IE43491B1 - Steam reforming and mathanation catalysts methods of making them and processes for the production of fuel gases - Google Patents
Steam reforming and mathanation catalysts methods of making them and processes for the production of fuel gasesInfo
- Publication number
- IE43491B1 IE43491B1 IE1565/76A IE156576A IE43491B1 IE 43491 B1 IE43491 B1 IE 43491B1 IE 1565/76 A IE1565/76 A IE 1565/76A IE 156576 A IE156576 A IE 156576A IE 43491 B1 IE43491 B1 IE 43491B1
- Authority
- IE
- Ireland
- Prior art keywords
- catalyst
- steam
- temperature
- stage
- sodium
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 206
- 238000000629 steam reforming Methods 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 title claims description 78
- 230000008569 process Effects 0.000 title claims description 71
- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 239000002737 fuel gas Substances 0.000 title description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000011734 sodium Substances 0.000 claims abstract description 70
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 66
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 66
- 239000007789 gas Substances 0.000 claims abstract description 65
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 60
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 53
- 239000011591 potassium Substances 0.000 claims abstract description 52
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 36
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 30
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 92
- 238000001914 filtration Methods 0.000 claims description 51
- 239000000203 mixture Substances 0.000 claims description 49
- 229930195733 hydrocarbon Natural products 0.000 claims description 46
- 150000002430 hydrocarbons Chemical class 0.000 claims description 46
- 239000002002 slurry Substances 0.000 claims description 45
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 239000000243 solution Substances 0.000 claims description 27
- 239000003513 alkali Substances 0.000 claims description 24
- 238000001556 precipitation Methods 0.000 claims description 20
- 239000004215 Carbon black (E152) Substances 0.000 claims description 18
- 230000008021 deposition Effects 0.000 claims description 17
- 239000000047 product Substances 0.000 claims description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 229910002651 NO3 Inorganic materials 0.000 claims description 15
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 15
- 238000009835 boiling Methods 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 14
- 238000002407 reforming Methods 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 238000006555 catalytic reaction Methods 0.000 claims description 13
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 13
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 12
- 239000001099 ammonium carbonate Substances 0.000 claims description 12
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 12
- 238000002309 gasification Methods 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Natural products O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 10
- 239000012065 filter cake Substances 0.000 claims description 10
- 239000000376 reactant Substances 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 7
- 239000002244 precipitate Substances 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 239000001569 carbon dioxide Substances 0.000 claims description 6
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 239000008246 gaseous mixture Substances 0.000 claims description 5
- -1 hydrogen carbon dioxide Chemical class 0.000 claims description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical group CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- 239000002826 coolant Substances 0.000 claims description 4
