IL26054A - Alanosine homologues - Google Patents
Alanosine homologuesInfo
- Publication number
- IL26054A IL26054A IL26054A IL2605466A IL26054A IL 26054 A IL26054 A IL 26054A IL 26054 A IL26054 A IL 26054A IL 2605466 A IL2605466 A IL 2605466A IL 26054 A IL26054 A IL 26054A
- Authority
- IL
- Israel
- Prior art keywords
- formula
- compound
- amino
- acid
- defined above
- Prior art date
Links
- ZGNLFUXWZJGETL-YUSKDDKASA-N (Z)-[(2S)-2-amino-2-carboxyethyl]-hydroxyimino-oxidoazanium Chemical compound N[C@@H](C\[N+]([O-])=N\O)C(O)=O ZGNLFUXWZJGETL-YUSKDDKASA-N 0.000 title description 5
- 229950005033 alanosine Drugs 0.000 title description 5
- MLFKVJCWGUZWNV-UHFFFAOYSA-N L-alanosine Natural products OC(=O)C(N)CN(O)N=O MLFKVJCWGUZWNV-UHFFFAOYSA-N 0.000 title description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 7
- -1 hydroxylamino compound Chemical class 0.000 claims description 6
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 230000004927 fusion Effects 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 2
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 4
- 230000003115 biocidal effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229960000443 hydrochloric acid Drugs 0.000 description 3
- 235000011167 hydrochloric acid Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- ISOVWEWRUVBJME-UHFFFAOYSA-N 1,2,3-triphenyltetrazole Chemical compound C1=NN(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N1C1=CC=CC=C1 ISOVWEWRUVBJME-UHFFFAOYSA-N 0.000 description 2
- DACPCWJGHZULGO-UHFFFAOYSA-N 2-amino-2-(hydroxyamino)-4-nitrosobutanoic acid Chemical compound ONC(C(O)=O)(N)CCN=O DACPCWJGHZULGO-UHFFFAOYSA-N 0.000 description 2
- VWEUVNWIQCGBNB-UHFFFAOYSA-N 2-amino-2-(hydroxyamino)-6-nitrosohexanoic acid Chemical compound NC(C(=O)O)(CCCCN=O)NO VWEUVNWIQCGBNB-UHFFFAOYSA-N 0.000 description 2
- KQAPACMXYALMQX-UHFFFAOYSA-N 5-[4-(hydroxyamino)butyl]imidazolidine-2,4-dione hydrochloride Chemical compound Cl.ONCCCCC1C(NC(N1)=O)=O KQAPACMXYALMQX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 2
- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- ZGNLFUXWZJGETL-WAYWQWQTSA-N (Z)-(2-amino-2-carboxyethyl)-hydroxyimino-oxidoazanium Chemical compound NC(C\[N+]([O-])=N\O)C(O)=O ZGNLFUXWZJGETL-WAYWQWQTSA-N 0.000 description 1
- VIWSVOOCJXAYRE-UHFFFAOYSA-N 2-amino-4-(hydroxyamino)butanoic acid Chemical compound OC(=O)C(N)CCNO VIWSVOOCJXAYRE-UHFFFAOYSA-N 0.000 description 1
- VIFOGXGRPDRQHS-UHFFFAOYSA-N 2-azaniumyl-3-(hydroxyamino)propanoate Chemical compound OC(=O)C(N)CNO VIFOGXGRPDRQHS-UHFFFAOYSA-N 0.000 description 1
- FZQOIMPLZAYIKU-UHFFFAOYSA-N 2-azaniumyl-6-(hydroxyamino)hexanoate Chemical compound OC(=O)C(N)CCCCNO FZQOIMPLZAYIKU-UHFFFAOYSA-N 0.000 description 1
- FFNNVNAMCNAOIW-UHFFFAOYSA-N 5-(2-bromoethyl)imidazolidine-2,4-dione Chemical compound BrCCC1NC(=O)NC1=O FFNNVNAMCNAOIW-UHFFFAOYSA-N 0.000 description 1
- TWRKXHFCQVEYHI-UHFFFAOYSA-N 5-(4-bromobutyl)imidazolidine-2,4-dione Chemical compound BrCCCCC1NC(=O)NC1=O TWRKXHFCQVEYHI-UHFFFAOYSA-N 0.000 description 1
- CBWBNGCOLMCZMD-UHFFFAOYSA-N 5-[2-(hydroxyamino)ethyl]imidazolidine-2,4-dione hydrochloride Chemical compound Cl.ONCCC1C(NC(N1)=O)=O CBWBNGCOLMCZMD-UHFFFAOYSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-UHFFFAOYSA-N Alanine Chemical compound CC([NH3+])C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 241000257159 Musca domestica Species 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 150000001371 alpha-amino acids Chemical class 0.000 description 1
