IL113668A - A cross-hybrid electrolytic membrane, its production and a battery cell containing it - Google Patents
A cross-hybrid electrolytic membrane, its production and a battery cell containing itInfo
- Publication number
- IL113668A IL113668A IL11366895A IL11366895A IL113668A IL 113668 A IL113668 A IL 113668A IL 11366895 A IL11366895 A IL 11366895A IL 11366895 A IL11366895 A IL 11366895A IL 113668 A IL113668 A IL 113668A
- Authority
- IL
- Israel
- Prior art keywords
- copolymer
- electrolyte
- group
- hexafluoropropylene
- crosslinking agent
- Prior art date
Links
- 239000003792 electrolyte Substances 0.000 title claims description 31
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 58
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 31
- 239000012528 membrane Substances 0.000 claims description 31
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 30
- 239000004014 plasticizer Substances 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 25
- 239000002904 solvent Substances 0.000 claims description 24
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 23
- 239000003431 cross linking reagent Substances 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 23
- -1 acrylate ester Chemical class 0.000 claims description 21
- 150000002148 esters Chemical class 0.000 claims description 15
- 229910052744 lithium Inorganic materials 0.000 claims description 15
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 229910003002 lithium salt Inorganic materials 0.000 claims description 11
- 159000000002 lithium salts Chemical class 0.000 claims description 11
- 230000005855 radiation Effects 0.000 claims description 11
- 238000009835 boiling Methods 0.000 claims description 7
- 238000009830 intercalation Methods 0.000 claims description 7
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 6
- 239000011159 matrix material Substances 0.000 claims description 6
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 6
- 230000002687 intercalation Effects 0.000 claims description 5
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 4
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 4
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 239000007784 solid electrolyte Substances 0.000 claims description 4
- NEBBLNDVSSWJLL-UHFFFAOYSA-N 2,3-bis(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(OC(=O)C(C)=C)COC(=O)C(C)=C NEBBLNDVSSWJLL-UHFFFAOYSA-N 0.000 claims description 3
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 claims description 3
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 claims description 3
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 2
- 229910013462 LiC104 Inorganic materials 0.000 claims description 2
- 229910000552 LiCF3SO3 Inorganic materials 0.000 claims description 2
- 229910013131 LiN Inorganic materials 0.000 claims description 2
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 claims description 2
- 210000004027 cell Anatomy 0.000 description 40
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 21
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 15
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 238000004132 cross linking Methods 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- 239000004971 Cross linker Substances 0.000 description 8
- 239000002033 PVDF binder Substances 0.000 description 8
- 238000005266 casting Methods 0.000 description 8
- 238000010894 electron beam technology Methods 0.000 description 8