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 150000004679 hydroxides Chemical class 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- 230000009471 action Effects 0.000 claims description 2
- 239000001273 butane Substances 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000003915 liquefied petroleum gas Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims description 2
- 150000002815 nickel Chemical class 0.000 claims 1
- 238000011176 pooling Methods 0.000 claims 1
- 239000012018 catalyst precursor Substances 0.000 abstract description 9
- 239000011261 inert gas Substances 0.000 abstract description 2
- 208000020442 loss of weight Diseases 0.000 abstract 1
- 235000012970 cakes Nutrition 0.000 description 27
- 238000002474 experimental method Methods 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 239000004744 fabric Substances 0.000 description 14
- 238000005245 sintering Methods 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 11
- 238000007792 addition Methods 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 8
- JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Chemical compound [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000006228 supernatant Substances 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 4
- 238000000975 co-precipitation Methods 0.000 description 4
- 229910052593 corundum Inorganic materials 0.000 description 4
- 239000010431 corundum Substances 0.000 description 4
- 230000009849 deactivation Effects 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000002939 deleterious effect Effects 0.000 description 3
- 235000021463 dry cake Nutrition 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 230000001376 precipitating effect Effects 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- DWAHIRJDCNGEDV-UHFFFAOYSA-N nickel(2+);dinitrate;hydrate Chemical compound O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DWAHIRJDCNGEDV-UHFFFAOYSA-N 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 239000004317 sodium nitrate Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 238000010744 Boudouard reaction Methods 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- YYCNOHYMCOXPPJ-UHFFFAOYSA-N alumane;nickel Chemical compound [AlH3].[Ni] YYCNOHYMCOXPPJ-UHFFFAOYSA-N 0.000 description 1
- ZZCONUBOESKGOK-UHFFFAOYSA-N aluminum;trinitrate;hydrate Chemical compound O.[Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O ZZCONUBOESKGOK-UHFFFAOYSA-N 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000005048 flame photometry Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000011268 mixed slurry Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical class [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB39724/75A GB1525017A (en) | 1975-09-29 | 1975-09-29 | Steam reforming and methanation catalysts methods of making them and processes for the production of fuel gases |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE43491L IE43491L (en) | 1977-03-29 |
| IE43491B1 true IE43491B1 (en) | 1981-03-11 |
Family
ID=10411127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE1565/76A IE43491B1 (en) | 1975-09-29 | 1976-07-15 | Steam reforming and mathanation catalysts methods of making them and processes for the production of fuel gases |
Country Status (21)
| Country | Link |
|---|---|
| US (3) | US4105591A (forum.php) |
| JP (1) | JPS594183B2 (forum.php) |
| AU (1) | AU497814B2 (forum.php) |
| BE (1) | BE846737A (forum.php) |
| BR (1) | BR7605606A (forum.php) |
| CA (1) | CA1097315A (forum.php) |
| CS (1) | CS205043B2 (forum.php) |
| DD (1) | DD128791A5 (forum.php) |
| DE (1) | DE2634541B2 (forum.php) |
| DK (1) | DK329376A (forum.php) |
| ES (2) | ES451939A1 (forum.php) |
| FR (1) | FR2325427A1 (forum.php) |
