-15 | エボニック デグサ ゲーエムベーハー | アクロレインの製造および青酸の製造からの排ガスを熱的に後燃焼させるための方法 |
| US9580376B2 (en) | 2013-07-18 | 2017-02-28 | Nippon Kayaku Kabushiki Kaisha | Method for producing unsaturated aldehyde and/or unsaturated carboxylic acid |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6620968B1 (en) * | 1999-11-23 | 2003-09-16 | Rohm And Haas Company | High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids |
| US20040104108A1 (en) | 2002-12-03 | 2004-06-03 | Mason Robert Michael | High capacity purification of thermally unstable compounds |
| TWI311131B (en) | 2003-03-25 | 2009-06-21 | Basf Ag | Heterogeneously catalyzed partial gas phase oxidation of propene to acrolein |
| ATE389630T1 (de) | 2003-03-25 | 2008-04-15 | Basf Se | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propen zu acrylsäure |
| DE10313208A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
| DE10313209A1 (de) | 2003-03-25 | 2004-03-04 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
| DE10313212A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrolein |
| DE10313214A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure |
| MXPA06001255A (es) * | 2003-07-31 | 2006-05-15 | Dow Global Technologies Inc | Proceso de oxidacion, y reactor con sistema de alimentacion modificado. |
| JP2007501193A (ja) | 2003-08-06 | 2007-01-25 | ビーエーエスエフ アクチェンゲゼルシャフト | 少なくとも１の有機化合物を不均一系触媒により連続的に気相部分酸化する方法 |
| EP1656335A1 (de) | 2003-08-14 | 2006-05-17 | Basf Aktiengesellschaft | Verfahren zur herstellung von (meth)acrolein und/oder (meth)acryls ure |
| US7012157B2 (en) | 2003-09-23 | 2006-03-14 | Basf Aktiengesellschaft | Preparation of (meth)acrylic acid |
| US7019169B2 (en) | 2003-09-23 | 2006-03-28 | Basf Aktiengesellschaft | Preparation of (meth)acrylic acid |
| BRPI0416081B1 (pt) | 2003-10-29 | 2014-08-19 | Basf Ag | Processo para a operação a longo prazo de uma oxidação parcial em fase gasosa heterogeneamente catalisada de acroleína a ácido acrílico |
| EP1682474B1 (de) | 2003-10-29 | 2015-01-14 | Basf Se | Verfahren zum langzeitbetrieb einer heterogen katalysierten gasphasenpartialoxidation von propen zu acrolein |
| DE10350812A1 (de) | 2003-10-29 | 2005-06-02 | Basf Ag | Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation von Propen zu Acrolein |
| DE10351269A1 (de) | 2003-10-31 | 2005-06-02 | Basf Ag | Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation von Propen zu Acrylsäure |
| JP4477640B2 (ja) * | 2003-12-24 | 2010-06-09 | エルジー・ケム・リミテッド | 固定層触媒酸化反応器における改善された熱制御システムによる不飽和酸の製造方法 |
| KR101237662B1 (ko) | 2004-05-07 | 2013-02-26 | 바스프 에스이 | 촉매 튜브 다발의 촉매 튜브를 구조화된 방식으로 충진하는방법 |
| DE102004025445A1 (de) | 2004-05-19 | 2005-02-10 | Basf Ag | Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation wenigstens einer organischen Verbindung |
| US7592483B2 (en) | 2004-07-01 | 2009-09-22 | Basf Aktiengesellschaft | Preparation of acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas phase oxidation of propylene |
| US7439389B2 (en) | 2005-03-01 | 2008-10-21 | Basf Aktiengesellschaft | Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation |
| DE102005019911A1 (de) | 2005-04-27 | 2006-11-02 | Basf Ag | Verfahren der rektifikativen Auftrennung einer Acrylsäure und/oder Methacrylsäure enthaltenden Flüssigkeit |
| DE102006000996A1 (de) | 2006-01-05 | 2007-07-12 | Basf Ag | Verfahren der heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Ausgangsverbindung |
