ES455759A1 - Catalyst its production and use in polymerization of olefins - Google Patents
Catalyst its production and use in polymerization of olefinsInfo
- Publication number
- ES455759A1 ES455759A1 ES455759A ES455759A ES455759A1 ES 455759 A1 ES455759 A1 ES 455759A1 ES 455759 A ES455759 A ES 455759A ES 455759 A ES455759 A ES 455759A ES 455759 A1 ES455759 A1 ES 455759A1
- Authority
- ES
- Spain
- Prior art keywords
- metal
- olefins
- mcl4
- trichlorides
- vaporised
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/002—Compounds containing, besides titanium, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/02—Halides of titanium
- C01G23/026—Titanium trichloride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
- C01G31/006—Compounds containing, besides vanadium, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G37/00—Compounds of chromium
- C01G37/006—Compounds containing, besides chromium, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/04—Compounds with a limited amount of crystallinty, e.g. as indicated by a crystallinity index
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
For the preparation of the trichlorides of titanium and vanadium, a metal is vaporised in vacuo and the vapour thus obtained is reacted at low temperature with MCl4, M being Ti or V. The vaporisation of the metal takes place in a vacuum of between 10<-1> and 10<-6> mm Hg, and the reaction of the metallic vapours and MCl4 takes place at temperatures of between -80 and +20 DEG C in the presence of an inert diluent selected from saturated or unsaturated aliphatic hydrocarbons or from halogenated hydrocarbons. The metal to be vaporised is preferably selected from the group comprising Al, Mg, Cr, Mn, Fe, V and Ti. The trichlorides thus obtained and an organometallic aluminium compound are used in catalytic compositions for the polymerisation of alpha-olefins in high yield.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1974876A IT1054583B (en) | 1976-01-30 | 1976-01-30 | Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst |
| IT2525776A IT1065073B (en) | 1976-07-13 | 1976-07-13 | Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES455759A1 true ES455759A1 (en) | 1978-01-01 |
Family
ID=26327289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES455759A Expired ES455759A1 (en) | 1976-01-30 | 1977-01-28 | Catalyst its production and use in polymerization of olefins |
Country Status (26)
| Country | Link |
|---|---|
| JP (1) | JPS6050806B2 (en) |
| AR (1) | AR217821A1 (en) |
| AU (1) | AU512820B2 (en) |
| CA (1) | CA1118748A (en) |
| CH (1) | CH628597A5 (en) |
| DD (2) | DD138218A5 (en) |
| DE (2) | DE2759512C2 (en) |
| DK (1) | DK147620C (en) |
| EG (1) | EG13429A (en) |
| ES (1) | ES455759A1 (en) |
| FR (2) | FR2345467A1 (en) |
| GB (1) | GB1576431A (en) |
| GR (1) | GR60862B (en) |
| IE (1) | IE45018B1 (en) |
| IL (1) | IL51283A (en) |
| IN (1) | IN145866B (en) |
| LU (1) | LU76666A1 (en) |
| MX (1) | MX142961A (en) |
| MY (1) | MY8200212A (en) |
| NL (1) | NL172329C (en) |
| NO (2) | NO150208C (en) |
| PH (1) | PH15890A (en) |
| PT (1) | PT66123B (en) |
| SU (1) | SU1056905A3 (en) |
| TR (1) | TR19781A (en) |
| YU (3) | YU39988B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1081277B (en) * | 1977-06-30 | 1985-05-16 | Snam Progetti | CHEMICAL COMPOSITIONS BASED ON TRIALHYGEN TITANIUM PROCEDURE FOR THEIR PREPARATION AND USE |
| IT1080687B (en) * | 1977-06-30 | 1985-05-16 | Snam Progetti | TRIALHYGEN TITANIUM-BASED CHEMICAL COMPOSITIONS, PROCEDURE FOR THEIR PREPARATION AND USE |
| IT1113421B (en) * | 1979-03-07 | 1986-01-20 | Anic Spa | METHOD FOR THE REDUCTION OF METALLIC ALCOXIDS AND USE OF THE COMPOUNDS SO OBTAINED |
| IT1130243B (en) * | 1980-02-01 | 1986-06-11 | Anic Spa | CHEMICAL COMPOSITION BASED ON TRIALHYGEN TITANIUM, METHOD FOR ITS PREPARATION AND PROCESS OF POLYMERIZATION OR COPOLYMERISATION OF UNSATURATED COMPOUNDS USING THE SAME |
| IT1137631B (en) * | 1981-07-29 | 1986-09-10 | Anic Spa | PROCEDURE FOR HIGH YIELD POLYMERIZATION AND COPOLYMERIZATION OF HYDRAULICALLY UNSATURATED COMPOUNDS AND MEDIA SUITABLE FOR SOCPO |
| IT1210855B (en) * | 1982-02-12 | 1989-09-29 | Assoreni Ora Enichem Polimeri | LINEAR STRUCTURE ETHYLENE POLYMERS AND PROCESSES FOR THEIR PREPARATION. |
| FR3033565B1 (en) | 2015-03-09 | 2017-03-24 | Centre Nat Rech Scient | IRON PRECATALYST AND USE THEREOF IN THE POLYMERIZATION OF OLEFINS |
| RU2707362C1 (en) * | 2019-04-05 | 2019-11-26 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) | Method of producing titanium trichloride |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3109822A (en) * | 1963-11-05 | catalyst composition | ||
| DE1302122C2 (en) * | 1954-12-03 | 1979-09-13 | Montecatini Edison S.pA, Mailand (Italien); Ziegler, Karl, Dr.Dr.eh, 4330 Mülheim | METHOD FOR MANUFACTURING LINEAR HEAD-TAIL POLYPROPYLENE OR -POL-ALPHA- BUTYLENE |
| NL215885A (en) * | 1956-04-02 | |||
| AT218733B (en) * | 1957-05-28 | 1961-12-27 | Titan Gmbh | Process for the production of a new, homogeneous, anhydrous aluminum-titanium-chlorine compound |
| DE1168876B (en) * | 1962-04-28 | 1964-04-30 | Basf Ag | Process for the preparation of a complex compound of titanium trichloride and aluminum chloride |
| DE1268598B (en) * | 1964-03-04 | 1968-05-22 | Rexall Drug Chemical | Process for the preparation of a catalyst for the polymerization of alpha-olefins |
| DE1229050B (en) * | 1965-01-13 | 1966-11-24 | Basf Ag | Process for the preparation of a catalyst component which is particularly active in the polymerization of propylene using Ziegler catalysts |
| GB1299862A (en) * | 1969-01-23 | 1972-12-13 | Shell Int Research | Improvements in or relating to the catalytic polymerisation of olefins |
| GB1359547A (en) * | 1970-12-04 | 1974-07-10 | Naphtachimie Sa | Based catalysts |
| BE785673A (en) * | 1971-06-30 | 1973-01-02 | Naphtachimie Sa | POLYMERIZATION CATALYZERS OF OLEFINS PREPARED FROM DECOMPOSED ORGANOMAGNESIANS |
| DE2158956A1 (en) * | 1971-11-27 | 1973-05-30 | Basf Ag | Prepn of violet titanium trichloride - by plasma chemical conversion of titanium tetrachloride |
| BE794323A (en) * | 1972-01-20 | 1973-07-19 | Naphtachimie Sa | PROCESS FOR THE MANUFACTURE OF ATACTIC POLYOLEFIN WAXES |
| IT998599B (en) * | 1972-09-18 | 1976-02-20 | Naphtachimie Sa | PROCEDURE OF POLYMERIZATION OF OLEFINS USING PRE ACTIVATED CATALYSTS |
| GB1467051A (en) * | 1974-01-03 | 1977-03-16 | Shell Int Research | Process for the production of polyolefins and catalyst therefor |
| JPS5724361B2 (en) * | 1974-03-27 | 1982-05-24 | ||
| IL46858A (en) * | 1974-04-17 | 1979-01-31 | Snam Progetti | Process for the polymerization of alpha-olefins,catalyst employed in said process and method for the preparation thereof |
-
1977
- 1977-01-18 GR GR52596A patent/GR60862B/en unknown
- 1977-01-18 IL IL51283A patent/IL51283A/en unknown
- 1977-01-20 CA CA000270122A patent/CA1118748A/en not_active Expired
- 1977-01-20 AU AU21472/77A patent/AU512820B2/en not_active Expired
- 1977-01-23 YU YU230/77A patent/YU39988B/en unknown
- 1977-01-25 DK DK30877A patent/DK147620C/en not_active IP Right Cessation
- 1977-01-25 TR TR19781A patent/TR19781A/en unknown
- 1977-01-26 EG EG51/77A patent/EG13429A/en active
- 1977-01-27 AR AR266342A patent/AR217821A1/en active
- 1977-01-27 NO NO770274A patent/NO150208C/en unknown
- 1977-01-27 GB GB3437/77A patent/GB1576431A/en not_active Expired
- 1977-01-27 FR FR7702334A patent/FR2345467A1/en active Granted
- 1977-01-28 PT PT66123A patent/PT66123B/en unknown
- 1977-01-28 MX MX167866A patent/MX142961A/en unknown
- 1977-01-28 JP JP52007909A patent/JPS6050806B2/en not_active Expired
- 1977-01-28 PH PH19393A patent/PH15890A/en unknown
- 1977-01-28 DE DE2759512A patent/DE2759512C2/en not_active Expired
- 1977-01-28 DE DE2703604A patent/DE2703604C3/en not_active Expired
- 1977-01-28 LU LU76666A patent/LU76666A1/xx unknown
- 1977-01-28 DD DD77205331A patent/DD138218A5/en unknown
- 1977-01-28 DD DD7700197143A patent/DD130130A5/en unknown
- 1977-01-28 SU SU772446350A patent/SU1056905A3/en active
- 1977-01-28 CH CH108477A patent/CH628597A5/en not_active IP Right Cessation
- 1977-01-28 ES ES455759A patent/ES455759A1/en not_active Expired
- 1977-01-28 IE IE189/77A patent/IE45018B1/en not_active IP Right Cessation
- 1977-01-29 IN IN133/CAL/77A patent/IN145866B/en unknown
- 1977-01-31 NL NLAANVRAGE7701005,A patent/NL172329C/en not_active IP Right Cessation
- 1977-06-14 FR FR7718179A patent/FR2345212A1/en active Granted
-
1981
- 1981-01-27 NO NO810263A patent/NO152562C/en unknown
-
1982
- 1982-07-29 YU YU1657/82A patent/YU44358B/en unknown
- 1982-07-29 YU YU1658/82A patent/YU44359B/en unknown
- 1982-12-30 MY MY212/82A patent/MY8200212A/en unknown
Also Published As
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