HRP20201258T1 - Fenolska smola, postupak pripreme, sastav za lijepljenje mineralnih vlakana i rezultirajući proizvod - Google Patents
Fenolska smola, postupak pripreme, sastav za lijepljenje mineralnih vlakana i rezultirajući proizvod Download PDFInfo
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- HRP20201258T1 HRP20201258T1 HRP20201258TT HRP20201258T HRP20201258T1 HR P20201258 T1 HRP20201258 T1 HR P20201258T1 HR P20201258T T HRP20201258T T HR P20201258TT HR P20201258 T HRP20201258 T HR P20201258T HR P20201258 T1 HRP20201258 T1 HR P20201258T1
- Authority
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- Croatia
- Prior art keywords
- equal
- glycine
- formaldehyde
- phenol
- resin
- Prior art date
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- 238000000034 method Methods 0.000 title claims 9
- 239000000203 mixture Substances 0.000 title claims 9
- 239000002557 mineral fiber Substances 0.000 title claims 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title claims 2
- 239000005011 phenolic resin Substances 0.000 title claims 2
- 229920001568 phenolic resin Polymers 0.000 title claims 2
- 238000004513 sizing Methods 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 22
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 18
- 239000004471 Glycine Substances 0.000 claims 10
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 10
- 229920005989 resin Polymers 0.000 claims 8
- 239000011347 resin Substances 0.000 claims 8
- 150000001875 compounds Chemical class 0.000 claims 6
- 238000006243 chemical reaction Methods 0.000 claims 4
- 238000004026 adhesive bonding Methods 0.000 claims 3
- 239000007788 liquid Substances 0.000 claims 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 2
- 125000003277 amino group Chemical group 0.000 claims 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 2
- 239000004202 carbamide Substances 0.000 claims 2
- 238000010790 dilution Methods 0.000 claims 2
- 239000012895 dilution Substances 0.000 claims 2
- 239000008103 glucose Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 238000006683 Mannich reaction Methods 0.000 claims 1
- 239000000654 additive Chemical group 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 150000001720 carbohydrates Chemical class 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 1
- 150000003141 primary amines Chemical class 0.000 claims 1
- 239000012429 reaction media Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 150000003335 secondary amines Chemical class 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
- C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
- C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
- C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/34—Condensation polymers of aldehydes, e.g. with phenols, ureas, melamines, amides or amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
- C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
- C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
- C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
- C08G14/10—Melamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C08L61/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C09J161/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Nonwoven Fabrics (AREA)
Claims (19)
1. Tekuća smola, koja se koristi za izradu sastava za lijepljenje mineralnih vlakana, naznačena time da se bitno sastoji od kondenzata feno-formaldehida (PF) i kondenzata feno-formaldehid-glicina (PFG).
2. Smola prema zahtjevu 1, naznačena time da sadrži razinu slobodnog formaldehida najviše jednaku 0,5% ukupne težine tekućine, poželjno najviše jednako 0,3%, a poželjnije najviše jednaku 0,1%
3. Smola prema zahtjevu 1 ili 2, naznačena time da sadrži razinu slobodnog fenola manju ili jednaku 0,5% ukupne težine tekućine, poželjno manju ili jednaku 0,3% a poželjnije manju ili jednaku 0,1%.
4. Smola prema jednom od zahtjeva 1 do 3, naznačena time da ima pH, izmjeren na 20°C, koji varira od 4 do 11, poželjno od 6,5 do 9,0, a poželjnije od 7,5 do 8,3.
5. Smola prema jednom od zahtjeva 1 do 4, naznačena time da pokazuje razrjedivost vodom, pri 20°C, veću ili jednaku 2000%
6. Postupak pripreme smole prema jednom od zahtjeva 1 do 5, naznačen time da sadrži korak reakcije fenola i formaldehida u prisutnosti bazičnog katalizatora, u molarnom omjeru formaldehid/fenol većem od 1, radi stvaranja PF kondenzata, a zatim korak unosa glicina u reakcijsku smjesu koji reagira sa slobodnim formaldehidom, slobodnim fenolom i PF kondenzatima u skladu s Mannichovom reakcijom .
7. Postupak prema zahtjevu 6, naznačen time da formaldehid i fenol reagiraju u molarnom omjeru formaldehid/fenol koji varira od 2 do 4, poželjno je manji od 3, a poželjnije varira od 2,50 do 2,65.
8. Postupak prema zahtjevu 7, naznačen time da se reakcija fenola i formaldehida nastavlja sve dok stupanj konverzije fenola ne bude veći ili jednak 93%, poželjno veći ili jednak 95 %, a poželjnije veći ili jednak 97%.
