HUP0302152A2 - Titán-cirkónium katalizátorok, elżállítási eljárásuk és alkalmazásuk észterek vagy poliészterek elżállítására - Google Patents

Titán-cirkónium katalizátorok, elżállítási eljárásuk és alkalmazásuk észterek vagy poliészterek elżállítására

Info

Publication number
HUP0302152A2
HUP0302152A2 HU0302152A HUP0302152A HUP0302152A2 HU P0302152 A2 HUP0302152 A2 HU P0302152A2 HU 0302152 A HU0302152 A HU 0302152A HU P0302152 A HUP0302152 A HU P0302152A HU P0302152 A2 HUP0302152 A2 HU P0302152A2
Authority
HU
Hungary
Prior art keywords
titanium
zirconium
catalysts
orthoester
produced
Prior art date
Application number
HU0302152A
Other languages
English (en)
Inventor
Erika Bauer
Andreas Hoffmann
Hartmut Nefzger
Original Assignee
Bayer Ag.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag. filed Critical Bayer Ag.
Publication of HUP0302152A2 publication Critical patent/HUP0302152A2/hu
Publication of HUP0302152A3 publication Critical patent/HUP0302152A3/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C08G18/4241—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols from dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Az észterezési, átészterezési és polikondenzációs reakciókban egyszerűösszetételű, nagy aktivitású, megfelelő oldhatóságú és hidrolízisselszemben ellenálló katalizátorokra van igény, amelyek gyakran szervestitánvegyületek. A találmány tárgyát új típusú titán-cirkóniumkatalizátorok képezik. A találmány szerinti titán-cirkóniumkatalizátorok a) titán és/vagy cirkónium ortoészterek vagy kondenzáltortoészterek b) egy vagy több, legalább két hidroxilcsoporttal éslegalább 180g/mol szám szerinti átlagos molekulatömeggel rendelkezőpolialkohollal való reakciójával állíthatók elő, ahol a b) pofialkoholmólaránya az a) titán és/vagy cirkónium ortoészterre vagy kondenzáltortoészterre vonatkoztatva legalább 2:1. Egy előnyös megvalósításbanaz alkalmazott ortoészter titán-tetraizopropoxilát és titán-tetra-n-butoxilát, az alkalmazott kondenzált ortoészter poli(titán-izopropoxilát) és poli(titán-butoxilát) lehet. Az alkalmazottpofialkoholok lehetnek polifunkciós kiindulási vegyületekre alkilén-oxidok poliaddíciójával előállított poliéter-poliolok vagy poliészter-poliolok, amelyek aromás és/vagy alifás pofikarbonsavakból és legalábbkét hidroxilcsoportot tartalmazó poliolokból állíthatók elő. Atalálmány további tárgya a katalizátorok alkalmazása észterezésireakciókban, átészterezési reakciókban és polikondenzációs reakciókbanészterek vagy poliészterek előállítására. Ó
HU0302152A 2000-12-01 2001-11-19 Titanium/zirconium catalysts and use thereof for production of esters or polyesters HUP0302152A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10059612A DE10059612A1 (de) 2000-12-01 2000-12-01 Titan-/Zirkonium-Katalysatoren sowie deren Verwendung zur Herstellung von Estern oder Polyestern
PCT/EP2001/013341 WO2002044243A1 (de) 2000-12-01 2001-11-19 Titan-/zirkonium-katalysatoren sowie deren verwendung zur herstellung von estern oder polyestern

Publications (2)

Publication Number Publication Date
HUP0302152A2 true HUP0302152A2 (hu) 2003-09-29
HUP0302152A3 HUP0302152A3 (en) 2004-04-28

Family

ID=7665335

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0302152A HUP0302152A3 (en) 2000-12-01 2001-11-19 Titanium/zirconium catalysts and use thereof for production of esters or polyesters

Country Status (14)