- 229910001416 lithium ion Inorganic materials 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 6
- 239000008151 electrolyte solution Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 210000001787 dendrite Anatomy 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- 229910001290 LiPF6 Inorganic materials 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000002939 deleterious effect Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 229920006370 Kynar Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000011243 crosslinked material Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- 239000004811 fluoropolymer Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- SYEWHONLFGZGLK-UHFFFAOYSA-N 2-[1,3-bis(oxiran-2-ylmethoxy)propan-2-yloxymethyl]oxirane Chemical compound C1OC1COCC(OCC1OC1)COCC1CO1 SYEWHONLFGZGLK-UHFFFAOYSA-N 0.000 description 1
- SHKUUQIDMUMQQK-UHFFFAOYSA-N 2-[4-(oxiran-2-ylmethoxy)butoxymethyl]oxirane Chemical compound C1OC1COCCCCOCC1CO1 SHKUUQIDMUMQQK-UHFFFAOYSA-N 0.000 description 1
- IGFAOCUGYURMCW-UHFFFAOYSA-N 2-cinnamylidene-6-phenyl-3-propylhexa-3,5-diene-1,1-diamine Chemical compound C=1C=CC=CC=1C=CC=C(C(N)N)C(CCC)=CC=CC1=CC=CC=C1 IGFAOCUGYURMCW-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002449 FKM Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 229910001547 lithium hexafluoroantimonate(V) Inorganic materials 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 239000002201 polymeric electrolyte material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
- VOSUIKFOFHZNED-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,3,5-tricarboxylate Chemical compound C=CCOC(=O)C1=CC(C(=O)OCC=C)=CC(C(=O)OCC=C)=C1 VOSUIKFOFHZNED-UHFFFAOYSA-N 0.000 description 1
- 229920003249 vinylidene fluoride hexafluoropropylene elastomer Polymers 0.000 description 1
- 229920005609 vinylidenefluoride/hexafluoropropylene copolymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M50/42—Acrylic resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M50/426—Fluorocarbon polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Dispersion Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/243,018 US5429891A (en) | 1993-03-05 | 1994-05-13 | Crosslinked hybrid electrolyte film and methods of making and using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL113668A0 IL113668A0 (en) | 1995-08-31 |
| IL113668A true IL113668A (en) | 1999-01-26 |
Family
ID=22917031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL11366895A IL113668A (en) | 1994-05-13 | 1995-05-09 | A cross-hybrid electrolytic membrane, its production and a battery cell containing it |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5429891A (de) |
| EP (1) | EP0760169A4 (de) |
| AU (1) | AU2547195A (de) |
| CA (1) | CA2188132A1 (de) |
| IL (1) | IL113668A (de) |
| TW (1) | TW363287B (de) |
| WO (1) | WO1995031835A1 (de) |
Families Citing this family (74)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5418091A (en) * | 1993-03-05 | 1995-05-23 | Bell Communications Research, Inc. | Polymeric electrolytic cell separator membrane |
| US5714282A (en) * | 1995-05-23 | 1998-02-03 | Tagawa; Kazuo | Coating paste and a nonaqueous electrode for a secondary battery |
| EP0862232B1 (de) * | 1995-11-15 | 2008-02-13 | Asahi Kasei EMD Corporation | Hybrider polymerverbundelektrolyt und nichtwässrige elektrochemische zelle |
| GB2309701B (en) * | 1996-01-31 | 1999-06-16 | Aea Technology Plc | Organic electrolyte composition |