9. Postupak prema jednom od zahtjeva 6 do 8, naznačen time da se reakcija između fenola i formaldehida provodi pri temperaturi koja varira od 60 do 75°C, poželjno oko 70°C.
10. Postupak prema jednom od zahtjeva 6 do 9, naznačen time da se glicin postupno unosi u reakcijski medij, a temperatura u vrijeme dodavanja glicina održava se konstantnom tijekom razdoblja kondenzacije glicina, razrjedivost smole vodom mora ostati najmanje jednaka 1000%.
11. Postupak prema jednom od zahtjeva 6 do 10, naznačen time da se dodavanje glicina vrši u količini od 0,5 do 20% mase ukupne količine glicina po minuti, poželjno 1 do 10%, a poželjnije 2,8 do 4%.
12. Postupak prema jednom od zahtjeva 6 do 11, naznačen time da količina glicina predstavlja 0,1 do 0,5 mola glicina po molu početnog fenola, poželjno 0,2 do 0,3 mola.
13. Postupak prema jednom od zahtjeva 6 do 12, naznačen time da je nakon uvođenja glicina temperatura održavana konstantnom 10 do 180 minuta, poželjno najmanje 30 minuta i poželjnije 60 do 120 minuta.
14. Vodenasti sastav za lijepljenje mineralnih vlakana koji sadrži fenolnu smolu prema jednom od zahtjeva 1 do 5, najmanje jedan spoj koji sadrži najmanje jednu hidroksi ili aminsku funkcionalnu skupinu i aditive za lijepljenje.
15. Sastav prema zahtjevu 14, naznačen time da navedeni spoj sadrži najmanje 2 funkcionalne skupine hidroksi i/ili amina.
16. Sastav prema zahtjevu 14 ili 15, naznačen time da se navedeni spoj bira između saharida i primarnih ili sekundarnih amina.
17. Sastav prema zahtjevu 16, naznačen time da je navedeni spoj glukoza, urea ili mješavina glukoze i uree
18. Sastav prema jednom od zahtjeva 14 do 17, naznačen time da količina navedenog spoja varira od 1 do 40 masenih dijelova na 100 masenih dijelova smole i navedenog spoja, izračunato na osnovi suhe težine.
19. Izolacijski proizvod, posebice zvučni i/ili toplinski, sadržeći mineralna vlakna slijepljena pomoću sastava za lijepljenje prema jednom od zahtjeva 14 do 18.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1056803A FR2964105B1 (fr) | 2010-08-27 | 2010-08-27 | Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produit resultant. |
| EP11761672.2A EP2609129B8 (fr) | 2010-08-27 | 2011-08-26 | Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produit resultant. |
| PCT/FR2011/051969 WO2012025699A1 (fr) | 2010-08-27 | 2011-08-26 | Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produit resultant. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20201258T1 true HRP20201258T1 (hr) | 2020-11-13 |
Family
ID=43902632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20201258TT HRP20201258T1 (hr) | 2010-08-27 | 2020-08-11 | Fenolska smola, postupak pripreme, sastav za lijepljenje mineralnih vlakana i rezultirajući proizvod |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US9580354B2 (hr) |
| EP (1) | EP2609129B8 (hr) |
| JP (2) | JP6001536B2 (hr) |
| KR (1) | KR101838974B1 (hr) |
| CN (1) | CN103221443B (hr) |
| AU (1) | AU2011294930B2 (hr) |
| BR (1) | BR112013004571B1 (hr) |
| CA (1) | CA2809427C (hr) |
| CL (1) | CL2013000565A1 (hr) |
| CO (1) | CO6700828A2 (hr) |
| DK (1) | DK2609129T3 (hr) |
| ES (1) | ES2808330T3 (hr) |
| FR (1) | FR2964105B1 (hr) |
| HR (1) | HRP20201258T1 (hr) |
| LT (1) | LT2609129T (hr) |
| PL (1) | PL2609129T3 (hr) |
| RU (1) | RU2572960C2 (hr) |
| SI (1) | SI2609129T1 (hr) |
| UA (1) | UA111171C2 (hr) |
| WO (1) | WO2012025699A1 (hr) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201016565D0 (en) | 2010-10-01 | 2010-11-17 | Dynea Oy | Low free formaldehyde resins for abrasive products |