| GB (1) | GB1525017A (forum.php) |
| IE (1) | IE43491B1 (forum.php) |
| IN (1) | IN146365B (forum.php) |
| IT (1) | IT1069115B (forum.php) |
| LU (1) | LU75631A1 (forum.php) |
| NL (1) | NL7610788A (forum.php) |
| PL (1) | PL101184B1 (forum.php) |
| SE (1) | SE427425B (forum.php) |
| ZA (1) | ZA764261B (forum.php) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2860763D1 (en) * | 1977-12-12 | 1981-09-17 | Azote & Prod Chim | Catalyst and process for the manufacture of amines from alcohols |
| FR2430262A2 (fr) * | 1978-07-04 | 1980-02-01 | Azote & Prod Chim | Catalyseur et procede de fabrication d'amines a partir d'alcools |
| FR2411030A1 (fr) * | 1977-12-12 | 1979-07-06 | Azote & Prod Chim | Catalyseur et procede de fabrication d'amines a partir d'alcools |
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| JP2001190917A (ja) * | 2000-01-13 | 2001-07-17 | Ngk Insulators Ltd | 三角セルハニカム構造体 |
| US7128769B2 (en) * | 2002-06-27 | 2006-10-31 | Idatech, Llc | Methanol steam reforming catalysts, steam reformers, and fuel cell systems incorporating the same |
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| US7601302B2 (en) | 2005-09-16 | 2009-10-13 | Idatech, Llc | Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same |
| US8021446B2 (en) | 2005-09-16 | 2011-09-20 | Idatech, Llc | Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same |
| US7972420B2 (en) | 2006-05-22 | 2011-07-05 | Idatech, Llc | Hydrogen-processing assemblies and hydrogen-producing systems and fuel cell systems including the same |
| US7939051B2 (en) | 2006-05-23 | 2011-05-10 | Idatech, Llc | Hydrogen-producing fuel processing assemblies, heating assemblies, and methods of operating the same |
| US7365102B1 (en) | 2007-02-26 | 2008-04-29 | Delphi Technologies, Inc. | Process for pre-reforming hydrocarbon fuels |
| US8262752B2 (en) | 2007-12-17 | 2012-09-11 | Idatech, Llc | Systems and methods for reliable feedstock delivery at variable delivery rates |
| EP2335824B1 (en) * | 2008-09-24 | 2018-03-28 | Nippon Steel & Sumitomo Metal Corporation | Method for producing catalyst for reforming tar-containing gas, method for reforming tar and method for regenerating catalyst for reforming tar-containing gas |
| KR100980591B1 (ko) | 2009-03-16 | 2010-09-06 | 서울대학교산학협력단 | 중형기공성 니켈-알루미나 공침촉매, 그 제조방법 및 상기 촉매를 이용한 액화천연가스의 수증기 개질반응에 의한 수소 제조방법 |
| US8137422B2 (en) | 2009-06-03 | 2012-03-20 | Air Products And Chemicals, Inc. | Steam-hydrocarbon reforming with reduced carbon dioxide emissions |
| FR2949020B1 (fr) | 2009-08-06 | 2012-01-13 | Franco Cell | Dispositif de production d'electricite et de chaleur, incluant une pile a combustible admettant au moins du methane comme combustible |
| EP3018095B1 (en) | 2014-11-10 | 2017-06-28 | Air Products And Chemicals, Inc. | Steam-hydrocarbon reforming process |
| US10476093B2 (en) | 2016-04-15 | 2019-11-12 | Chung-Hsin Electric & Machinery Mfg. Corp. | Membrane modules for hydrogen separation and fuel processors and fuel cell systems including the same |
| US11712655B2 (en) | 2020-11-30 | 2023-08-01 | H2 Powertech, Llc | Membrane-based hydrogen purifiers |
| GB202103658D0 (en) | 2021-03-17 | 2021-04-28 | Johnson Matthey Plc | Catalyst activation |
| GB202103659D0 (en) | 2021-03-17 | 2021-04-28 | Johnson Matthey Plc | Getter activation and use |
| KR20250021383A (ko) | 2022-08-02 | 2025-02-12 | 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 | 이산화탄소 배출이 감소된 증기-탄화수소 개질 |
| US20240270573A1 (en) | 2023-02-15 | 2024-08-15 | Air Products And Chemicals, Inc. | Steam-Hydrocarbon Reforming with Low Steam Production |
| US20240279057A1 (en) | 2023-02-15 | 2024-08-22 | Air Products And Chemicals, Inc. | Steam-Hydrocarbon Reforming with Low Steam Production |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3320182A (en) | 1963-10-21 | 1967-05-16 | Exxon Research Engineering Co | High activity nickel-alumina catalyst |