| EP1734030A1 (de) | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung |
| DE102007004961A1 (de) | 2007-01-26 | 2008-07-31 | Basf Se | Verfahren zur Herstellung von Katalysatorformkörpern, deren Aktivmasse ein Multielementoxid ist |
| DE102007010422A1 (de) | 2007-03-01 | 2008-09-04 | Basf Se | Verfahren zur Herstellung eines Katalysators bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Masse |
| DE102007017080A1 (de) | 2007-04-10 | 2008-10-16 | Basf Se | Verfahren zur Beschickung eines Längsabschnitts eines Kontaktrohres |
| DE102007025869A1 (de) | 2007-06-01 | 2008-07-03 | Basf Se | Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett |
| DE102007028333A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors |
| DE102007028332A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst |
| TW200948474A (en) | 2008-04-09 | 2009-12-01 | Basf Se | Coated catalysts comprising a multimetal oxide comprising molybdenum |
| DE102008040093A1 (de) | 2008-07-02 | 2008-12-18 | Basf Se | Verfahren zur Herstellung eines ringähnlichen oxidischen Formkörpers |
| DE102008040094A1 (de) | 2008-07-02 | 2009-01-29 | Basf Se | Verfahren zur Herstellung eines oxidischen geometrischen Formkörpers |
| DE102008042060A1 (de) | 2008-09-12 | 2009-06-18 | Basf Se | Verfahren zur Herstellung von geometrischen Katalysatorformkörpern |
| DE102008042064A1 (de) | 2008-09-12 | 2010-03-18 | Basf Se | Verfahren zur Herstellung von geometrischen Katalysatorformkörpern |
| DE102008042061A1 (de) | 2008-09-12 | 2010-03-18 | Basf Se | Verfahren zur Herstellung von geometrischen Katalysatorformkörpern |
| DE102008054586A1 (de) | 2008-12-12 | 2010-06-17 | Basf Se | Verfahren zur kontinuierlichen Herstellung von geometrischen Katalysatorformkörpern K |
| DE102010048405A1 (de) | 2010-10-15 | 2011-05-19 | Basf Se | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein |
| DE102011076931A1 (de) | 2011-06-03 | 2012-12-06 | Basf Se | Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base |
| DE102011079035A1 (de) | 2011-07-12 | 2013-01-17 | Basf Se | Mo, Bi und Fe enthaltende Multimetalloxidmassen |
| MY171079A (en) | 2011-07-12 | 2019-09-24 | Basf Se | Mo-, bi- and fe-comprising multimetal oxide compositions |
| DE102011084040A1 (de) | 2011-10-05 | 2012-01-05 | Basf Se | Mo, Bi und Fe enthaltende Multimetalloxidmasse |
| DE102013202048A1 (de) | 2013-02-07 | 2013-04-18 | Basf Se | Verfahren zur Herstellung einer katalytisch aktiven Masse, die ein Gemisch aus einem die Elemente Mo und V enthaltenden Multielementoxid und wenigstens einem Oxid des Molybdäns ist |
| WO2015067659A1 (de) | 2013-11-11 | 2015-05-14 | Basf Se | Mechanisch stabiler hohlzylindrischer katalysatorformkörper zur gasphasenoxidation eines alkens zu einem ungesättigten aldehyd und/oder einer ungesättigten carbonsäure |
| EP3068754B1 (de) | 2013-11-11 | 2018-01-31 | Basf Se | Verfahren zur herstellung eines ungesättigten aldehyds und/oder einer ungesättigten carbonsäure |
| DE102015209638A1 (de) | 2015-05-27 | 2016-07-07 | Basf Se | Verfahren zur Herstellung eines Bismut und Wolfram enthaltenden Multielementoxids durch Co-Präzipitation |
| DE102018200841A1 (de) | 2018-01-19 | 2019-07-25 | Basf Se | Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen |
| EP3770145A1 (en) | 2019-07-24 | 2021-01-27 | Basf Se | A process for the continuous production of either acrolein or acrylic acid as the target product from propene |