| DE69700138T2 (de) * | 1996-01-31 | 1999-09-02 | Aea Technology Plc | Polyvinylidenfluorid als polymerer Festelektrolyt für Lithium-Ionen-Batterien |
| DE19612769A1 (de) * | 1996-03-29 | 1997-10-02 | Basf Ag | Als Trägermaterial für Festelektrolyten oder Separatoren für elektrochemische Zellen geeignete Gemische |
| JP3539570B2 (ja) * | 1996-06-13 | 2004-07-07 | 旭化成エレクトロニクス株式会社 | ハイブリッド電解質、該電解質の製造方法、および該電解質を用いた電気化学素子の製造方法 |
| US5948464A (en) * | 1996-06-19 | 1999-09-07 | Imra America, Inc. | Process of manufacturing porous separator for electrochemical power supply |
| US6346351B1 (en) | 1996-09-30 | 2002-02-12 | Danionics A/S | Lithium salt/carbonate electrolyte system, a method for the preparation thereof, the use thereof and a battery containing the electrolyte system |
| US6444356B1 (en) | 1996-11-01 | 2002-09-03 | Jackson C. Ma | Lithium battery with secondary battery separator |
| US5720780A (en) * | 1996-11-04 | 1998-02-24 | Valence Technology, Inc. | Film forming method for lithium ion rechargeable batteries |
| DE19652174A1 (de) * | 1996-12-14 | 1998-06-18 | Varta Batterie | Verfahren zur Herstellung von Polymerelektrolyten |
| JP3225867B2 (ja) * | 1996-12-18 | 2001-11-05 | 三菱電機株式会社 | リチウムイオン二次電池及びその製造方法 |
| JP3223824B2 (ja) * | 1996-12-26 | 2001-10-29 | 三菱電機株式会社 | リチウムイオン二次電池 |
| ID20294A (id) * | 1997-02-28 | 1998-11-26 | Atochem North America Elf | Kopolimer viniliden fluorida dan heksafluoropropilena yang mempunyai kandungan zat yang dapat diekstrak yang berkurang dan kejernihan larutan yang lebih baik |
| JPH10302843A (ja) * | 1997-02-28 | 1998-11-13 | Mitsubishi Electric Corp | 電池用接着剤及びそれを用いた電池とその製造法 |
| KR100269204B1 (ko) * | 1997-04-10 | 2000-10-16 | 윤종용 | 고분자 고체 전해질, 그 제조방법 및 이 고분자 고체 전해질을 채용한 리튬 2차전지 |
| US5882721A (en) * | 1997-05-01 | 1999-03-16 | Imra America Inc | Process of manufacturing porous separator for electrochemical power supply |
| JPH1116561A (ja) * | 1997-06-23 | 1999-01-22 | Elf Atochem Japan Kk | バッテリーセパレータ、その製造方法、および非水系二次電池 |
| JPH1135765A (ja) * | 1997-07-24 | 1999-02-09 | Sharp Corp | 高分子固体電解質とその製造方法 |
| US6077624A (en) * | 1997-08-14 | 2000-06-20 | Valence Technology, Inc. | Lithium ion cells with improved thermal stability |
| US6171723B1 (en) | 1997-10-10 | 2001-01-09 | 3M Innovative Properties Company | Batteries with porous components |
| US6235433B1 (en) * | 1997-12-19 | 2001-05-22 | Nec Corporation | High molecular gel electrolyte and secondary battery using the same |
| JP4421107B2 (ja) * | 1997-12-26 | 2010-02-24 | 株式会社クレハ | ポリマー電解質及びそれを用いた非水系電池 |
| US6811928B2 (en) * | 1998-01-22 | 2004-11-02 | Mitsubishi Denki Kabushiki Kaisha | Battery with adhesion resin layer including filler |
| ATE242549T1 (de) * | 1998-02-25 | 2003-06-15 | Celanese Ventures Gmbh | Verfahren zur herstellung einer membran aus geliertem verbundelektrolyten |
| JP4247583B2 (ja) * | 1998-04-27 | 2009-04-02 | ソニー株式会社 | 固体電解質二次電池およびその製造方法 |
| DE19819752A1 (de) | 1998-05-04 | 1999-11-11 | Basf Ag | Für elektrochemische Zellen geeignete Zusammensetzungen |
| AU4225799A (en) * | 1998-06-02 | 1999-12-20 | Ultralife Batteries, Inc. | Cross-linked polymeric components of rechargeable solid lithium batteries and methods for making same |
| DE19835615A1 (de) | 1998-08-06 | 2000-02-10 | Basf Ag | Für elektrochemische Zellen geeignete Zusammensetzungen |
| DE19839217C2 (de) * | 1998-08-28 | 2001-02-08 | Fraunhofer Ges Forschung | Pastöse Massen, Schichten und Schichtverbände, Zellen und Verfahren zur Herstellung |