| NL6402670A (forum.php) * | 1964-03-13 | 1965-09-14 | ||
| BE663807A (forum.php) * | 1964-05-12 | |||
| GB1043377A (forum.php) * | 1964-06-08 | 1966-09-21 | ||
| GB1265481A (forum.php) * | 1968-05-03 | 1972-03-01 | ||
| GB1271721A (en) * | 1968-05-03 | 1972-04-26 | Gas Council | A process for the production of methane-containing gases |
| US3759678A (en) * | 1971-04-08 | 1973-09-18 | Du Pont | Reformer catalyst |
| DE2255956A1 (de) * | 1972-11-15 | 1974-05-22 | Basf Ag | Katalysator und dessen verwendung zur herstellung von methan |
| DE2314804C3 (de) * | 1973-03-24 | 1982-01-21 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Erzeugung methanhaltiger Gase aus Kohlenwasserstoffen |
| GB1432696A (en) * | 1973-04-30 | 1976-04-22 | Ici Ltd | Catalytic process |
| US4104201A (en) * | 1974-09-06 | 1978-08-01 | British Gas Corporation | Catalytic steam reforming and catalysts therefor |
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| US4005996A (en) * | 1975-09-04 | 1977-02-01 | El Paso Natural Gas Company | Methanation process for the production of an alternate fuel for natural gas |
-
1975
- 1975-09-29 GB GB39724/75A patent/GB1525017A/en not_active Expired
-
1976
- 1976-07-12 US US05/704,410 patent/US4105591A/en not_active Expired - Lifetime
- 1976-07-15 IE IE1565/76A patent/IE43491B1/en unknown
- 1976-07-19 ZA ZA00764261A patent/ZA764261B/xx unknown
- 1976-07-19 CA CA257,271A patent/CA1097315A/en not_active Expired
- 1976-07-20 SE SE7608261A patent/SE427425B/xx unknown
- 1976-07-21 DK DK329376A patent/DK329376A/da not_active Application Discontinuation
- 1976-07-29 PL PL1976191516A patent/PL101184B1/pl unknown
- 1976-07-31 DE DE2634541A patent/DE2634541B2/de not_active Ceased
- 1976-08-02 IN IN1375/CAL/76A patent/IN146365B/en unknown
- 1976-08-20 FR FR7625404A patent/FR2325427A1/fr active Granted
- 1976-08-20 LU LU75631A patent/LU75631A1/xx unknown
- 1976-08-25 BR BR7605606A patent/BR7605606A/pt unknown
- 1976-09-02 JP JP51105387A patent/JPS594183B2/ja not_active Expired
- 1976-09-20 AU AU17913/76A patent/AU497814B2/en not_active Expired
- 1976-09-24 DD DD7600194988A patent/DD128791A5/xx unknown
- 1976-09-28 IT IT69320/76A patent/IT1069115B/it active
- 1976-09-29 CS CS766287A patent/CS205043B2/cs unknown
- 1976-09-29 BE BE171073A patent/BE846737A/xx not_active IP Right Cessation
- 1976-09-29 ES ES451939A patent/ES451939A1/es not_active Expired
- 1976-09-29 NL NL7610788A patent/NL7610788A/xx unknown
-
1977
- 1977-10-17 ES ES463282A patent/ES463282A1/es not_active Expired
-
1979
- 1979-06-18 US US06/049,601 patent/US4250060A/en not_active Expired - Lifetime
-
1980
- 1980-07-30 US US06/173,718 patent/US4417905A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US4250060A (en) | 1981-02-10 |
| AU497814B2 (en) | 1979-01-11 |
| DE2634541B2 (de) | 1980-09-25 |
| CA1097315A (en) | 1981-03-10 |
| BR7605606A (pt) | 1977-08-09 |
| ZA764261B (en) | 1978-03-29 |
| SE427425B (sv) | 1983-04-11 |
| FR2325427B1 (forum.php) | 1978-11-03 |
| IE43491L (en) | 1977-03-29 |
| PL101184B1 (pl) | 1978-12-30 |
| US4105591A (en) | 1978-08-08 |
| NL7610788A (nl) | 1977-03-31 |
| ES463282A1 (es) | 1978-07-16 |
| JPS5242488A (en) | 1977-04-02 |
| JPS594183B2 (ja) | 1984-01-28 |
| BE846737A (fr) | 1977-01-17 |
| LU75631A1 (forum.php) | 1977-03-29 |
| DD128791A5 (de) | 1977-12-07 |
| DE2634541A1 (de) | 1977-03-31 |
| FR2325427A1 (fr) | 1977-04-22 |
| DK329376A (da) | 1977-03-30 |
| US4417905A (en) | 1983-11-29 |
| IN146365B (forum.php) | 1979-05-12 |
| CS205043B2 (en) | 1981-04-30 |
| ES451939A1 (es) | 1977-12-16 |
| AU1791376A (en) | 1978-04-06 |
| IT1069115B (it) | 1985-03-25 |
| GB1525017A (en) | 1978-09-20 |
| SE7608261L (sv) | 1977-03-30 |
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