| BR112013013409A2 (pt) * | 2010-12-06 | 2016-09-06 | Rockwool Int | "método de reduzir a emissão de formaldeído de um produto de fibra mineral, e produto de fibra mineral com emissão de formaldeído reduzida" |
| GB201120137D0 (en) * | 2011-11-22 | 2012-01-04 | Dynea Oy | Modified binder compositions |
| EP2657266A1 (en) | 2012-04-27 | 2013-10-30 | URSA Insulation, S.A. | Process for the preparation of a phenol-formaldehyde resin having a low amount of free formaldehyde, a phenol-formaldehyde resin resulting from this process, and the use of this resin as a binder for mineral wool insulation products |
| EP2657203A1 (en) | 2012-04-27 | 2013-10-30 | URSA Insulation, S.A. | Process for the production of a phenol-formaldehyde resin having low free-formaldehyde content, the phenol-formaldehyde resin resulting from this process, and its use as a binder for mineral wool insulation products |
| EP2865799B1 (en) | 2013-10-25 | 2018-07-04 | URSA Insulation, S.A. | Method for the manufacture of mineral wool insulation products having low formaldehyde emissions |
| KR101861404B1 (ko) * | 2014-06-10 | 2018-05-29 | 주식회사 케이씨씨 | 수성 복합 접착제 조성물 및 이를 사용하여 섬유상 재료를 결속하는 방법 |
| WO2016069970A1 (en) * | 2014-10-30 | 2016-05-06 | Ppg Industries Ohio, Inc. | Amino acid-containing sizing compositions for glass fibers and sized fiber glass products |
| DE202015000192U1 (de) | 2015-01-16 | 2016-04-20 | Saint-Gobain Isover | Phenol-Formaldehydharz-gebundenes Mineralwollprodukt |
| CN105131877B (zh) * | 2015-08-24 | 2017-10-10 | 江西省科学院应用化学研究所 | 一种硅烷改性酚醛树脂胶黏剂 |
| CN107189338A (zh) * | 2017-06-13 | 2017-09-22 | 长兴华悦耐火材料厂 | 一种耐火材料用复合结合剂及其制备方法 |
| EP3489302A1 (en) | 2017-11-22 | 2019-05-29 | Prefere Resins Holding GmbH | Solid phenolic aldehyde resin composition with reduced aldehyde release, solid curing composition and method for curing a phenolic aldehyde resin and article obtained therefrom |
| CN108892919A (zh) * | 2018-04-16 | 2018-11-27 | 安徽昊森新材料科技有限公司 | 一种轻质隔音酚醛树脂 |
| CN110862499A (zh) * | 2019-11-27 | 2020-03-06 | 山东阳谷华泰化工股份有限公司 | 一种氨基酸改性烷基酚-甲醛树脂及其制备方法 |
| EP3835276A1 (en) | 2019-12-10 | 2021-06-16 | Saint-Gobain Isover | Method for producing mineral wool composites |
| FR3105233B1 (fr) * | 2019-12-19 | 2021-12-17 | Commissariat Energie Atomique | Procédé de préparation d’une résine phénolique de type résol à teneur en formaldéhyde réduite |
| EP4253441A1 (en) * | 2020-11-26 | 2023-10-04 | Sumitomo Bakelite Co., Ltd. | Phenolic resin composition and method for producing same |
| CN118284636A (zh) | 2021-11-25 | 2024-07-02 | 住友电木株式会社 | 酚醛树脂组合物和物品 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2555591B1 (fr) | 1983-11-29 | 1986-09-26 | Saint Gobain Isover | Resine pour une composition d'encollage, son procede de fabrication et la composition d'encollage obtenue |
| US5270434A (en) | 1990-10-12 | 1993-12-14 | Isover Saint-Gobain | Phenolic resin, procedure for preparation of the resin, and sizing composition for mineral fibers containing this resin |
| FR2667865B1 (fr) * | 1990-10-12 | 1992-12-11 | Saint Gobain Isover | Resine phenolique, procede de preparation de la resine et composition d'encollage de fibres minerales la contenant. |
| US5705537A (en) * | 1997-02-24 | 1998-01-06 | Armstrong World Industries, Inc. | Phenolic foams having a low formaldehyde evolution |
| FR2766201A1 (fr) * | 1997-07-15 | 1999-01-22 | Saint Gobain Isover | Resine phenolique pour composition d'encollage, procede de preparation et composition d'encollage la contenant |
