IE35763B1 - Process for treating surfaces of plastics materials - Google Patents
Process for treating surfaces of plastics materialsInfo
- Publication number
- IE35763B1 IE35763B1 IE1328/71A IE132871A IE35763B1 IE 35763 B1 IE35763 B1 IE 35763B1 IE 1328/71 A IE1328/71 A IE 1328/71A IE 132871 A IE132871 A IE 132871A IE 35763 B1 IE35763 B1 IE 35763B1
- Authority
- IE
- Ireland
- Prior art keywords
- mole
- contain
- electroless
- treating
- nah
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/28—Sensitising or activating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
- C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
- C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemically Coating (AREA)
Abstract
1371913 Pre-treatment and electroless plating of plastics SCHERING AG 19 Oct 1971 [23 Oct 1970] 48580/71 Heading C7F An ABS plastics, modified polyolefin, polymer of an ester of acrylic acid, or polyamide, is pretreated for electroless plating by (i) treating with chromosulphuric acid, (ii) activating and (iii) treating with an aqueous solution containing a boron hydride compound. Steps (i) and (ii) may be separate, or simultaneous using CrO 3 /H 2 SO 4 / PdCl 2 with or without H 3 PO 4 . The boron hydride compound may be NaBH 4 , or R<SP>1</SP> R<SP>2</SP>R<SP>3</SP>NBH 3 where R<SP>1</SP> = lower alkyl and R<SP>2</SP>, R<SP>3</SP> = H or lower alkyl, and may be used in concentration 0À0001 to 0À1 mole/l, or in the case of subsequent Ni plating, the solution may also contain 0À1-0À5 mole/l of the reducing agent to be used in the Ni bath, e.g. NaH 2 PO 2 , in which case the amount of B compound may be as low as 0À00005 mole/l; the treatment temperature is 25-50C and the solution may also contain N 2 H 4 .H 2 O. The electroless Ni bath may contain 20-30 g/l Ni salt, e.g. NiSO 4 , 40-70 g/l complex former/buffer, e.g. citric or succinic acid, and 10-30 g/l alkali metal hypophosphite, e.g. NaH 2 PO 2 ; an electrolytic layer may be applied to the electroless Ni.
[GB1371913A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702053921 DE2053921A1 (en) | 1970-10-23 | 1970-10-23 | Process for the pretreatment of plastics for metallizing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE35763L IE35763L (en) | 1972-04-23 |
| IE35763B1 true IE35763B1 (en) | 1976-05-12 |
Family
ID=5786976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE1328/71A IE35763B1 (en) | 1970-10-23 | 1971-10-21 | Process for treating surfaces of plastics materials |
Country Status (13)
| Country | Link |
|---|---|
| AU (1) | AU460177B2 (en) |
| BE (1) | BE774333A (en) |
| BR (1) | BR7107048D0 (en) |
| CH (1) | CH562277A5 (en) |
| DE (1) | DE2053921A1 (en) |
| ES (1) | ES394868A1 (en) |
| FR (1) | FR2111801B1 (en) |
| GB (1) | GB1371913A (en) |
| IE (1) | IE35763B1 (en) |
| IT (1) | IT941351B (en) |
| NL (1) | NL7114530A (en) |
| YU (1) | YU34546B (en) |
| ZA (1) | ZA716726B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3816494A1 (en) * | 1988-05-10 | 1989-11-16 | Schering Ag | SOLUTION AND METHOD FOR THE AETZING AND ACTIVATION OF INSULATED SURFACES |
-
1970
- 1970-10-23 DE DE19702053921 patent/DE2053921A1/en active Pending
-
1971
- 1971-09-07 ES ES394868A patent/ES394868A1/en not_active Expired
- 1971-10-04 YU YU2508/71A patent/YU34546B/en unknown
- 1971-10-07 ZA ZA716726A patent/ZA716726B/en unknown
- 1971-10-14 AU AU34567/71A patent/AU460177B2/en not_active Expired
- 1971-10-18 CH CH1520071A patent/CH562277A5/xx not_active IP Right Cessation
- 1971-10-19 GB GB4858071A patent/GB1371913A/en not_active Expired
- 1971-10-21 BR BR7048/71A patent/BR7107048D0/en unknown
- 1971-10-21 IT IT30160/71A patent/IT941351B/en active
- 1971-10-21 NL NL7114530A patent/NL7114530A/xx not_active Application Discontinuation
- 1971-10-21 IE IE1328/71A patent/IE35763B1/en unknown
- 1971-10-22 BE BE774333A patent/BE774333A/en unknown
- 1971-10-25 FR FR7138216A patent/FR2111801B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2111801B1 (en) | 1974-10-11 |
| YU250871A (en) | 1979-02-28 |
| FR2111801A1 (en) | 1972-06-09 |
| NL7114530A (en) | 1972-04-25 |
| YU34546B (en) | 1979-09-10 |
| DE2053921A1 (en) | 1972-04-27 |
| BE774333A (en) | 1972-04-24 |
| ES394868A1 (en) | 1974-03-01 |
| AU3456771A (en) | 1973-04-19 |
| IE35763L (en) | 1972-04-23 |
| GB1371913A (en) | 1974-10-30 |
| IT941351B (en) | 1973-03-01 |
| ZA716726B (en) | 1972-06-28 |
| AU460177B2 (en) | 1975-04-17 |
| CH562277A5 (en) | 1975-05-30 |
| BR7107048D0 (en) | 1973-04-05 |
| SU403200A3 (en) | 1973-10-19 |
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