| DE19964159B4 (de) | 1998-10-20 | 2005-08-11 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zum Herstellen selbsttragender oder auf einem Substrat aufliegender, in elektrochemischen Bauelementen verwendbarer Schichten und Zwischenprodukte hierfür |
| JP4081895B2 (ja) * | 1998-11-26 | 2008-04-30 | ソニー株式会社 | リチウムイオン二次電池用のゲル状電解質及びゲル状電解質リチウムイオン二次電池 |
| KR100441611B1 (ko) * | 1998-12-22 | 2004-09-18 | 주식회사 파인셀 | 흡수제를 이용한 고분자 전해질 및 그의 제조방법 |
| GB2346729B (en) * | 1999-02-10 | 2003-01-15 | Aea Technology Plc | Polymer electrolyte |
| US6316142B1 (en) | 1999-03-31 | 2001-11-13 | Imra America, Inc. | Electrode containing a polymeric binder material, method of formation thereof and electrochemical cell |
| US6148503A (en) * | 1999-03-31 | 2000-11-21 | Imra America, Inc. | Process of manufacturing porous separator for electrochemical power supply |
| US20030170536A1 (en) * | 1999-09-22 | 2003-09-11 | Mitsubishi Denki Kabushiki Kaisha | Bttery with adhesion resin layer including filler |
| WO2001032726A1 (en) * | 1999-11-03 | 2001-05-10 | Atofina Chemicals, Inc. | Low crystallinity vinylidene fluoride hexafluoropropylene copolymers |
| KR100647565B1 (ko) * | 1999-11-09 | 2006-11-17 | 삼성에스디아이 주식회사 | 리튬 2차 전지의 제조방법 |
| US6733924B1 (en) * | 1999-11-23 | 2004-05-11 | Moltech Corporation | Lithium anodes for electrochemical cells |
| US7247408B2 (en) | 1999-11-23 | 2007-07-24 | Sion Power Corporation | Lithium anodes for electrochemical cells |
| TW480758B (en) | 1999-12-14 | 2002-03-21 | Sanyo Electric Co | Lithium ion secondary battery and battery device comprising same |
| WO2001057940A2 (en) * | 2000-02-04 | 2001-08-09 | Amtek Research International Llc | Freestanding microporous separator including a gel-forming polymer |
| KR100513634B1 (ko) * | 2000-09-22 | 2005-09-09 | 에스케이씨 주식회사 | 리튬 2차전지 및 그 제조방법 |
| US7238451B2 (en) | 2000-12-29 | 2007-07-03 | The Board Of Regents Of The University Of Oklahoma | Conductive polyamine-based electrolyte |
| US6746794B2 (en) | 2001-06-12 | 2004-06-08 | Tech Drive, Inc | Thermal runaway inhibitors |
| US7008722B2 (en) * | 2002-04-10 | 2006-03-07 | Sui-Yang Huang | Polymer-gel lithium ion battery |
| DE10219424A1 (de) * | 2002-05-02 | 2003-11-20 | Varta Microbattery Gmbh | Galvanisches Element mit dünnen Elektroden |
| JP3867709B2 (ja) * | 2003-03-26 | 2007-01-10 | ダイキン工業株式会社 | 薄膜の形成方法 |
| WO2004086419A1 (ja) * | 2003-03-26 | 2004-10-07 | Daikin Industries Ltd. | 強誘電性薄膜の形成方法 |
| CN1300863C (zh) * | 2003-12-16 | 2007-02-14 | 中国电子科技集团公司第十八研究所 | 电池用复合型聚合物电解质膜及其制造方法 |
| US7358012B2 (en) | 2004-01-06 | 2008-04-15 | Sion Power Corporation | Electrolytes for lithium sulfur cells |
| US8828610B2 (en) * | 2004-01-06 | 2014-09-09 | Sion Power Corporation | Electrolytes for lithium sulfur cells |
| US10297827B2 (en) | 2004-01-06 | 2019-05-21 | Sion Power Corporation | Electrochemical cell, components thereof, and methods of making and using same |
| JP2007335319A (ja) * | 2006-06-16 | 2007-12-27 | Sony Corp | 非水電解質二次電池 |
| KR101002161B1 (ko) * | 2007-11-29 | 2010-12-17 | 주식회사 엘지화학 | 다공성 코팅층이 형성된 세퍼레이터, 그 제조방법 및 이를 구비한 전기화학소자 |
| KR20160036105A (ko) * | 2007-12-21 | 2016-04-01 | 바티움 캐나다 인크. | 리튬 폴리머 배터리용 전해질 |
| US8283074B2 (en) * | 2008-08-15 | 2012-10-09 | Uchicago Argonne, Llc | Electrolyte salts for nonaqueous electrolytes |
| US8906548B2 (en) | 2009-10-07 | 2014-12-09 | Miltec Corporation | Actinic and electron beam radiation curable electrode binders and electrodes incorporating same |
| KR20130105838A (ko) | 2010-08-24 | 2013-09-26 | 바스프 에스이 | 전기화학 셀용 전해질 물질 |
