IT1054583B - Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst - Google Patents

Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst

Info

Publication number
IT1054583B
IT1054583B IT1974876A IT1974876A IT1054583B IT 1054583 B IT1054583 B IT 1054583B IT 1974876 A IT1974876 A IT 1974876A IT 1974876 A IT1974876 A IT 1974876A IT 1054583 B IT1054583 B IT 1054583B
Authority
IT
Italy
Prior art keywords
metal
reacting
pref
partic
vapours
Prior art date
Application number
IT1974876A
Other languages
Italian (it)
Inventor
A Greco
M Corbellini
Original Assignee
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Snam Progetti filed Critical Snam Progetti
Priority to IT1974876A priority Critical patent/IT1054583B/en
Priority to IL51283A priority patent/IL51283A/en
Priority to GR52596A priority patent/GR60862B/en
Priority to ZA77262A priority patent/ZA77262B/en
Priority to AU21472/77A priority patent/AU512820B2/en
Priority to CA000270122A priority patent/CA1118748A/en
Priority to YU230/77A priority patent/YU39988B/en
Priority to CS77451A priority patent/CS208192B2/en
Priority to MW2/77A priority patent/MW277A1/en
Priority to ZM8/77A priority patent/ZM877A1/en
Priority to TR19781A priority patent/TR19781A/en
Priority to DK30877A priority patent/DK147620C/en
Priority to EG51/77A priority patent/EG13429A/en
Priority to AR266342A priority patent/AR217821A1/en
Priority to FR7702334A priority patent/FR2345467A1/en
Priority to HU7SA3009A priority patent/HU175166B/en
Priority to RO7789154A priority patent/RO72499A/en
Priority to GB3437/77A priority patent/GB1576431A/en
Priority to NO770274A priority patent/NO150208C/en
Priority to CH108477A priority patent/CH628597A5/en
Priority to DE2703604A priority patent/DE2703604C3/en
Priority to PT66123A priority patent/PT66123B/en
Priority to BE174487A priority patent/BE850878A/en
Priority to JP52007909A priority patent/JPS6050806B2/en
Priority to DD7700197143A priority patent/DD130130A5/en
Priority to ES455759A priority patent/ES455759A1/en
Priority to IE189/77A priority patent/IE45018B1/en
Priority to MX167866A priority patent/MX142961A/en
Priority to SE7700926A priority patent/SE439638B/en
Priority to SU772446350A priority patent/SU1056905A3/en
Priority to DE2759512A priority patent/DE2759512C2/en
Priority to LU76666A priority patent/LU76666A1/xx
Priority to AT55077A priority patent/AT359042B/en
Priority to PH19393A priority patent/PH15890A/en
Priority to DD77205331A priority patent/DD138218A5/en
Priority to PL1977195656A priority patent/PL106893B1/en
Priority to IN133/CAL/77A priority patent/IN145866B/en
Priority to NLAANVRAGE7701005,A priority patent/NL172329C/en
Priority to FR7718179A priority patent/FR2345212A1/en
Priority to IN795/CAL/78A priority patent/IN146150B/en
Priority to US05/926,518 priority patent/US4194992A/en
Priority to CS7998A priority patent/CS208194B2/en
Priority to AT370179A priority patent/AT368174B/en
Priority to DK458580A priority patent/DK156481C/en
Priority to NO810263A priority patent/NO152562C/en
Application granted granted Critical
Publication of IT1054583B publication Critical patent/IT1054583B/en
Priority to YU1658/82A priority patent/YU44359B/en
Priority to YU1657/82A priority patent/YU44358B/en
Priority to MY212/82A priority patent/MY8200212A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/002—Compounds containing, besides titanium, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/02—Halides of titanium
    • C01G23/026—Titanium trichloride
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G31/00—Compounds of vanadium
    • C01G31/006—Compounds containing, besides vanadium, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G37/00—Compounds of chromium
    • C01G37/006—Compounds containing, besides chromium, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/10—Solid density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

TiCl3 and VCl3 are prepd. by vaporising a metal (I) under vacuum and reacting the vapours with MCl4, (where M is Ti or V) at low temps. Vapourisation is pref. effected under a vacuum of 10-1-10-6 mm Hg and reaction is pref. at -80 to +20 degrees C. The metal (I) is pref. Al, Mg, Cr, Mn, Fe, V and Ti. Reaction between metal vapours and MCl4 is pref. effected in presence of an inert diluent chosen from (un)satd. aliphatic hydrocarbons and halogenated hydrocarbon. The process is partic. for reacting Mg vapours with TiCl4 to obtain a catalyst component (II) to be used in conjunction with an organometallic Al cpd. for the (co)polymn. of alpha-olefins. (I) may be any metal i.e. transition or other metal, so that catalysts having different activities can be prepd. The catalysts have high activities (e.g. 230kg polymer per g. Ti per hr.) and need not be sepd. from the polymers. The polymers are obtd. in high yields, are morphologically homogenous, have adjustable mol. wts. and can also be obtd. in gaseous phase with high yields.
IT1974876A 1976-01-30 1976-01-30 Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst IT1054583B (en)