| KR102705461B1 (ko) * | 2019-08-23 | 2024-09-09 | 주식회사 엘지화학 | (메트)아크릴산 제조용 복수의 반응관의 제조 방법 |
| EP3805194A1 (en) | 2020-09-25 | 2021-04-14 | Basf Se | Method for producing a multimetal oxide catalyst under gas-tight conditions |
| EP4572887A1 (de) | 2022-08-16 | 2025-06-25 | Basf Se | Verfahren zur herstellung von vollkatalysatorformkörpern zur gasphasenoxidation eines alkens und/oder eines alkohols zu einem a,b-ungesättigtem aldehyd und/oder einer a,b-ungesättigten carbonsäure |
| WO2025172145A1 (de) | 2024-02-16 | 2025-08-21 | Basf Se | Anorganische faser-haltiger multi-element-vollkatalysatorformkörper zur herstellung von ungesättigten aldehyden und ungesättigten carbonsäuren; dessen herstellungsverfahren sowie verwendung in der gasphasenoxidation |
| WO2025176520A1 (de) | 2024-02-23 | 2025-08-28 | Basf Se | Verfahren zur herstellung eines ethylenisch ungesättigten aldehyds und/oder einer ethylenisch ungesättigten carbonsäure an einem katalysatorfestbett eines rohrbündelreaktors |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5419479A (en) * | 1977-07-13 | 1979-02-14 | Nippon Shokubai Kagaku Kogyo Co Ltd | Reactor |
| JPS6463543A (en) * | 1987-05-27 | 1989-03-09 | Nippon Catalytic Chem Ind | Production of acrylic acid |
| JPH02218428A (ja) * | 1989-02-17 | 1990-08-31 | Jgc Corp | 中間管板を有する多管式装置 |
| JPH02218432A (ja) * | 1989-02-17 | 1990-08-31 | Jgc Corp | 仕切板をそなえた容器 |
| JPH04217932A (ja) * | 1990-04-03 | 1992-08-07 | Nippon Shokubai Co Ltd | 不飽和アルデヒドおよび不飽和酸の製造方法 |
| JPH05125010A (ja) * | 1991-10-30 | 1993-05-21 | Nippon Shokubai Co Ltd | 不飽和アルデヒドまたは不飽和酸の製造用反応器 |
| JPH1028877A (ja) * | 1996-05-14 | 1998-02-03 | Nippon Kayaku Co Ltd | 触媒及び不飽和アルデヒドおよび不飽和酸の製造方法 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4924898B1 (enExample) | 1970-12-26 | 1974-06-26 | ||
| JPS5129124B1 (enExample) | 1971-04-27 | 1976-08-24 | ||
| US4025565A (en) | 1972-02-22 | 1977-05-24 | Asahi Glass Co., Ltd. | Process for preparing unsaturated aldehyde having three to four carbon atoms |
| US3988213A (en) | 1972-09-25 | 1976-10-26 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method of distilling vinyl compounds |
| US4021310A (en) | 1972-12-22 | 1977-05-03 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for inhibiting the polymerization of acrylic acid or its esters |
| US3893951A (en) | 1973-02-22 | 1975-07-08 | Standard Oil Co | Catalysts for oxidation reactions |
| JPS5246208B2 (enExample) | 1973-03-22 | 1977-11-22 | ||
| US4034008A (en) | 1975-08-25 | 1977-07-05 | Union Carbide Corporation | Process for preparing unsaturated acids and aldehydes |
| JPS5223589A (en) | 1975-08-18 | 1977-02-22 | Mitsubishi Petrochem Co Ltd | Catalyst for producing alpha,beta-unsaturaded carboxylic acid |
| US4339355A (en) | 1975-10-09 | 1982-07-13 | Union Carbide Corporation | Catalytic oxide of molybdenum, vanadium, niobium and optional 4th metal |
| JPS52108917A (en) | 1976-03-11 | 1977-09-12 | Nippon Shokubai Kagaku Kogyo Co Ltd | Preparation of acrylic acid by vapor-phase catalytic oxidation of prop ylene |
| IT1063376B (it) | 1976-05-20 | 1985-02-11 | Montedison Spa | Procedimento per la preparazione di acidi carbossilici insaturi per ossidazione catalitica in fase gassosa delle corrispondenti aldeidi |
| DE2626887B2 (de) | 1976-06-16 | 1978-06-29 | Basf Ag, 6700 Ludwigshafen | Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure |
| AU529228B2 (en) | 1977-07-13 | 1983-06-02 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Catalytic vapour phase oxidation |
| US4317926A (en) | 1978-01-19 | 1982-03-02 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for preparing and recovering acrylic acid |
| JPS55102536A (en) | 1979-01-30 | 1980-08-05 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
| JPS5673041A (en) | 1979-11-19 | 1981-06-17 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
| AU606160B2 (en) * | 1987-05-27 | 1991-01-31 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Process for production of acrylic acid |
| US5218146A (en) | 1987-05-27 | 1993-06-08 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for production of acrylic acid |
| US5177260A (en) | 1989-11-06 | 1993-01-05 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for production of acrylic acid |
| DE69402567T2 (de) | 1993-01-28 | 1997-11-27 | Mitsubishi Chem Corp | Methode zur Herstellung einer ungesättigten Carbonsäure |
| DE4431957A1 (de) | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein |
| DE4431949A1 (de) | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
| JP3948798B2 (ja) | 1997-10-27 | 2007-07-25 | 株式会社日本触媒 | アクリル酸の製造方法 |
| JP3948837B2 (ja) * | 1998-08-10 | 2007-07-25 | 株式会社日本触媒 | アクリル酸の製造方法 |
| MY121878A (en) | 1999-03-10 | 2006-02-28 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrylic acid |
| MY121141A (en) | 1999-03-10 | 2005-12-30 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrolein |
| DE19910508A1 (de) | 1999-03-10 | 2000-09-21 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
| MY119958A (en) | 1999-03-10 | 2005-08-30 | Basf Ag | Catalytic gas-phase oxidation of propene to acrylic acid |
| JP3943284B2 (ja) * | 1999-05-27 | 2007-07-11 | 株式会社日本触媒 | アクリル酸の製造方法 |
| US6620968B1 (en) * | 1999-11-23 | 2003-09-16 | Rohm And Haas Company | High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids |
-
2000
- 2000-11-08 US US09/708,138 patent/US6620968B1/en not_active Expired - Lifetime
- 2000-11-15 EP EP00310165A patent/EP1106598A3/en not_active Ceased
- 2000-11-20 TW TW089124534A patent/TW581758B/zh active
- 2000-11-22 KR KR1020000069477A patent/KR100811510B1/ko not_active Expired - Lifetime
- 2000-11-22 JP JP2000355843A patent/JP2001213821A/ja active Pending
- 2000-11-23 CN CNB001380486A patent/CN1149184C/zh not_active Expired - Lifetime
- 2000-11-23 BR BR0005544-1A patent/BR0005544A/pt not_active Application Discontinuation
-
2003
- 2003-08-01 US US10/632,705 patent/US20040059155A1/en not_active Abandoned
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5419479A (en) * | 1977-07-13 | 1979-02-14 | Nippon Shokubai Kagaku Kogyo Co Ltd | Reactor |
| JPS6463543A (en) * | 1987-05-27 | 1989-03-09 | Nippon Catalytic Chem Ind | Production of acrylic acid |
| JPH02218428A (ja) * | 1989-02-17 | 1990-08-31 | Jgc Corp | 中間管板を有する多管式装置 |
| JPH02218432A (ja) * | 1989-02-17 | 1990-08-31 | Jgc Corp | 仕切板をそなえた容器 |
| JPH04217932A (ja) * | 1990-04-03 | 1992-08-07 | Nippon Shokubai Co Ltd | 不飽和アルデヒドおよび不飽和酸の製造方法 |
| JPH05125010A (ja) * | 1991-10-30 | 1993-05-21 | Nippon Shokubai Co Ltd | 不飽和アルデヒドまたは不飽和酸の製造用反応器 |
| JPH1028877A (ja) * | 1996-05-14 | 1998-02-03 | Nippon Kayaku Co Ltd | 触媒及び不飽和アルデヒドおよび不飽和酸の製造方法 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006521314A (ja) * | 2003-03-25 | 2006-09-21 | ビーエーエスエフ アクチェンゲゼルシャフト | アクロレインからアクリル酸への不均一系接触部分気相酸化法 |
