GB1484086A - Titanium trichloride catalyst component - Google Patents

Titanium trichloride catalyst component

Info

Publication number
GB1484086A
GB1484086A GB25016/75A GB2501675A GB1484086A GB 1484086 A GB1484086 A GB 1484086A GB 25016/75 A GB25016/75 A GB 25016/75A GB 2501675 A GB2501675 A GB 2501675A GB 1484086 A GB1484086 A GB 1484086A
Authority
GB
United Kingdom
Prior art keywords
ticl
propylene
olefin
violet
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25016/75A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB25016/75A priority Critical patent/GB1484086A/en
Priority to BE1007430A priority patent/BE842591A/en
Priority to NL7606139A priority patent/NL7606139A/en
Priority to FR7617360A priority patent/FR2313979A1/en
Priority to BR3688/76A priority patent/BR7603688A/en
Priority to DE19762625858 priority patent/DE2625858A1/en
Priority to ZA763417A priority patent/ZA763417B/en
Priority to AU14762/76A priority patent/AU496720B2/en
Priority to NO761969A priority patent/NO142993C/en
Priority to IT49851/76A priority patent/IT1061335B/en
Priority to JP51067555A priority patent/JPS51149897A/en
Priority to SE7606512A priority patent/SE7606512L/en
Publication of GB1484086A publication Critical patent/GB1484086A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/02—Halides of titanium
    • C01G23/026—Titanium trichloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1484086 Olefin polymerization catalysts SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 9 June 1976 [11 June 1975 26 Nov 1975] 25016/75 Heading C3P [Also in Division C1] Olefins are polymerized in the presence of violet TiCl 3 as catalyst together with a dialkyl aluminium halide as activator, said violet TiCl 3 being made by heating brown TiCl 3 in the presence of a halogenated aliphatic or aromatic hydrocarbon (see Division C1). If desired, before polymerization, the violet TiCl 3 together with some or all of the activator may be prepolymerized with a small amount of the olefin. The process is particularly applicable to the homopolymerization of propylene and the copolymerization of ethylene and propylene. The polymerization is typically carried out in an inert liquid, in the vapour phase or in the liquid olefin monomer, In the examples TiCl 4 is reduced with triethyl aluminium, heated with nbutyl- or n-octyl-chloride or CCl 4 and n-ootylchloride and used with diethyl aluminium chloride to polymerize propylene in n-octane in the presence of hydrogen.
GB25016/75A 1975-06-11 1975-06-11 Titanium trichloride catalyst component Expired GB1484086A (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
GB25016/75A GB1484086A (en) 1975-06-11 1975-06-11 Titanium trichloride catalyst component
BE1007430A BE842591A (en) 1975-06-11 1976-06-04 PROCESS FOR PREPARING VIOLET TIC13,
NL7606139A NL7606139A (en) 1975-06-11 1976-06-08 PROCESS FOR PREPARING VIOLET TIC13.
FR7617360A FR2313979A1 (en) 1975-06-11 1976-06-09 Violet titanium trichloride for olefin polymerisation - by heating brown form with an organic halo cpd.
BR3688/76A BR7603688A (en) 1975-06-11 1976-06-09 PROCESS TO PREPARE VIOLET TICI3
DE19762625858 DE2625858A1 (en) 1975-06-11 1976-06-09 PROCESS FOR THE PRODUCTION OF VIOLET TITANIUM TRICHLORIDE
ZA763417A ZA763417B (en) 1975-06-11 1976-06-09 Titanium trichloride catalyst component
AU14762/76A AU496720B2 (en) 1975-06-11 1976-06-09 Titanium trichloride catalyst component
NO761969A NO142993C (en) 1975-06-11 1976-06-09 PROCEDURE FOR THE PREPARATION OF Violet TICL3
IT49851/76A IT1061335B (en) 1975-06-11 1976-06-09 PROCEDURE FOR TREATING TI.CL.3 USABLE IN THE POLYMERIZATION OF OLEFINE
JP51067555A JPS51149897A (en) 1975-06-11 1976-06-09 Manufacturing process for catalytic compnent of titanium trichloride
SE7606512A SE7606512L (en) 1975-06-11 1976-06-09 TITANTRICHLORIDE CATALYST COMPONENT

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB25016/75A GB1484086A (en) 1975-06-11 1975-06-11 Titanium trichloride catalyst component

Publications (1)

Publication Number Publication Date
GB1484086A true GB1484086A (en) 1977-08-24

Family

ID=10220859

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25016/75A Expired GB1484086A (en) 1975-06-11 1975-06-11 Titanium trichloride catalyst component

Country Status (4)

Country Link
BE (1) BE842591A (en)
GB (1) GB1484086A (en)
SE (1) SE7606512L (en)
ZA (1) ZA763417B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0011914A1 (en) * 1978-09-26 1980-06-11 Exxon Research And Engineering Company Titanium trichloride catalyst composition and its use in the polymerization of alpha-olefins
US4240928A (en) 1976-03-08 1980-12-23 Toa Nenryo Kogyo Kabushiki Kaisha Titanium trichloride catalyst and process for the production thereof
US4431569A (en) * 1979-12-12 1984-02-14 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
US4434081A (en) 1980-02-13 1984-02-28 Toyo Stauffer Chemical Co., Ltd. Titanium trichloride catalytic component and homo- or co-polymerization of α-olefin
US4543400A (en) * 1978-09-26 1985-09-24 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4240928A (en) 1976-03-08 1980-12-23 Toa Nenryo Kogyo Kabushiki Kaisha Titanium trichloride catalyst and process for the production thereof
EP0011914A1 (en) * 1978-09-26 1980-06-11 Exxon Research And Engineering Company Titanium trichloride catalyst composition and its use in the polymerization of alpha-olefins
US4543400A (en) * 1978-09-26 1985-09-24 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
US4431569A (en) * 1979-12-12 1984-02-14 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
US4434081A (en) 1980-02-13 1984-02-28 Toyo Stauffer Chemical Co., Ltd. Titanium trichloride catalytic component and homo- or co-polymerization of α-olefin

Also Published As

Publication number Publication date
SE7606512L (en) 1976-12-12
ZA763417B (en) 1977-05-25
BE842591A (en) 1976-12-06

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee