CO6700828A2 - Resina fenólica, procedimeinto para preparación, compuesto de encolado para fibras minerales y producto resultante - Google Patents

Resina fenólica, procedimeinto para preparación, compuesto de encolado para fibras minerales y producto resultante

Info

Publication number
CO6700828A2
CO6700828A2 CO13052186A CO13052186A CO6700828A2 CO 6700828 A2 CO6700828 A2 CO 6700828A2 CO 13052186 A CO13052186 A CO 13052186A CO 13052186 A CO13052186 A CO 13052186A CO 6700828 A2 CO6700828 A2 CO 6700828A2
Authority
CO
Colombia
Prior art keywords
equal
phenol
formaldehyde
conveniently
less
Prior art date
Application number
CO13052186A
Other languages
English (en)
Inventor
Claudio Roncuzzi
Jerome Douce
Guillaume Rousselet
Jean-Louis Mallier
Original Assignee
Saint Gobain Isover
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Isover filed Critical Saint Gobain Isover
Publication of CO6700828A2 publication Critical patent/CO6700828A2/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/34—Condensation polymers of aldehydes, e.g. with phenols, ureas, melamines, amides or amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
    • C08G14/10—Melamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C08L61/14—Modified phenol-aldehyde condensates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C09J161/14—Modified phenol-aldehyde condensates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core

Abstract

Resma líquida, destinada a participar en la elaboración de un compuesto de encolado para fibras minerales, caracterizada por que está constituida esencialmente de condensados de fenol-formaldehído (P-F) y de fenol-formaldehído-glicina (P-F-G).Resma según la reivindicación 1, caracterizada por que presenta una tasa de formaldehído libre máxima igual a 05% en peso total de líquido, preferentemente como máximo igual a 0,3%, y convenientemente como máximo igual a 0,1%.Resma según la reivindicación 1 o 2, caracterizada por que presenta una tasa de fenol libre inferior o igual a 0,5% en peso total de líquido, preferentemente inferior o igual a 0,3%, y convenientemente inferior o igual a 0,1%.Resma según una de las reivindicaciones 1 a 3, caracterizada por que presenta un pH, medido a 20°C, que varía de 4 a 11, preferentemente de 6,5 a 9,0, y convenientemente 7,5 a 8,3.Resma según una de las reivindicaciones 1 a 4, caracterizada por que presenta una solubilidad en agua, a 20°C, superior o igual a 2000%.Procedimiento de preparación de una resma según una de las reivindicaciones 1 a 5, que comprende las etapas consistentes en hacer reaccionar fenol y formaldehído en presencia de un catalizador básico, en una proporción molar formaldehído/fenol superior a 1, para formar condensados P-F, y en introducir a continuación en la mezcla de reacción la glicina, que reacciona con el formaldehído libre, el fenol libre y los condensados P-F según la reacción de Mannich.Procedimiento según la reivindicación 6, caracterizado por qué se hace reaccionar el fenol y el formaldehído en una relación molar formaldehído/fenol que varía de 2 a 4, convenientemente es inferior o igual a 3, y mejor aún que varía de 2,50 a 2,65.Procedimiento según la reivindicación 7, caracterizado por que la reacción del fenol y del formaldehído es proseguida hasta que la tase de conversión del fenol sea superior o igual a 93%, preferentemente superior o igual a 95%, y convenientemente superior o igual a 97%.
CO13052186A 2010-08-27 2013-03-15 Resina fenólica, procedimeinto para preparación, compuesto de encolado para fibras minerales y producto resultante CO6700828A2 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1056803A FR2964105B1 (fr) 2010-08-27 2010-08-27 Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produit resultant.

Publications (1)

Publication Number Publication Date
CO6700828A2 true CO6700828A2 (es) 2013-06-28

Family

ID=43902632

Family Applications (1)

Application Number Title Priority Date Filing Date
CO13052186A CO6700828A2 (es) 2010-08-27 2013-03-15 Resina fenólica, procedimeinto para preparación, compuesto de encolado para fibras minerales y producto resultante

Country Status (20)

