IT997886B - PROCEDURE AND PLANT FOR THE OXIDATION OF HYDROCARBONS - Google Patents

PROCEDURE AND PLANT FOR THE OXIDATION OF HYDROCARBONS

Info

Publication number
IT997886B
IT997886B IT53195/73A IT5319573A IT997886B IT 997886 B IT997886 B IT 997886B IT 53195/73 A IT53195/73 A IT 53195/73A IT 5319573 A IT5319573 A IT 5319573A IT 997886 B IT997886 B IT 997886B
Authority
IT
Italy
Prior art keywords
boric acid
oxidation
liquid phase
gas
water
Prior art date
Application number
IT53195/73A
Other languages
Italian (it)
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19722260114 external-priority patent/DE2260114C3/en
Application filed by Bayer Ag filed Critical Bayer Ag
Application granted granted Critical
Publication of IT997886B publication Critical patent/IT997886B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered

Abstract

1413035 Process for the oxidation of hydrocarbons BAYER AG 19 Oct 1973 [8 Dec 1972] 48827/73 Heading C2C The invention comprises a process for oxidizing a C 4 - to C 20 -hydrocarbon in which the hydrocarbon is reacted with a gas comprising molecular oxygen in the presence of a boron compound; the resulting reaction mixture, containing at least one basic acid ester, is hydrolysed by an aqueous medium containing boric acid; the hydrolysate is separated into a substantially organic component, from which the required oxidation product is obtained, and into a substantially aqueous component, containing boric acid and one or more water-soluble organic secondary products; boric acid is recovered from the aqueous component; the residual boric acid mother liquor, or part thereof, is oxidized in the liquid phase with a gas comprising molecular oxygen at a temperature of at least 200‹ C. and under a pressure sufficient to keep at least some of the water in the liquid phase; and the resulting solution is returned to the hydrolysis medium. The gas for the oxidation of the boric acid mother liquor preferably contains oxygen in at least the stoichiometric quantity sufficient for burning all the organic impurities in a reaction zone heated to at least 200‹ C. under a pressure sufficient to keep at least some of the water in the liquid phase.
IT53195/73A 1972-12-08 1973-10-18 PROCEDURE AND PLANT FOR THE OXIDATION OF HYDROCARBONS IT997886B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19722260114 DE2260114C3 (en) 1972-12-08 Process for the oxidation of hydrocarbons to alcohols and ketones

Publications (1)

Publication Number Publication Date
IT997886B true IT997886B (en) 1975-12-30

Family

ID=5863886

Family Applications (1)

Application Number Title Priority Date Filing Date
IT53195/73A IT997886B (en) 1972-12-08 1973-10-18 PROCEDURE AND PLANT FOR THE OXIDATION OF HYDROCARBONS

Country Status (7)

Country Link
JP (1) JPS524524B2 (en)
BE (1) BE806488A (en)
CS (1) CS175466B2 (en)
FR (1) FR2209737B1 (en)
GB (1) GB1413035A (en)
IT (1) IT997886B (en)
NL (1) NL175169C (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5835051U (en) * 1981-08-31 1983-03-07 日産自動車株式会社 one way valve
JPS6010964U (en) * 1983-06-30 1985-01-25 株式会社　テイエルブイ Disc type check valve

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE787564A (en) * 1971-08-18 1973-02-14 Halcon International Inc OXIDIZATION OF HYDROCARBONS

Also Published As

Publication number Publication date
JPS524524B2 (en) 1977-02-04
NL175169C (en) 1984-10-01
GB1413035A (en) 1975-11-05
JPS4987608A (en) 1974-08-22
DE2260114A1 (en) 1974-06-12
BE806488A (en) 1974-04-25
DE2260114B2 (en) 1977-03-10
FR2209737B1 (en) 1979-05-04
FR2209737A1 (en) 1974-07-05
NL7315022A (en) 1974-06-11
CS175466B2 (en) 1977-05-31
AU6167573A (en) 1975-04-24

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