Country Link
US (1) US6541411B2 (hu)
EP (1) EP1339774B1 (hu)
JP (1) JP4098084B2 (hu)
KR (1) KR100799032B1 (hu)
CN (1) CN1240748C (hu)
AT (1) ATE384752T1 (hu)
AU (1) AU2002223683A1 (hu)
DE (2) DE10059612A1 (hu)
ES (1) ES2299535T3 (hu)
HK (1) HK1063328A1 (hu)
HU (1) HUP0302152A3 (hu)
PL (1) PL361838A1 (hu)
PT (1) PT1339774E (hu)
WO (1) WO2002044243A1 (hu)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030084183A (ko) * 2002-04-25 2003-11-01 켐엔텍 주식회사 폴리에스테르의 제조방법
US6841505B2 (en) * 2002-07-26 2005-01-11 E..I. Du Pont De Nemours And Company Titanium-zirconium catalyst compositions and use thereof
DE102004020582B4 (de) * 2004-04-27 2020-01-30 Lurgi Zimmer Gmbh Polykondensationsverfahren unter Verwendung eines Katalysators und dafür geeigneter Katalysator
US8455608B2 (en) 2010-02-26 2013-06-04 Basf Se Catalyzed pellet heat treatment for thermoplastic polyurethanes
CN102770473B (zh) 2010-02-26 2015-02-18 巴斯夫欧洲公司 热塑性聚氨酯的催化颗粒热处理
CN104039859B (zh) 2011-12-20 2017-03-01 科思创德国股份有限公司 羟基氨基聚合物及其制备方法
CN112920387A (zh) * 2019-12-05 2021-06-08 中国科学院成都有机化学有限公司 一种合成聚对苯二甲酸丙二醇酯的催化剂、制备方法及聚对苯二甲酸丙二醇酯
US20220332940A1 (en) * 2021-04-14 2022-10-20 Chang Chun Plastics Co., Ltd. Polyester composition and method for preparing the same, product and application

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2822348A (en) 1951-11-14 1958-02-04 Du Pont Ester interchange catalysts
US3047515A (en) * 1956-07-09 1962-07-31 Goodyear Tire & Rubber Preparation of polyesters using titanium-containing catalysts
GB1590291A (en) * 1977-09-12 1981-05-28 Teijin Ltd Process for the preparation of polyesters
US4705764A (en) * 1985-10-03 1987-11-10 Research Development Corporation Of Japan Esterification and/or ester interchange catalyst
FR2602229B1 (fr) * 1986-07-31 1988-09-09 Charbonnages Ste Chimique Procede de preparation d'esters d'acides carboxyliques insatures
US5097004A (en) * 1990-05-11 1992-03-17 E. I. Du Pont De Nemours And Company Novel polyesters and their use in compostable products such as disposable diapers
US5605940A (en) * 1995-02-13 1997-02-25 The Celotex Corporation High equivalent weight polyester polyols for closed cell, rigid foams
GB9612161D0 (en) * 1996-06-11 1996-08-14 Tioxide Specialties Ltd Esterification process
GB9725419D0 (en) * 1997-12-02 1998-01-28 Tioxide Specialties Ltd Esterification catalysts
US6080834A (en) 1999-04-16 2000-06-27 E. I. Du Pont De Nemours And Company Titanium-containing catalyst composition and processes therefor and therewith

Also Published As

Publication number Publication date
KR100799032B1 (ko) 2008-01-28
EP1339774B1 (de) 2008-01-23
US6541411B2 (en) 2003-04-01
ATE384752T1 (de) 2008-02-15
DE50113540D1 (de) 2008-03-13
CN1478116A (zh) 2004-02-25
CN1240748C (zh) 2006-02-08
HK1063328A1 (en) 2004-12-24
JP4098084B2 (ja) 2008-06-11
HUP0302152A3 (en) 2004-04-28
DE10059612A1 (de) 2002-06-20
PL361838A1 (en) 2004-10-04
EP1339774A1 (de) 2003-09-03
ES2299535T3 (es) 2008-06-01
JP2004514771A (ja) 2004-05-20
KR20030068165A (ko) 2003-08-19
AU2002223683A1 (en) 2002-06-11
PT1339774E (pt) 2008-04-15
WO2002044243A1 (de) 2002-06-06
US20020107143A1 (en) 2002-08-08

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