Priority Applications (48)

Application Number Priority Date Filing Date Title
IT1974876A IT1054583B (en) 1976-01-30 1976-01-30 Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst
IL51283A IL51283A (en) 1976-01-30 1977-01-18 Process for preparing a co-catalyst for use in the polymerization of a-olefins,a co-catalyst prepared by the process,a catalytic system comprising such a co-catalyst and a process for polymerizing an a-olefin using such catalytic system
GR52596A GR60862B (en) 1976-01-30 1977-01-18 Process for olephines polymerization and compositions suitable for the polymerization
ZA77262A ZA77262B (en) 1976-01-30 1977-01-18 Method for the polymerization of olephins and means suitable thereto
AU21472/77A AU512820B2 (en) 1976-01-30 1977-01-20 Production of co-catalyst forthe polymerisation of olefins
CA000270122A CA1118748A (en) 1976-01-30 1977-01-20 Titanium and vanadium trichloride catalysts for polymerization of olephins
YU230/77A YU39988B (en) 1976-01-30 1977-01-23 Process for obtaining catalysts for polymerization of olefines consisting of titanium or vanadium trichloride comprising metal chlorides
CS77451A CS208192B2 (en) 1976-01-30 1977-01-24 Method of preparation of the titanium and vanadium chloride
MW2/77A MW277A1 (en) 1976-01-30 1977-01-25 Method for the polymerization of olephins and means suitable thereto
ZM8/77A ZM877A1 (en) 1976-01-30 1977-01-25 Method for the polymerisation of olephins and means suitable thereto
TR19781A TR19781A (en) 1976-01-30 1977-01-25 PREPARATION METHOD OF TITAN AND VANADIUM TRICHLORES AND THE PRODUCTS OBTAINED IN THIS HOW
DK30877A DK147620C (en) 1976-01-30 1977-01-25 METHOD OF PREPARING METAL CHLORIDE MIXTURES CONTAINING TITAN OR VANADIUM TRICHLORIDE
EG51/77A EG13429A (en) 1976-01-30 1977-01-26 Method for the polymerization of olephines and means adapted thereto
AR266342A AR217821A1 (en) 1976-01-30 1977-01-27 PROCEDURE FOR THE PREPARATION OF A CATALYST BASED ON TITANIUM TRICHLORIDE, OR VANADIUM AND CATALYTIC COMPOSITION AND PROCEDURE FOR HIGH PERFORMANCE POLYMERIZATION OF ALPHA OLEPHINE
FR7702334A FR2345467A1 (en) 1976-01-30 1977-01-27 PROCESS FOR THE POLYMERIZATION OF OLEFINS, APPROPRIATE MEANS FOR PERFORMING THIS POLYMERIZATION, AND PROCESS FOR MANUFACTURING THESE MEANS
HU7SA3009A HU175166B (en) 1976-01-30 1977-01-27 Process for producing titane- or vanadiumtrichloride-containing catalyst-component
RO7789154A RO72499A (en) 1976-01-30 1977-01-27 PROCESS FOR OBTAINING DUCTS OF DUTY HALOGENS OF TITAN OR VANADIUM
GB3437/77A GB1576431A (en) 1976-01-30 1977-01-27 Catalyst its production and use in polymerization of olefins
NO770274A NO150208C (en) 1976-01-30 1977-01-27 PROCEDURE FOR THE PREPARATION OF TITAN OR VANADIUM TRICHLORIDE-METAL CHLORIDE MIXTURES FOR USE IN POLYMERIZATION CATALYST SYSTEMS
CH108477A CH628597A5 (en) 1976-01-30 1977-01-28 Process for preparing trichlorides of titanium and vanadium for use in catalytic systems for the polymerisation of olefins
DE2703604A DE2703604C3 (en) 1976-01-30 1977-01-28 Process for the production of titanium or vanadium trichloride-containing metal chloride mixtures and their use in polymerization catalysts for olefins
PT66123A PT66123B (en) 1976-01-30 1977-01-28 Process for the preparation of a novel catalytic composition and application of said catalytic composition to the polymerization of olephines
BE174487A BE850878A (en) 1976-01-30 1977-01-28 IMPROVEMENTS IN THE POLYMERIZATION OF OLEFINS
JP52007909A JPS6050806B2 (en) 1976-01-30 1977-01-28 New catalyst composition
DD7700197143A DD130130A5 (en) 1976-01-30 1977-01-28 PROCESS FOR PREPARING TITANIUM AND VANADIUM TRICHLORIDES
ES455759A ES455759A1 (en) 1976-01-30 1977-01-28 Catalyst its production and use in polymerization of olefins
IE189/77A IE45018B1 (en) 1976-01-30 1977-01-28 Catalyst, its production and use in polymerization of olefins
MX167866A MX142961A (en) 1976-01-30 1977-01-28 IMPROVEMENTS TO A METHOD FOR PREPARING A CATALYST CONTAINING TICL3 OR VCL3 FOR THE POLYMERIZATION AND COPOLYMERIZATION OF ETHYLENE
SE7700926A SE439638B (en) 1976-01-30 1977-01-28 PROCEDURE FOR HOMO OR COPOLYMERIZATION OF ONE AND CATALYST COMPOSITION CONTAINING AN MG AND TI-CONTENT SUBSTANCE FOR USE THEREOF
SU772446350A SU1056905A3 (en) 1976-01-30 1977-01-28 Method for preparing catalyst of polymerization of olefins
DE2759512A DE2759512C2 (en) 1976-01-30 1977-01-28 Titanium-containing catalyst and its use in combination with an organoaluminum compound for the polymerization of α-olefins
LU76666A LU76666A1 (en) 1976-01-30 1977-01-28
AT55077A AT359042B (en) 1976-01-30 1977-01-28 METHOD FOR PRODUCING TITANIUM AND VANADIUM TRICHLORIDES
PH19393A PH15890A (en) 1976-01-30 1977-01-28 Method for preparing a catalyst useful in the polymerization of olefins
DD77205331A DD138218A5 (en) 1976-01-30 1977-01-28 CATALYST COMPOSITION AND USE IN OLEFIN POLYMERIZATION
PL1977195656A PL106893B1 (en) 1976-01-30 1977-01-29 METHOD OF MANUFACTURE OF TITANIUM AND Vanadium Triethylchloride
IN133/CAL/77A IN145866B (en) 1976-01-30 1977-01-29
NLAANVRAGE7701005,A NL172329C (en) 1976-01-30 1977-01-31 PROCESS FOR THE PREPARATION OF A CATALYST COMPONENT FOR THE POLYMERIZATION OF ALFA-OLEFINS, PROCESS FOR PREPARATION OF A CATALYST SYSTEM, PROCESS FOR THE POLYMERIZATION OF ALPHENES AND FOR PREPARED PREPARATION OF ALKES.
FR7718179A FR2345212A1 (en) 1976-01-30 1977-06-14 PROCESS FOR THE PREPARATION OF TITANIUM TRICHLORIDE AND VANADIUM TRICHLORIDE
IN795/CAL/78A IN146150B (en) 1976-01-30 1978-07-19
US05/926,518 US4194992A (en) 1976-01-30 1978-07-20 Method for the polymerization of olefines and means suitable thereto
CS7998A CS208194B2 (en) 1976-01-30 1979-01-03 Catalytic mixture for polymeration of the alpha-olefins
AT370179A AT368174B (en) 1976-01-30 1979-05-18 METHOD FOR POLYMERIZING OLEFINS
DK458580A DK156481C (en) 1976-01-30 1980-10-29 TITANIC CATALYST AND USE OF THIS COMBINED WITH AN ALUMINUM ORGANIC COMPOUND FOR POLYMERIZATION OF ALFA OLEFINES
NO810263A NO152562C (en) 1976-01-30 1981-01-27 PROCEDURE FOR POLYMERIZATION AND CO-POLYMERIZATION OF OLEFINES
YU1658/82A YU44359B (en) 1976-01-30 1982-07-29 Process for the polymerization of alpha-olefines
YU1657/82A YU44358B (en) 1976-01-30 1982-07-29 Process for obtaining catalyst for the polymerization of alpha-olefines
MY212/82A MY8200212A (en) 1976-01-30 1982-12-30 C atalyst its production and use in polymerization of olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1974876A IT1054583B (en) 1976-01-30 1976-01-30 Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst

Publications (1)

Publication Number Publication Date
IT1054583B true IT1054583B (en) 1981-11-30

Family

ID=11160895

Family Applications (1)

Application Number Title Priority Date Filing Date
IT1974876A IT1054583B (en) 1976-01-30 1976-01-30 Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst

Country Status (11)

Country Link
AT (1) AT359042B (en)
BE (1) BE850878A (en)
CS (1) CS208192B2 (en)
HU (1) HU175166B (en)
IT (1) IT1054583B (en)
MW (1) MW277A1 (en)
PL (1) PL106893B1 (en)
RO (1) RO72499A (en)
SE (1) SE439638B (en)
ZA (1) ZA77262B (en)
ZM (1) ZM877A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1137631B (en) * 1981-07-29 1986-09-10 Anic Spa PROCEDURE FOR HIGH YIELD POLYMERIZATION AND COPOLYMERIZATION OF HYDRAULICALLY UNSATURATED COMPOUNDS AND MEDIA SUITABLE FOR SOCPO

Also Published As

Publication number Publication date
PL106893B1 (en) 1980-01-31
SE7700926L (en) 1977-07-31
HU175166B (en) 1980-05-28
ATA55077A (en) 1980-03-15
MW277A1 (en) 1978-05-10
SE439638B (en) 1985-06-24
CS208192B2 (en) 1981-08-31
ZM877A1 (en) 1977-09-21
BE850878A (en) 1977-07-28
AT359042B (en) 1980-10-10
RO72499A (en) 1980-12-30
ZA77262B (en) 1977-11-30

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Effective date: 19950216