- 235000008206 alpha-amino acids Nutrition 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229940091173 hydantoin Drugs 0.000 description 1
- 150000001469 hydantoins Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- UQDJGEHQDNVPGU-UHFFFAOYSA-N serine phosphoethanolamine Chemical compound [NH3+]CCOP([O-])(=O)OCC([NH3+])C([O-])=O UQDJGEHQDNVPGU-UHFFFAOYSA-N 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/72—Two oxygen atoms, e.g. hydantoin
- C07D233/76—Two oxygen atoms, e.g. hydantoin with substituted hydrocarbon radicals attached to the third ring carbon atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB30363/65A GB1117310A (en) | 1965-07-16 | 1965-07-16 | Substituted ª‡-amino acids and a method of preparation therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IL26054A true IL26054A (en) | 1970-03-22 |
Family
ID=10306479
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL26054A IL26054A (en) | 1965-07-16 | 1966-06-28 | Alanosine homologues |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3823186A (en, 2012) |
| AT (1) | AT261570B (en, 2012) |
| BE (1) | BE683262A (en, 2012) |
| BR (1) | BR6681316D0 (en, 2012) |
| CH (1) | CH473093A (en, 2012) |
| DE (1) | DE1543735B1 (en, 2012) |
| DK (1) | DK113649B (en, 2012) |
| ES (1) | ES328772A1 (en, 2012) |
| FI (1) | FI45181C (en, 2012) |
| FR (2) | FR1500114A (en, 2012) |
| GB (1) | GB1117310A (en, 2012) |
| IL (1) | IL26054A (en, 2012) |
| NL (2) | NL6609820A (en, 2012) |
| SE (1) | SE301815B (en, 2012) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3900567A (en) * | 1972-09-14 | 1975-08-19 | Lepetit Spa | Antibiotic substances |
-
0
- NL NL128388D patent/NL128388C/xx active
-
1965
- 1965-07-16 GB GB30363/65A patent/GB1117310A/en not_active Expired
-
1966
- 1966-06-23 US US00559749A patent/US3823186A/en not_active Expired - Lifetime
- 1966-06-28 BE BE683262D patent/BE683262A/xx not_active IP Right Cessation
- 1966-06-28 IL IL26054A patent/IL26054A/en unknown
- 1966-07-05 CH CH968766A patent/CH473093A/de not_active IP Right Cessation
- 1966-07-06 ES ES328772A patent/ES328772A1/es not_active Expired
- 1966-07-08 SE SE9404/66A patent/SE301815B/xx unknown
- 1966-07-08 AT AT658466A patent/AT261570B/de active
- 1966-07-09 DE DE19661543735 patent/DE1543735B1/de active Pending
- 1966-07-13 DK DK363466AA patent/DK113649B/da unknown
- 1966-07-13 NL NL6609820A patent/NL6609820A/xx unknown
- 1966-07-15 FI FI661892A patent/FI45181C/fi active
- 1966-07-15 FR FR69603A patent/FR1500114A/fr not_active Expired
- 1966-07-15 BR BR181316/66A patent/BR6681316D0/pt unknown
- 1966-12-13 FR FR79816A patent/FR5776M/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR5776M (en, 2012) | 1968-02-05 |
| DK113649B (da) | 1969-04-14 |
| SE301815B (en, 2012) | 1968-06-24 |
| US3823186A (en) | 1974-07-09 |
| FR1500114A (fr) | 1967-11-03 |
| ES328772A1 (es) | 1968-05-01 |
| AT261570B (de) | 1968-05-10 |
| BR6681316D0 (pt) | 1973-11-13 |
| NL6609820A (en, 2012) | 1967-01-17 |
| FI45181C (fi) | 1972-04-10 |
| FI45181B (en, 2012) | 1971-12-31 |
| DE1793681B1 (de) | 1972-08-03 |
| BE683262A (en, 2012) | 1966-12-01 |
| GB1117310A (en) | 1968-06-19 |
| DE1543735B1 (de) | 1972-02-03 |
| CH473093A (de) | 1969-05-31 |
| NL128388C (en, 2012) |
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