HRP20220504T1 - Integrirana proizvodnja uree za ispušne tekućine dizela i urea amonijev nitrat - Google Patents

Integrirana proizvodnja uree za ispušne tekućine dizela i urea amonijev nitrat Download PDF

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Publication number
HRP20220504T1
HRP20220504T1 HRP20220504TT HRP20220504T HRP20220504T1 HR P20220504 T1 HRP20220504 T1 HR P20220504T1 HR P20220504T T HRP20220504T T HR P20220504TT HR P20220504 T HRP20220504 T HR P20220504T HR P20220504 T1 HRP20220504 T1 HR P20220504T1
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Croatia
Prior art keywords
urea
ammonium nitrate
solution
specified
ammonia
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HRP20220504TT
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English (en)
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Joey DOBREE
Johannes Henricus Mennen
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Stamicarbon B.V.
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Publication of HRP20220504T1 publication Critical patent/HRP20220504T1/hr

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/002Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2455Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/18Nitrates of ammonium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/18Nitrates of ammonium
    • C01C1/185Preparation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C1/00Ammonium nitrate fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • C05G5/23Solutions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/02Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/02Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
    • C07C273/04Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/02Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
    • C07C273/10Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds combined with the synthesis of ammonia
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/02Salts; Complexes; Addition compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00105Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals

Claims (7)

1. Proces za integriranu proizvodnju urea amonijevog nitrata i vodene otopine uree prikladne za uporabu u postrojenju za smanjenje NOx, koji se sastoji od koraka - reakcija dušične kiseline i amonijaka u jedinici za proizvodnju amonijevog nitrata pod uvjetima tako da se dobije vodena otopina amonijevog nitrata; - reakcija ugljičnog dioksida i amonijaka u uvjetima stvaranja uree tako da se dobije reakcijska otopina koja sadrži vodu, ureu, amonijev karbamat, i neizreagirani CO2 i NH3; - podvrgavanje navedene reakcijske otopine uklanjanju tako da se dobije neizreagirani amonijak i ugljični dioksid, te očišćena reakcijska otopina; recirkuliranje navedenog dohvaćenog amonijaka i ugljičnog dioksida kao početnih materijala za stvaranje uree; - podvrgavanje navedene očišćene reakcijske otopine odvajanju tako da se dobije vodena struja uree i struja plina koja sadrži CO2 i NH3; - dovod NH3 iz navedene struje plina kao reaktanta u navedenu jedinicu za proizvodnju amonijevog nitrata; - miješanje barem dijela navedene vodene struje uree s navedenom vodenom otopinom amonijevog nitrata tako da se dobije otopina urea amonijevog nitrata; - razrjeđivanje dobivenog dijela vodene struje uree s demineraliziranom vodom tako da se dobije navedena otopina prikladna za korištenje u jedinici za redukciju NOx.
2. Postupak za integriranu proizvodnju urea amonijevog nitrata i praha krute uree koji je prikladan za pretvorbu razrjeđivanjem s demineraliziranom vodom u otopinu prikladnu za uporabu u jedinici za redukciju NOx, koji se sastoji od koraka - reakcija dušične kiseline i amonijaka u jedinici za proizvodnju amonijevog nitrata pod uvjetima tako da se dobije vodena otopina amonijevog nitrata; - reakcija ugljičnog dioksida i amonijaka u uvjetima stvaranja uree tako da se dobije reakcijska otopina koja sadrži vodu, ureu, amonijev karbamat i neizreagirani CO2 i NH3; - podvrgavanje navedene reakcijske otopine uklanjanju tako da se dobije neizreagirani amonijak i ugljični dioksid, te očišćena reakcijska otopina; recirkuliranje navedenog dohvaćenog amonijaka i ugljičnog dioksida kao početnih materijala za stvaranje uree; - podvrgavanje navedene očišćene reakcijske otopine odvajanju tako da se dobije vodena struja uree, i struja plina koja sadrži CO2 i NH3; - dovod NH3 iz navedene struje plina kao reaktanta u navedenu jedinicu za proizvodnju amonijevog nitrata; - miješanje barem dijela navedene vodene struje uree s navedenom vodenom otopinom amonijevog nitrata tako da se dobije otopina urea amonijevog nitrata; - podvrgavanje dijela vodene struje uree, dobivene odvajanjem reakcijske otopine uree, brzoj kristalizaciji tako da se formira navedeni prah krute uree.
3. Postupak prema zahtjevu 1 ili 2, naznačen time što otopina urea amonijevog nitrata sadrži od 29 tež. % do 38 tež. % uree i od 36 tež. % do 46 tež. % amonijevog nitrata, i pri čemu dio vodene struje uree pomiješane s otopinom amonijevog nitrata je u količini koja je barem dovoljna da osigura količinu uree koja odgovara količini amonijevog nitrata koja se može dobiti količinom NH3 koji se dovodi u jedinicu za proizvodnju amonijaka.
4. Postupak prema zahtjevu 1 ili 2, naznačen time što se urea proizvodi korištenjem potopljenog kondenzatora/reaktora.
5. Postupak prema zahtjevu 2, naznačen time što se flash kristalizacija provodi pri tlaku ispod 15 kPa.
6. Postupak prema zahtjevu 2, naznačen time što je flash kristalizacija suho ispiranje koje se provodi u posudi za suho ispiranje koja radi pri tlaku u rasponu od 1 do 15 kPa, pri čemu se u navedenoj posudi za suho ispiranje otopina uree distribuira pomoću razdjelnika tekućine.
7. Postupak prema zahtjevu 1 ili 2, naznačen time što se korak reakcije ugljičnog dioksida i amonijaka pod uvjetima stvaranja uree provodi u sekciji za sintezu uree koja sadrži najmanje jedan reaktor, dio za odvajanje, i kondenzator, pri čemu navedeni najmanje jedan reaktor, dio za odvajanje i kondenzator rade pod visokim tlakom (HP).
HRP20220504TT 2015-03-25 2016-03-29 Integrirana proizvodnja uree za ispušne tekućine dizela i urea amonijev nitrat HRP20220504T1 (hr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15160826 2015-03-25
EP16730029.2A EP3274297B1 (en) 2015-03-25 2016-03-29 Integrated production of urea for diesel exhaust fluid and urea ammonium nitrate
PCT/NL2016/050213 WO2016153354A1 (en) 2015-03-25 2016-03-29 Integrated production of urea for diesel exhaust fluid and urea ammonium nitrate

