HUP9700936A2 - Titán karbonitrid komplex szilicium-nitrid anyagból készült szerszám - Google Patents
Titán karbonitrid komplex szilicium-nitrid anyagból készült szerszámInfo
- Publication number
- HUP9700936A2 HUP9700936A2 HU9700936A HUP9700936A HUP9700936A2 HU P9700936 A2 HUP9700936 A2 HU P9700936A2 HU 9700936 A HU9700936 A HU 9700936A HU P9700936 A HUP9700936 A HU P9700936A HU P9700936 A2 HUP9700936 A2 HU P9700936A2
- Authority
- HU
- Hungary
- Prior art keywords
- silicon nitride
- tool
- nitride
- si3n4
- shock
- Prior art date
Links
- 229910052581 Si3N4 Inorganic materials 0.000 title abstract 6
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052719 titanium Inorganic materials 0.000 title abstract 2
- 239000010936 titanium Substances 0.000 title abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title 1
- 239000000463 material Substances 0.000 abstract 2
- 230000008646 thermal stress Effects 0.000 abstract 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 abstract 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 abstract 1
- 239000011365 complex material Substances 0.000 abstract 1
- NLQFUUYNQFMIJW-UHFFFAOYSA-N dysprosium(III) oxide Inorganic materials O=[Dy]O[Dy]=O NLQFUUYNQFMIJW-UHFFFAOYSA-N 0.000 abstract 1
- 238000007373 indentation Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 239000004575 stone Substances 0.000 abstract 1
- -1 titanium carbide nitride Chemical class 0.000 abstract 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 abstract 1
- FIXNOXLJNSSSLJ-UHFFFAOYSA-N ytterbium(III) oxide Inorganic materials O=[Yb]O[Yb]=O FIXNOXLJNSSSLJ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
- C04B35/58007—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on refractory metal nitrides
- C04B35/58014—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on refractory metal nitrides based on titanium nitrides, e.g. TiAlON
- C04B35/58021—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on refractory metal nitrides based on titanium nitrides, e.g. TiAlON based on titanium carbonitrides
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
- C04B35/584—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicon nitride
- C04B35/593—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on silicon nitride obtained by pressure sintering
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
- C04B35/6455—Hot isostatic pressing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5031—Alumina
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5053—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials non-oxide ceramics
- C04B41/5057—Carbides
- C04B41/5061—Titanium carbide
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5053—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials non-oxide ceramics
- C04B41/5062—Borides, Nitrides or Silicides
- C04B41/5068—Titanium nitride
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/87—Ceramics
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
- B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/46—Gases other than oxygen used as reactant, e.g. nitrogen used to make a nitride phase
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Products (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
Abstract
Titán-karbő-nitrid kőmplex anyagból készült szilíciűm-nitrid anyagbólkészült szerszám, amely főképpen titán-karbő-nitridből és szilíciűm-nitridből van, és 10-56 tömeg% Ti, 11,6-51 tömeg% Si összetevőt,tővábbá összességében 1-21 tömeg% Ce és/vagy Y és/vagy Yb és/vagy Dyösszetevőt tartalmaz. A szerszám anyagában a Si3N4 a szilárdságőt és alökésszerű termikűs igénybevétellel szembeni ellenállóképességetnöveli, a TiCN pedig a keménységet főkőzza, űgyanakkőr meggátőlja,hőgy a Si3N4 és az Fe reakcióba lépjen egymással. Ha a Ce, Y, Yb és Dyfentiekben meghatárőzőtt mennyiségi viszőnyait alapűl véveszinterezési segédanyagként CeO2 és/vagy Y2O3 és/vagy Yb2O3 és/vagyDy2O3 őxidő(ka)t alkalmaznak, csökken a vágóél végének hőmlőkőldalibemaródása (kőpása), és nő a lökésszerű termikűs igénybevétellelszembeni ellenállóképesség, tehát a találmány szerinti szerszámőt ahagyőmányős szilíciűm-nitrid vágószerszámőkhőz képest növeltélettartam jellemzi. ŕ