| US8735002B2 (en) | 2011-09-07 | 2014-05-27 | Sion Power Corporation | Lithium sulfur electrochemical cell including insoluble nitrogen-containing compound |
| JP6097284B2 (ja) * | 2011-06-23 | 2017-03-15 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | 二次電池 |
| US9850394B2 (en) * | 2012-06-28 | 2017-12-26 | Kureha Corporation | Resin composition, filler-containing resin film for non-aqueous electrolyte secondary battery, and method for producing filler-containing resin film for non-aqueous electrolyte secondary battery |
| US9577289B2 (en) | 2012-12-17 | 2017-02-21 | Sion Power Corporation | Lithium-ion electrochemical cell, components thereof, and methods of making and using same |
| EP2997612B1 (de) | 2013-05-17 | 2019-11-20 | Miltec Corporation | Mit aktinischer und elektronenstrahlung härtbare elektrodenbinder auf wasserbasis und elektroden damit |
| KR101618681B1 (ko) * | 2014-12-30 | 2016-05-11 | 삼성에스디아이 주식회사 | 다공성 내열층 조성물, 다공성 내열층을 포함하는 분리막, 상기 분리막을 이용한 전기 화학 전지, 및 상기 분리막의 제조 방법 |
| KR101551757B1 (ko) * | 2014-12-30 | 2015-09-10 | 삼성에스디아이 주식회사 | 다공성 내열층 조성물, 다공성 내열층을 포함하는 분리막, 상기 분리막을 이용한 전기 화학 전지, 및 상기 분리막의 제조 방법 |
| CN105742551A (zh) * | 2016-03-23 | 2016-07-06 | 上海恩捷新材料科技股份有限公司 | 一种电化学装置隔离膜及其制备方法和用途 |
| CN112366422A (zh) | 2016-03-29 | 2021-02-12 | 浙江地坤键新能源科技有限公司 | 一种无孔隔膜及其应用 |
| TWI846664B (zh) * | 2016-10-20 | 2024-07-01 | 義大利商首威專業聚合物義大利公司 | 用於金屬／金屬離子電池之聚偏二氟乙烯（ｐｖｄｆ） |
| US20230235158A1 (en) * | 2016-10-20 | 2023-07-27 | Solvay Specialty Polymers Italy S.P.A. | Pvdf for metal/metal ion batteries |
| JP6959885B2 (ja) | 2018-03-14 | 2021-11-05 | 株式会社クレハ | 非水電解質二次電池用のポリマーゲル電解質および非水電解質二次電池 |
| US12122679B2 (en) | 2018-04-10 | 2024-10-22 | Alpha Assembly Solutions Inc. | Applications of engineered graphene |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4468441A (en) * | 1981-10-01 | 1984-08-28 | Rai Research Corp. | Separator membranes for redox-type electrochemical cells |
| GB8517571D0 (en) * | 1985-07-11 | 1985-08-14 | Raychem Ltd | Polymer composition |
| US4735875A (en) * | 1986-03-24 | 1988-04-05 | W. R. Grace & Co. | Cathodic electrode |
| US4731310A (en) * | 1986-08-15 | 1988-03-15 | W. R. Grace & Co. | Cathodic electrode |
| US4699857A (en) * | 1986-10-15 | 1987-10-13 | W. R. Grace & Co. | Battery separator |
| JP2528693B2 (ja) * | 1988-06-09 | 1996-08-28 | 日立マクセル株式会社 | ポリマ―電池 |
| US5296318A (en) * | 1993-03-05 | 1994-03-22 | Bell Communications Research, Inc. | Rechargeable lithium intercalation battery with hybrid polymeric electrolyte |
-
1994
- 1994-05-13 US US08/243,018 patent/US5429891A/en not_active Expired - Fee Related
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1995
- 1995-05-09 IL IL11366895A patent/IL113668A/en active IP Right Grant
- 1995-05-09 TW TW084104587A patent/TW363287B/zh active
- 1995-05-10 AU AU25471/95A patent/AU2547195A/en not_active Abandoned
- 1995-05-10 CA CA002188132A patent/CA2188132A1/en not_active Abandoned
- 1995-05-10 EP EP95919792A patent/EP0760169A4/de not_active Withdrawn
- 1995-05-10 WO PCT/US1995/005881 patent/WO1995031835A1/en not_active Ceased
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|---|---|
| IL113668A0 (en) | 1995-08-31 |
| TW363287B (en) | 1999-07-01 |
| EP0760169A1 (de) | 1997-03-05 |
| US5429891A (en) | 1995-07-04 |
| EP0760169A4 (de) | 1997-06-04 |
| CA2188132A1 (en) | 1995-11-23 |
| AU2547195A (en) | 1995-12-05 |
| WO1995031835A1 (en) | 1995-11-23 |
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