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HRP20220504T1 true HRP20220504T1 (hr) 2022-06-24

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US (2) US11083976B2 (hr)
EP (2) EP4015455B1 (hr)
CN (1) CN108137335B (hr)
EA (2) EA036463B1 (hr)
HR (1) HRP20220504T1 (hr)
HU (1) HUE058722T2 (hr)
PL (1) PL3274297T3 (hr)
SA (2) SA522431894B1 (hr)
WO (1) WO2016153354A1 (hr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3323805A1 (en) * 2016-11-18 2018-05-23 Casale SA A process for integrated production of urea and urea-ammonium nitrate
AU2018366077B2 (en) 2017-11-10 2021-07-08 Stamicarbon B.V. Urea production process and plant
CN113651674A (zh) * 2020-05-12 2021-11-16 淮北师范大学 用硫酸二甲酯蒸馏釜残液制备硫酸铵和甲醇的系统和方法
EP4294556A1 (en) 2021-02-22 2023-12-27 Stamicarbon B.V. Urea production process and plant with parallel mp units
US20240059623A1 (en) 2022-02-15 2024-02-22 Stamicarbon B.V. Stripping-type urea plant for def production

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2087325A (en) * 1933-09-13 1937-07-20 Solvay Process Co Process for the production of urea and ammonium salts
NL165712C (nl) * 1970-05-30 1981-05-15 Stamicarbon Werkwijze en inrichting voor het bij synthesedruk terug- winnen van ammoniak en kooldioxyde uit het spuigas van een ureumsynthese.
NL7612162A (nl) * 1976-11-03 1978-05-08 Unie Van Kunstmestfab Bv Werkwijze voor de bereiding van een ureum- oplossing uit nh3 en co2.
US4174379A (en) * 1978-04-13 1979-11-13 Foster Wheeler Energy Corporation Manufacture of ammonium nitrate
NL1028497C2 (nl) * 2005-03-09 2006-09-12 Dsm Ip Assets Bv Werkwijze voor de bereiding van een ureum-bevattende waterige stroom.
EP1923383A1 (en) * 2006-11-20 2008-05-21 Urea Casale S.A. Method for the modernization of a urea production plant
EP2153880A1 (en) * 2008-07-31 2010-02-17 Urea Casale S.A. Process and plant for the production of a urea solution for use in SCR process for reduction of Nox
GEP20166500B (en) * 2011-10-14 2016-06-27 Stamicarbon Method for urea final processing
EP2784062A1 (en) * 2013-03-27 2014-10-01 Urea Casale SA Method for revamping a self-stripping urea plant
JP2016064991A (ja) * 2014-09-22 2016-04-28 東洋エンジニアリング株式会社 尿素製造プロセスにおける高純度尿素水溶液の製造方法
WO2016085343A1 (en) * 2014-11-27 2016-06-02 Stamicarbon B.V. Method and plant for producing urea-ammonium nitrate (uan)

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Publication number Publication date
HUE058722T2 (hu) 2022-09-28
EA201990748A1 (ru) 2019-08-30
EP4015455A1 (en) 2022-06-22
EP3274297B1 (en) 2022-03-30
US20180071653A1 (en) 2018-03-15
EA036463B1 (ru) 2020-11-12
CN108137335B (zh) 2021-10-26
PL3274297T3 (pl) 2022-06-13
US11083976B2 (en) 2021-08-10
EA201792117A1 (ru) 2018-02-28
EP4015455B1 (en) 2024-03-20
WO2016153354A8 (en) 2018-03-08
US20210331086A1 (en) 2021-10-28
WO2016153354A1 (en) 2016-09-29
CN108137335A (zh) 2018-06-08
SA517390004B1 (ar) 2022-08-03
WO2016153354A9 (en) 2016-11-10
SA522431894B1 (ar) 2023-03-01
EA037089B1 (ru) 2021-02-04
EP3274297A1 (en) 2018-01-31

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