| US6362275B1 (en) * | 2000-12-12 | 2002-03-26 | Ashland Inc. | Reduction of free formaldehyde in aldehyde resins |
| FR2842815B1 (fr) | 2002-07-25 | 2007-06-22 | Saint Gobain Isover | Solution aqueuse de resine compose phenolique-formaldhehyde- aminoalcool, procede de preparation, composition d'encollage de fibres minerales renfermant ladite resine et produits resultants |
| WO2008005729A2 (en) * | 2006-06-30 | 2008-01-10 | Georgia-Pacific Chemicals Llc | Reducing formaldehyde emissions from fiberglass insulation |
| FR2907123B1 (fr) | 2006-10-11 | 2008-12-05 | Saint Gobain Isover Sa | Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produits resultants |
| FR2907122B1 (fr) * | 2006-10-11 | 2008-12-05 | Saint Gobain Isover Sa | Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produits resultants |
| FR2929952B1 (fr) * | 2008-04-11 | 2011-02-11 | Saint Gobain Isover | Composition d'encollage pour fibres minerales et produits resultants |
-
2010
- 2010-08-27 FR FR1056803A patent/FR2964105B1/fr not_active Expired - Fee Related
-
2011
- 2011-08-26 KR KR1020137005363A patent/KR101838974B1/ko active IP Right Grant
- 2011-08-26 CN CN201180051963.9A patent/CN103221443B/zh active Active
- 2011-08-26 AU AU2011294930A patent/AU2011294930B2/en active Active
- 2011-08-26 RU RU2013113582/05A patent/RU2572960C2/ru active
- 2011-08-26 EP EP11761672.2A patent/EP2609129B8/fr active Active
- 2011-08-26 LT LTEP11761672.2T patent/LT2609129T/lt unknown
- 2011-08-26 CA CA2809427A patent/CA2809427C/fr active Active
- 2011-08-26 PL PL11761672T patent/PL2609129T3/pl unknown
- 2011-08-26 DK DK11761672.2T patent/DK2609129T3/da active
- 2011-08-26 ES ES11761672T patent/ES2808330T3/es active Active
- 2011-08-26 US US13/819,127 patent/US9580354B2/en active Active
- 2011-08-26 BR BR112013004571A patent/BR112013004571B1/pt active IP Right Grant
- 2011-08-26 JP JP2013526528A patent/JP6001536B2/ja active Active
- 2011-08-26 UA UAA201303717A patent/UA111171C2/uk unknown
- 2011-08-26 WO PCT/FR2011/051969 patent/WO2012025699A1/fr active Application Filing
- 2011-08-26 SI SI201131899T patent/SI2609129T1/sl unknown
-
2013
- 2013-02-27 CL CL2013000565A patent/CL2013000565A1/es unknown
- 2013-03-15 CO CO13052186A patent/CO6700828A2/es unknown
-
2016
- 2016-07-01 JP JP2016131635A patent/JP2016180115A/ja not_active Withdrawn
-
2020
- 2020-08-11 HR HRP20201258TT patent/HRP20201258T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR101838974B1 (ko) | 2018-03-16 |
| CA2809427A1 (fr) | 2012-03-01 |
| KR20130100117A (ko) | 2013-09-09 |
| FR2964105B1 (fr) | 2012-09-28 |
| JP6001536B2 (ja) | 2016-10-05 |
| RU2013113582A (ru) | 2014-10-10 |
| PL2609129T3 (pl) | 2020-11-16 |
| CN103221443A (zh) | 2013-07-24 |
| AU2011294930A1 (en) | 2013-04-18 |
| CL2013000565A1 (es) | 2013-07-12 |
| ES2808330T3 (es) | 2021-02-26 |
| US9580354B2 (en) | 2017-02-28 |
| LT2609129T (lt) | 2020-07-10 |
| CN103221443B (zh) | 2015-08-12 |
| SI2609129T1 (sl) | 2020-09-30 |
| JP2016180115A (ja) | 2016-10-13 |
| BR112013004571B1 (pt) | 2020-01-21 |
| EP2609129A1 (fr) | 2013-07-03 |
| BR112013004571A2 (pt) | 2016-09-06 |
| DK2609129T3 (da) | 2020-08-03 |
| US20130183524A1 (en) | 2013-07-18 |
| UA111171C2 (uk) | 2016-04-11 |
| CA2809427C (fr) | 2018-10-09 |
| RU2572960C2 (ru) | 2016-01-20 |
| AU2011294930B2 (en) | 2016-01-14 |
| EP2609129B8 (fr) | 2020-07-15 |
| EP2609129B1 (fr) | 2020-05-20 |
| JP2013536311A (ja) | 2013-09-19 |
| WO2012025699A1 (fr) | 2012-03-01 |
| CO6700828A2 (es) | 2013-06-28 |
| FR2964105A1 (fr) | 2012-03-02 |
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