JP2000501721A - 有機ジスルフィドおよび有機ポリスルフィドの製造法 - Google Patents
有機ジスルフィドおよび有機ポリスルフィドの製造法Info
- Publication number
- JP2000501721A JP2000501721A JP9521776A JP52177697A JP2000501721A JP 2000501721 A JP2000501721 A JP 2000501721A JP 9521776 A JP9521776 A JP 9521776A JP 52177697 A JP52177697 A JP 52177697A JP 2000501721 A JP2000501721 A JP 2000501721A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- organic
- sulfur
- group
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/22—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
- C07C319/24—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides by reactions involving the formation of sulfur-to-sulfur bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 塩基性官能基を有する樹脂の形態の触媒の存在下で、イオウをメルカプタ ンと反応させることによって、又はイオウ鎖長の短い有機ポリスルフィドをイオ ウ鎖長の長い有機ポリスルフィドに変換するためにイオウをイオウ鎖長の短い有 機ポリスルフィドと反応させることによって、あるいはイオウ鎖長の長い有機ポ リスルフィドをイオウ鎖長の短い有機ポリスルフィドに変換するために、メルカ プタンをイオウ鎖長の長い有機ポリスルフィドと反応させることによって、有機 ジスルフィドおよび有機ポリスルフィドを製造する方法であって、前記樹脂が、 第1級アミン基で官能化され且つ以下の一般式(I): り、Lはメチレン基(−CH2−)以上の鎖長の直鎖有機基である] を有するポリスチレン−ジビニルベンゼン(PS−DVB)を基体とすることを 特徴とする方法。 2. 一般式(I)を有する樹脂がマクロ架橋され且つマクロポーラス構造をも つことを特徴とする、請求項1に記載の方法。 3. Lがメチレン(−CH2−)を表すことを特徴とする、請求項1又は2に 記載の方法。 4. Lが式(II) −CH2−(−X−CH2−CH2−)m− (II) [式中、Xは酸素(−O−)またはイオウ(−S−)を表し、mは1又は2であ る] の基を表すことを特徴とする、請求項1又は2に記載の方法。 5. Xが酸素を表し、mが1であることを特徴とする、請求項4に記載の方法 。 6. Xがイオウを表し、mが1であることを特徴とする、請求項4に記載の方 法。 7. メルカプタン並びに有機ジスルフィドおよび有機ポリスルフィドがアルキ ル、シクロアルキル、アリール、アラルキル又はアルキルアリール基から選択さ れた炭化水素基Rを有することを特徴とする、請求項1〜6のいずれか一項に記 載の方法。 8. 基Rが1以上の官能基をもつことを特徴とする、請求項7に記載の方法。 9. 樹脂が、樹脂を含む反応混合物の100重量部当り0.01〜20重量部 の範囲内の量で存在することを特徴とする、請求項6に記載の方法。 10. 反応を−10℃〜150℃の温度で行うことを特徴とする、請求項1〜 9のいずれか一項に記載の方法。 11. 温度が+10℃〜120℃であることを特徴とする、請求項10に記載 の方法。
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR95/14581 | 1995-12-11 | ||
FR9514581A FR2742144B1 (fr) | 1995-12-11 | 1995-12-11 | Procede de preparation de disulfures et de polysulfures organiques en presence de resines polystyrene-divinylbenzene possedant des groupes amine primaire |
PCT/FR1996/001921 WO1997021649A1 (fr) | 1995-12-11 | 1996-12-03 | Procede de preparation de disulfures et de polysulfures organiques |
US08/764,012 US5786511A (en) | 1995-12-11 | 1996-12-11 | Process for the preparation of organic disulphides and polysulphides in the presence of polystyrene-divinyl-benzene possessing primary amine groups |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2000501721A true JP2000501721A (ja) | 2000-02-15 |
JP2000501721A5 JP2000501721A5 (ja) | 2004-10-21 |
JP3911025B2 JP3911025B2 (ja) | 2007-05-09 |
Family
ID=26232369
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52177697A Expired - Fee Related JP3911025B2 (ja) | 1995-12-11 | 1996-12-03 | 有機ジスルフィドおよび有機ポリスルフィドの製造法 |
Country Status (16)
Country | Link |
---|---|
US (1) | US5786511A (ja) |
EP (1) | EP0876312B1 (ja) |
JP (1) | JP3911025B2 (ja) |
CN (1) | CN1171834C (ja) |
AT (1) | ATE199703T1 (ja) |
AU (1) | AU703677B2 (ja) |
BR (1) | BR9611842A (ja) |
CA (1) | CA2235714A1 (ja) |
DE (1) | DE69612117T2 (ja) |
DK (1) | DK0876312T3 (ja) |
ES (1) | ES2156302T3 (ja) |
FR (1) | FR2742144B1 (ja) |
GR (1) | GR3035791T3 (ja) |
IL (1) | IL124094A (ja) |
PT (1) | PT876312E (ja) |
WO (1) | WO1997021649A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014141428A (ja) * | 2013-01-23 | 2014-08-07 | Shin Etsu Chem Co Ltd | スルフィド基含有有機ケイ素化合物の製造方法 |
JP2018514579A (ja) * | 2015-05-08 | 2018-06-07 | アーケマ・インコーポレイテッド | 有機ポリスルフィドおよびそれらの塩の製造 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2773799B1 (fr) * | 1998-01-22 | 2000-02-18 | Elf Aquitaine Exploration Prod | Synthese de disulfures et polysulfures organiques |
FR2774984B1 (fr) * | 1998-02-18 | 2000-03-24 | Atochem Elf Sa | Purification du thiophene |
DE19854427A1 (de) * | 1998-11-25 | 2000-05-31 | Basf Ag | Verfahren zur Herstellung von organischen Disulfiden |
FR2808272B1 (fr) | 2000-04-28 | 2002-06-14 | Atofina | Procede de fabrication d'olefines sulfurees |
CN113603656B (zh) * | 2021-10-08 | 2022-03-15 | 科迈化工股份有限公司 | 橡胶硫化促进剂mbts的生产工艺 |
CN115197109B (zh) * | 2022-08-04 | 2024-02-20 | 大连九信精细化工有限公司 | 一种制备3-巯基丙酸甲酯的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH026465A (ja) * | 1988-04-14 | 1990-01-10 | Soc Natl Elf Aquitaine <Snea> | 有機ジスルフィド及びポリスルフィドの製造方法 |
JPH04211645A (ja) * | 1990-03-05 | 1992-08-03 | Soc Natl Elf Aquitaine <Snea> | 二硫化ジメチルの製造方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2237625A (en) * | 1938-10-07 | 1941-04-08 | Sharples Solvents Corp | Sulphurization of sulphur-containing organic conpounds |
DE1250430B (ja) * | 1963-05-20 | |||
US3277180A (en) * | 1964-01-15 | 1966-10-04 | Aquitaine Petrole | Process for the manufacture of organic disulphides |
FR1527462A (fr) * | 1966-06-15 | 1968-05-31 | Mobil Oil Corp | Procédé de préparation de sulfures d'alkyle |
FR1553249A (ja) * | 1967-01-20 | 1969-01-10 |
-
1995
- 1995-12-11 FR FR9514581A patent/FR2742144B1/fr not_active Expired - Fee Related
-
1996
- 1996-12-03 AT AT96941103T patent/ATE199703T1/de not_active IP Right Cessation
- 1996-12-03 CA CA002235714A patent/CA2235714A1/fr not_active Abandoned
- 1996-12-03 DK DK96941103T patent/DK0876312T3/da active
- 1996-12-03 BR BR9611842-3A patent/BR9611842A/pt active Search and Examination
- 1996-12-03 DE DE69612117T patent/DE69612117T2/de not_active Expired - Lifetime
- 1996-12-03 CN CNB961989394A patent/CN1171834C/zh not_active Expired - Fee Related
- 1996-12-03 WO PCT/FR1996/001921 patent/WO1997021649A1/fr not_active Application Discontinuation
- 1996-12-03 IL IL12409496A patent/IL124094A/xx not_active IP Right Cessation
- 1996-12-03 AU AU10357/97A patent/AU703677B2/en not_active Ceased
- 1996-12-03 PT PT96941103T patent/PT876312E/pt unknown
- 1996-12-03 EP EP96941103A patent/EP0876312B1/fr not_active Expired - Lifetime
- 1996-12-03 ES ES96941103T patent/ES2156302T3/es not_active Expired - Lifetime
- 1996-12-03 JP JP52177697A patent/JP3911025B2/ja not_active Expired - Fee Related
- 1996-12-11 US US08/764,012 patent/US5786511A/en not_active Expired - Lifetime
-
2001
- 2001-04-27 GR GR20010400639T patent/GR3035791T3/el not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH026465A (ja) * | 1988-04-14 | 1990-01-10 | Soc Natl Elf Aquitaine <Snea> | 有機ジスルフィド及びポリスルフィドの製造方法 |
JPH04211645A (ja) * | 1990-03-05 | 1992-08-03 | Soc Natl Elf Aquitaine <Snea> | 二硫化ジメチルの製造方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014141428A (ja) * | 2013-01-23 | 2014-08-07 | Shin Etsu Chem Co Ltd | スルフィド基含有有機ケイ素化合物の製造方法 |
JP2018514579A (ja) * | 2015-05-08 | 2018-06-07 | アーケマ・インコーポレイテッド | 有機ポリスルフィドおよびそれらの塩の製造 |
Also Published As
Publication number | Publication date |
---|---|
PT876312E (pt) | 2001-08-30 |
GR3035791T3 (en) | 2001-07-31 |
CA2235714A1 (fr) | 1997-06-19 |
EP0876312B1 (fr) | 2001-03-14 |
ATE199703T1 (de) | 2001-03-15 |
IL124094A (en) | 2003-07-06 |
US5786511A (en) | 1998-07-28 |
WO1997021649A1 (fr) | 1997-06-19 |
AU1035797A (en) | 1997-07-03 |
DE69612117T2 (de) | 2001-08-23 |
AU703677B2 (en) | 1999-04-01 |
ES2156302T3 (es) | 2001-06-16 |
CN1171834C (zh) | 2004-10-20 |
BR9611842A (pt) | 1999-12-28 |
EP0876312A1 (fr) | 1998-11-11 |
DK0876312T3 (da) | 2001-07-16 |
CN1204312A (zh) | 1999-01-06 |
FR2742144A1 (fr) | 1997-06-13 |
JP3911025B2 (ja) | 2007-05-09 |
FR2742144B1 (fr) | 1998-01-16 |
DE69612117D1 (de) | 2001-04-19 |
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