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9033181A JPH09268071A (ja) | 1996-02-02 | 1997-01-31 | 炭窒化チタン複合窒化珪素工具 |
Publications (3)
Publication Number | Publication Date |
---|---|
HU9700936D0 HU9700936D0 (en) | 1997-07-28 |
HUP9700936A2 true HUP9700936A2 (hu) | 1999-06-28 |
HUP9700936A3 HUP9700936A3 (en) | 2002-01-28 |
Family
ID=12379344
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU9700936A HUP9700936A3 (en) | 1997-01-31 | 1997-05-22 | Titanium carbo-nitride complex silicon nitride tool |
Country Status (7)
Country | Link |
---|---|
US (1) | US6010777A (hu) |
EP (1) | EP0856498B1 (hu) |
KR (1) | KR100481075B1 (hu) |
DE (1) | DE69710173T2 (hu) |
ES (1) | ES2167639T3 (hu) |
HU (1) | HUP9700936A3 (hu) |
PL (1) | PL184535B1 (hu) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR19990075035A (ko) * | 1998-03-17 | 1999-10-05 | 유창종 | 탄질화티탄기 복합 탄질화물 세라믹 소결체및 이의 제조방법 |
JP2948803B1 (ja) * | 1998-03-31 | 1999-09-13 | 日本特殊陶業株式会社 | サーメット工具及びその製造方法 |
US20040144874A1 (en) * | 2003-01-24 | 2004-07-29 | Moskowitz Joel P. | Method and apparatus for making high purity silica powder by ball milling |
JP4975481B2 (ja) * | 2007-02-27 | 2012-07-11 | トーヨーエイテック株式会社 | プレス用金型 |
CN114538930B (zh) * | 2022-03-23 | 2023-01-17 | 山东大学 | 一种裂纹自愈合梯度功能陶瓷刀具材料及其制备方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5632377A (en) * | 1979-08-20 | 1981-04-01 | Mitsubishi Metal Corp | Silicon nitride base sintered material for cutting tool |
JPS5895662A (ja) * | 1981-11-30 | 1983-06-07 | 京セラ株式会社 | 窒化珪素と窒化チタニウム複合焼結体 |
US4406667A (en) * | 1982-05-20 | 1983-09-27 | Gte Laboratories Incorporated | Nitride coated composite silicon nitride cutting tools |
US4416670A (en) * | 1982-05-20 | 1983-11-22 | Gte Laboratories Incorporated | Carbide coated composite silicon nitride cutting tools |
KR870000309B1 (ko) * | 1984-05-29 | 1987-02-26 | 한국과학기술원 | 절삭 공구용 질화규소 소결체 및 그의 제조 방법 |
DE3420848A1 (de) * | 1984-06-05 | 1985-12-05 | Gebr. Happich Gmbh, 5600 Wuppertal | Verfahren und vorrichtung zum anbringen von endstuecken an kunststoff-profilleisten |
JPS61101482A (ja) * | 1984-10-23 | 1986-05-20 | 住友電気工業株式会社 | 窒化珪素切削工具 |
JPS6117473A (ja) * | 1985-05-17 | 1986-01-25 | 三菱マテリアル株式会社 | 切削工具用窒化けい素基焼結材料 |
US5250477A (en) * | 1986-08-04 | 1993-10-05 | Gte Valenite Corporation | Silicon nitride based composite with improved fracture toughness |
JPH0625039B2 (ja) * | 1988-07-08 | 1994-04-06 | 日本タングステン株式会社 | 窒化珪素質焼結体及びその製造方法 |
ES2084850T3 (es) * | 1991-02-15 | 1996-05-16 | Sumitomo Electric Industries | Herramienta de nitruro de silicio sinterizado. |
JPH057122A (ja) * | 1991-09-25 | 1993-01-14 | Murata Mfg Co Ltd | 電子部品 |
JPH06122563A (ja) * | 1992-10-12 | 1994-05-06 | Sumitomo Electric Ind Ltd | セラミックス複合材料及びその製造方法 |
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1997
- 1997-05-14 US US08/856,164 patent/US6010777A/en not_active Expired - Fee Related
- 1997-05-20 DE DE69710173T patent/DE69710173T2/de not_active Expired - Fee Related
- 1997-05-20 ES ES97108146T patent/ES2167639T3/es not_active Expired - Lifetime
- 1997-05-20 EP EP97108146A patent/EP0856498B1/en not_active Expired - Lifetime
- 1997-05-22 HU HU9700936A patent/HUP9700936A3/hu unknown
- 1997-06-10 PL PL97320470A patent/PL184535B1/pl not_active IP Right Cessation
- 1997-07-19 KR KR1019970033793A patent/KR100481075B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
HUP9700936A3 (en) | 2002-01-28 |
KR19980069846A (ko) | 1998-10-26 |
EP0856498A3 (en) | 1998-12-30 |
ES2167639T3 (es) | 2002-05-16 |
PL320470A1 (en) | 1998-08-03 |
KR100481075B1 (ko) | 2005-07-21 |
US6010777A (en) | 2000-01-04 |
HU9700936D0 (en) | 1997-07-28 |
EP0856498B1 (en) | 2002-01-30 |
EP0856498A2 (en) | 1998-08-05 |
DE69710173T2 (de) | 2002-11-28 |
DE69710173D1 (de) | 2002-03-14 |
PL184535B1 (pl) | 2002-11-29 |
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