Country Link
US (1) US9580354B2 (es)
EP (1) EP2609129B8 (es)
JP (2) JP6001536B2 (es)
KR (1) KR101838974B1 (es)
CN (1) CN103221443B (es)
AU (1) AU2011294930B2 (es)
BR (1) BR112013004571B1 (es)
CA (1) CA2809427C (es)
CL (1) CL2013000565A1 (es)
CO (1) CO6700828A2 (es)
DK (1) DK2609129T3 (es)
ES (1) ES2808330T3 (es)
FR (1) FR2964105B1 (es)
HR (1) HRP20201258T1 (es)
LT (1) LT2609129T (es)
PL (1) PL2609129T3 (es)
RU (1) RU2572960C2 (es)
SI (1) SI2609129T1 (es)
UA (1) UA111171C2 (es)
WO (1) WO2012025699A1 (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201016565D0 (en) 2010-10-01 2010-11-17 Dynea Oy Low free formaldehyde resins for abrasive products
US20130295813A1 (en) * 2010-12-06 2013-11-07 Rockwool International A/S Method of reducing the formaldehyde emission of a mineral fiber product, and mineral fiber product with reduced formaldehyde emission
GB201120137D0 (en) * 2011-11-22 2012-01-04 Dynea Oy Modified binder compositions
EP2657203A1 (en) 2012-04-27 2013-10-30 URSA Insulation, S.A. Process for the production of a phenol-formaldehyde resin having low free-formaldehyde content, the phenol-formaldehyde resin resulting from this process, and its use as a binder for mineral wool insulation products
EP2657266A1 (en) 2012-04-27 2013-10-30 URSA Insulation, S.A. Process for the preparation of a phenol-formaldehyde resin having a low amount of free formaldehyde, a phenol-formaldehyde resin resulting from this process, and the use of this resin as a binder for mineral wool insulation products
EP2865799B1 (en) 2013-10-25 2018-07-04 URSA Insulation, S.A. Method for the manufacture of mineral wool insulation products having low formaldehyde emissions
KR101861404B1 (ko) * 2014-06-10 2018-05-29 주식회사 케이씨씨 수성 복합 접착제 조성물 및 이를 사용하여 섬유상 재료를 결속하는 방법
WO2016069970A1 (en) * 2014-10-30 2016-05-06 Ppg Industries Ohio, Inc. Amino acid-containing sizing compositions for glass fibers and sized fiber glass products
DE202015000192U1 (de) 2015-01-16 2016-04-20 Saint-Gobain Isover Phenol-Formaldehydharz-gebundenes Mineralwollprodukt
CN105131877B (zh) * 2015-08-24 2017-10-10 江西省科学院应用化学研究所 一种硅烷改性酚醛树脂胶黏剂
CN107189338A (zh) * 2017-06-13 2017-09-22 长兴华悦耐火材料厂 一种耐火材料用复合结合剂及其制备方法
EP3489302A1 (en) 2017-11-22 2019-05-29 Prefere Resins Holding GmbH Solid phenolic aldehyde resin composition with reduced aldehyde release, solid curing composition and method for curing a phenolic aldehyde resin and article obtained therefrom
CN108892919A (zh) * 2018-04-16 2018-11-27 安徽昊森新材料科技有限公司 一种轻质隔音酚醛树脂
CN110862499A (zh) * 2019-11-27 2020-03-06 山东阳谷华泰化工股份有限公司 一种氨基酸改性烷基酚-甲醛树脂及其制备方法
EP3835276A1 (en) 2019-12-10 2021-06-16 Saint-Gobain Isover Method for producing mineral wool composites
FR3105233B1 (fr) * 2019-12-19 2021-12-17 Commissariat Energie Atomique Procédé de préparation d’une résine phénolique de type résol à teneur en formaldéhyde réduite
EP4253441A1 (en) * 2020-11-26 2023-10-04 Sumitomo Bakelite Co., Ltd. Phenolic resin composition and method for producing same
JP7338809B1 (ja) 2021-11-25 2023-09-05 住友ベークライト株式会社 フェノール樹脂組成物および物品

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2555591B1 (fr) 1983-11-29 1986-09-26 Saint Gobain Isover Resine pour une composition d'encollage, son procede de fabrication et la composition d'encollage obtenue
US5270434A (en) 1990-10-12 1993-12-14 Isover Saint-Gobain Phenolic resin, procedure for preparation of the resin, and sizing composition for mineral fibers containing this resin
FR2667865B1 (fr) * 1990-10-12 1992-12-11 Saint Gobain Isover Resine phenolique, procede de preparation de la resine et composition d'encollage de fibres minerales la contenant.
US5705537A (en) * 1997-02-24 1998-01-06 Armstrong World Industries, Inc. Phenolic foams having a low formaldehyde evolution
FR2766201A1 (fr) * 1997-07-15 1999-01-22 Saint Gobain Isover Resine phenolique pour composition d'encollage, procede de preparation et composition d'encollage la contenant
US6362275B1 (en) * 2000-12-12 2002-03-26 Ashland Inc. Reduction of free formaldehyde in aldehyde resins
FR2842815B1 (fr) 2002-07-25 2007-06-22 Saint Gobain Isover Solution aqueuse de resine compose phenolique-formaldhehyde- aminoalcool, procede de preparation, composition d'encollage de fibres minerales renfermant ladite resine et produits resultants
WO2008005729A2 (en) * 2006-06-30 2008-01-10 Georgia-Pacific Chemicals Llc Reducing formaldehyde emissions from fiberglass insulation
FR2907122B1 (fr) * 2006-10-11 2008-12-05 Saint Gobain Isover Sa Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produits resultants
FR2907123B1 (fr) 2006-10-11 2008-12-05 Saint Gobain Isover Sa Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produits resultants
FR2929952B1 (fr) 2008-04-11 2011-02-11 Saint Gobain Isover Composition d'encollage pour fibres minerales et produits resultants

Also Published As

Publication number Publication date
AU2011294930B2 (en) 2016-01-14
US9580354B2 (en) 2017-02-28
EP2609129B8 (fr) 2020-07-15
EP2609129B1 (fr) 2020-05-20
JP2013536311A (ja) 2013-09-19
BR112013004571B1 (pt) 2020-01-21
UA111171C2 (uk) 2016-04-11
RU2013113582A (ru) 2014-10-10
HRP20201258T1 (hr) 2020-11-13
KR20130100117A (ko) 2013-09-09
ES2808330T3 (es) 2021-02-26
LT2609129T (lt) 2020-07-10
CN103221443A (zh) 2013-07-24
KR101838974B1 (ko) 2018-03-16
JP2016180115A (ja) 2016-10-13
DK2609129T3 (da) 2020-08-03
EP2609129A1 (fr) 2013-07-03
FR2964105A1 (fr) 2012-03-02
CA2809427A1 (fr) 2012-03-01
CA2809427C (fr) 2018-10-09
BR112013004571A2 (pt) 2016-09-06
CN103221443B (zh) 2015-08-12
CL2013000565A1 (es) 2013-07-12
SI2609129T1 (sl) 2020-09-30
US20130183524A1 (en) 2013-07-18
WO2012025699A1 (fr) 2012-03-01
RU2572960C2 (ru) 2016-01-20
JP6001536B2 (ja) 2016-10-05
FR2964105B1 (fr) 2012-09-28
AU2011294930A1 (en) 2013-04-18
PL2609129T3 (pl) 2020-11-16

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