| JP4762899B2 (ja) * | 2003-09-01 | 2011-08-31 | エルジー・ケム・リミテッド | 固定層触媒部分酸化反応器における改善された熱制御システムによる不飽和アルデヒド及び不飽和酸の製造方法 |
| JP2008528683A (ja) * | 2005-02-01 | 2008-07-31 | エルジー・ケム・リミテッド | 不飽和脂肪酸の製造法 |
| JP2014511343A (ja) * | 2010-12-22 | 2014-05-15 | エボニック デグサ ゲーエムベーハー | アクロレインの製造および青酸の製造からの排ガスを熱的に後燃焼させるための方法 |
| US9580376B2 (en) | 2013-07-18 | 2017-02-28 | Nippon Kayaku Kabushiki Kaisha | Method for producing unsaturated aldehyde and/or unsaturated carboxylic acid |
| JPWO2015008814A1 (ja) * | 2013-07-18 | 2017-03-02 | 日本化薬株式会社 | 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US6620968B1 (en) | 2003-09-16 |
| EP1106598A2 (en) | 2001-06-13 |
| EP1106598A3 (en) | 2003-01-29 |
| KR20010051867A (ko) | 2001-06-25 |
| BR0005544A (pt) | 2001-07-03 |
| CN1149184C (zh) | 2004-05-12 |
| US20040059155A1 (en) | 2004-03-25 |
| TW581758B (en) | 2004-04-01 |
| CN1311177A (zh) | 2001-09-05 |
| KR100811510B1 (ko) | 2008-03-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2001213821A (ja) | 不飽和のアルデヒドおよび酸を製造するための高炭化水素空間速度プロセス | |
| EP1412077B8 (en) | Flow reactors for chemical conversions with hetergeneouos catalysts | |
| EP0990636B1 (en) | Single reactor process for preparing acrylic acid from propylene having improved capacity | |
| AU2002322502A1 (en) | Flow reactors for chemical conversions with heterogeneous catalysts | |
| JPH0892154A (ja) | アクロレインのアクリル酸への接触気相酸化法 | |
| JPH0813778B2 (ja) | メタクリル酸の製造方法 | |
| CN100491302C (zh) | 在具有提高热控制系统的固定床催化部分氧化反应器中制备不饱和酸的方法 | |
| WO2003055835A1 (en) | Process for vapor-phase catalytic oxidation and process for production of (meth)acrolein or (meth)acrylic acid | |
| US20100015017A1 (en) | Method of producing unsaturated acid in fixed-bed catalytic partial oxidation reactor with high efficiency | |
| JP5260300B2 (ja) | プロパンからのアクロレイン、又はアクリル酸、又はその混合物の製法 | |
| RU2416595C2 (ru) | Способ снижения температуры горячей точки неподвижного слоя катализатора в процессе получения акролеина или акриловой кислоты или их смеси гетерогенно катализируемым частичным окислением в газовой фазе | |
| MXPA00011545A (en) | High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids | |
| JPS5929679A (ja) | 無水マレイン酸の製造方法 | |
| JPH0343258B2 (enExample) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20061016 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070912 |
|
| RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20070912 |
|
| A524 | Written submission of copy of amendment under section 19 (pct) |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20071121 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100726 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101021 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20101026 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101124 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20101129 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20101221 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20101227 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20110323 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110722 |
|
| A911 | Transfer of reconsideration by examiner before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20110906 |
|
| A912 | Removal of reconsideration by examiner before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20111111 |