IT1034845B - Procedimento per la preparazione di ossalati dialchilici - Google Patents

Procedimento per la preparazione di ossalati dialchilici

Info

Publication number
IT1034845B
IT1034845B IT21999/75A IT2199975A IT1034845B IT 1034845 B IT1034845 B IT 1034845B IT 21999/75 A IT21999/75 A IT 21999/75A IT 2199975 A IT2199975 A IT 2199975A IT 1034845 B IT1034845 B IT 1034845B
Authority
IT
Italy
Prior art keywords
procedure
preparation
dialkyl oxalates
oxalates
dialkyl
Prior art date
Application number
IT21999/75A
Other languages
English (en)
Original Assignee
Ube Industries
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP3801074A external-priority patent/JPS557418B2/ja
Priority claimed from JP49072251A external-priority patent/JPS516916A/ja
Application filed by Ube Industries filed Critical Ube Industries
Application granted granted Critical
Publication of IT1034845B publication Critical patent/IT1034845B/it

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/122—Halides of copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
IT21999/75A 1974-04-05 1975-04-04 Procedimento per la preparazione di ossalati dialchilici IT1034845B (it)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP3801074A JPS557418B2 (it) 1974-04-05 1974-04-05
JP49072251A JPS516916A (en) 1974-06-26 1974-06-26 Shusanjesuteruno seizohoho

Publications (1)

Publication Number Publication Date
IT1034845B true IT1034845B (it) 1979-10-10

Family

ID=26377188

Family Applications (1)

Application Number Title Priority Date Filing Date
IT21999/75A IT1034845B (it) 1974-04-05 1975-04-04 Procedimento per la preparazione di ossalati dialchilici

Country Status (7)

Country Link
US (1) US3994960A (it)
CA (1) CA1067093A (it)
DE (1) DE2514685B2 (it)
FR (1) FR2266690B1 (it)
GB (1) GB1451764A (it)
IT (1) IT1034845B (it)
NL (1) NL172147B (it)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1028419B (it) * 1975-01-17 1979-01-30 Montedison Spa Processo per la preparazione di acido ossalico e suoi esteeri
US3992436A (en) * 1976-01-02 1976-11-16 Atlantic Richfield Company Synthesis of oxalate esters from carbon monoxide and carboxylic ortho esters
US4005131A (en) * 1976-01-02 1977-01-25 Atlantic Richfield Company Synthesis of oxalate esters from carbon monoxide and acetals or ketals
US4065490A (en) * 1976-03-22 1977-12-27 Atlantic Richfield Company Process for the preparation of oxalate esters from carbon monoxide and an enol ether
US4160107A (en) * 1976-04-12 1979-07-03 Montedison S.P.A. Process for the preparation of esters of oxalic acid
NL171698C (nl) * 1976-05-13 1983-05-02 Atlantic Richfield Co Werkwijze voor de bereiding van oxaalzuuresters.
US4041068A (en) * 1976-06-29 1977-08-09 Atlantic Richfield Company Synthesis of oxalate esters by catalytic oxidative carbonylation of borate esters
US4041067A (en) * 1976-07-21 1977-08-09 Atlantic Richfield Company Synthesis of oxalate esters by the oxidative carbonylation of amide acetals
JPS5315313A (en) * 1976-07-27 1978-02-13 Ube Ind Ltd Production of oxalic acid diesters
US4069388A (en) * 1976-10-22 1978-01-17 Atlantic Richfield Company Preparation of oxalate esters from carbon monoxide and an alkoxycycloalkene
IT1078033B (it) * 1977-04-07 1985-05-08 Snam Progetti Processo per la preparazione di esteri dell'acido ossalico
US4614832A (en) * 1979-12-17 1986-09-30 Chevron Research Company Dialkyl oxalates from carbon monoxide and an alcohol
US4379939A (en) * 1980-04-04 1983-04-12 Tennessee Valley Authority Preparation of nitrogen fertilizers from oxalate esters prepared by the oxidative carbonylation of alcohols over noble metal catalysts utilizing regenerable 2,5-cyclohexadiene-1,4-dione oxidants
US4281174A (en) * 1980-04-21 1981-07-28 Chevron Research Company Oxidative carbonylation of alcohols to produce dialkyl oxalates
US4571435A (en) * 1980-06-30 1986-02-18 Tennessee Valley Authority Preparation of nitrogen fertilizers from oxalate esters prepared by the oxidative carbonylation of alcohols over noble metal catalysts utilizing regenerable 2,5-cyclohexadiene-1,4-dione oxidants
JPS57114551A (en) * 1981-01-08 1982-07-16 Ube Ind Ltd Preparation of formic acid ester
US4431839A (en) * 1981-12-09 1984-02-14 E. I. Du Pont De Nemours And Company Toluic acid
US4523029A (en) * 1982-06-15 1985-06-11 Chevron Research Company Oxidative carbonylation of alcohols to produce dialkyl oxalates
US4468523A (en) * 1982-06-16 1984-08-28 Atlantic Richfield Company Synthesis of dialkyl oxalates by the heterogeneously catalyzed oxidative carbonylation of alcohols
US4454342A (en) * 1982-07-13 1984-06-12 Atlantic Richfield Company Preparation of dialkyl oxalates using a heterogeneous Pd-V-P catalyst for the oxidative carbonylation of alcohols
US4447638A (en) * 1982-08-02 1984-05-08 Atlantic Richfield Company Preparation of dialkyl oxalates by the oxidative carbonylation of alcohols with a heterogeneous Pd-V-P-Ti containing catalyst system
US4447639A (en) * 1982-08-06 1984-05-08 Atlantic Richfield Company Oxidative carbonylation of alcohols to dialkyl oxalates using a heterogeneous iron promoted Pd-V-P catalyst
US4451666A (en) * 1982-08-06 1984-05-29 Atlantic Richfield Company Synthesis of oxalate esters by the oxidative carbonylation of alcohols with a heterogeneous manganese promoted Pd-V-P catalyst
JPS5982233A (ja) * 1982-11-01 1984-05-12 Hitachi Ltd アンロ−ダの運転方法
CA1213607A (en) * 1982-12-15 1986-11-04 George E. Morris Process for the production of dihydrocarbyl oxalates
US5093513A (en) * 1983-06-20 1992-03-03 Texaco Inc. Process for oxycarbonylation of lower alkanols
DE3342291A1 (de) * 1983-11-23 1985-05-30 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung von oxalsaeurediestern
US4544507A (en) * 1984-02-06 1985-10-01 Celanese Corporation Production of carbonate diesters from oxalate diesters
DE3513255A1 (de) * 1985-04-13 1986-10-23 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung von oxalsaeurediestern
US4689422A (en) * 1985-12-27 1987-08-25 Texaco Inc. Novel ligand catalyst systems formed by reaction of carbonyl compounds with organosilicon compounds
US5089650A (en) * 1986-09-12 1992-02-18 Daicel Chemical Industries, Ltd. Process for producing carbonic acid ester
GB2216036A (en) * 1988-03-31 1989-10-04 Shell Int Research Process and catalyst for the carbo-amination or carbo-amidation of olefins
US5142086A (en) * 1991-04-01 1992-08-25 General Electric Company Method for making organic carbonates
DE69210338T2 (de) * 1991-09-17 1996-12-05 Mitsubishi Chem Corp Verfahren zur Herstellung eines Esters der Kohlensäure
US5391803A (en) * 1992-09-30 1995-02-21 The Dow Chemical Company Production of dimethyl carbonate using copper zeolite catalysts
EP0927711A4 (en) 1997-03-11 2004-12-08 Daicel Chem ADAMANT DERIVATIVES AND METHOD FOR THEIR PRODUCTION
US6235851B1 (en) * 1997-05-23 2001-05-22 Daicel Chemical Industries, Ltd. Polymerizable adamantane derivatives and process for producing the same
CN110064420B (zh) * 2018-01-23 2021-11-30 中国石油天然气股份有限公司 一种氧化态连续重整催化剂及其制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2213435A1 (de) * 1972-03-20 1973-10-11 Roehm Gmbh Verfahren zur herstellung von oxalsaeure und estern dieser saeure

Also Published As

Publication number Publication date
FR2266690A1 (it) 1975-10-31
DE2514685A1 (de) 1975-10-16
GB1451764A (en) 1976-10-06
NL172147B (nl) 1983-02-16
DE2514685B2 (de) 1977-11-17
CA1067093A (en) 1979-11-27
NL7503679A (nl) 1975-10-07
FR2266690B1 (it) 1979-04-27
US3994960A (en) 1976-11-30

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