HRP20190741T1 - Postupak za proizvodnju stabilne vodene otopine klorovog dioksida - Google Patents
Postupak za proizvodnju stabilne vodene otopine klorovog dioksida Download PDFInfo
- Publication number
- HRP20190741T1 HRP20190741T1 HRP20190741TT HRP20190741T HRP20190741T1 HR P20190741 T1 HRP20190741 T1 HR P20190741T1 HR P20190741T T HRP20190741T T HR P20190741TT HR P20190741 T HRP20190741 T HR P20190741T HR P20190741 T1 HRP20190741 T1 HR P20190741T1
- Authority
- HR
- Croatia
- Prior art keywords
- chlorine dioxide
- chlorite
- peroxodisulfate
- solution
- aqueous solution
- Prior art date
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims 36
- 239000004155 Chlorine dioxide Substances 0.000 title claims 18
- 235000019398 chlorine dioxide Nutrition 0.000 title claims 18
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910001919 chlorite Inorganic materials 0.000 claims 14
- 229910052619 chlorite group Inorganic materials 0.000 claims 14
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims 14
- 125000005385 peroxodisulfate group Chemical group 0.000 claims 14
- 239000000243 solution Substances 0.000 claims 13
- 239000007864 aqueous solution Substances 0.000 claims 11
- 238000000034 method Methods 0.000 claims 6
- 238000002360 preparation method Methods 0.000 claims 3
- 239000007787 solid Substances 0.000 claims 3
- 239000003125 aqueous solvent Substances 0.000 claims 2
- 238000004659 sterilization and disinfection Methods 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 241000589248 Legionella Species 0.000 claims 1
- 208000007764 Legionnaires' Disease Diseases 0.000 claims 1
- 238000004378 air conditioning Methods 0.000 claims 1
- 244000052616 bacterial pathogen Species 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 claims 1
- 239000002781 deodorant agent Substances 0.000 claims 1
- 239000000645 desinfectant Substances 0.000 claims 1
- 239000003651 drinking water Substances 0.000 claims 1
- 235000020188 drinking water Nutrition 0.000 claims 1
- 239000007800 oxidant agent Substances 0.000 claims 1
- 230000009182 swimming Effects 0.000 claims 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/42—Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Claims (13)
1. Postupak za pripravu vodene otopine klorovog dioksida s koncentracijom klorovog dioksida u rasponu od 0.3 do 4.5 masenih %, koji obuhvaća korake:
(a) osiguravanje klorita,
(b) osiguravanje peroksodisulfata,
(c) miješanje klorita i peroksodisulfata u vodenom sustavu i u molarnom odnosu peroksodisulfata prema kloritu [S2O82-] / [ClO2-] većem od 1 uz stvaranje vodene otopine klorovog dioksida,
naznačen time što se ne dodaje dodatni pufer za pripravu vodene otopine klorovog dioksida.
2. Postupak prema zahtjevu 1, naznačen time što je molarni omjer između peroksodisulfata i klorita [S2O82-] / [ClO2-] veći od 2.
3. Postupak prema zahtjevu 1, naznačen time što molarni omjer između peroksodisulfata i klorita [S2O82-] / [ClO2-] leži između 1 i 2.
4. Postupak prema bilo kojem od zahtjeva 1 do 3, naznačen time što su klorit i peroksodisulfat u koracima (a) i (b) osigurani u čvrstom obliku ili u obliku vodene otopine,
naznačen time što u koraku (c):
(c1) obje komponente, ako su obje komponente osigurane u čvrstom obliku, su otopljene u vodi prije miješanja, ili
(c2) obje komponente se unose u vodeno otapalo u čvrstom obliku istovremeno ili uzastopno, ili
(c3) obje otopine se miješaju, ako su obje komponente osigurane u obliku vodenih otopina, ili
(c4) obje komponente su osigurane u vodenoj otopini i unose se istovremeno ili uzastopno u vodeno otapalo,
kako bi se pripremila vodena otopina klorovog dioksida.
5. Postupak prema zahtjevu 4, naznačen time što su oba i peroksodisulfat i klorit osigurani u obliku vodenih otopina, kroz koje otopina peroksodisulfata pokazuje pH vrijednost u rasponu od oko 4 do oko 6 i otopina klorita pokazuje pH vrijednost u rasponu od oko 10 do oko 12.
6. Postupak prema bilo kojem od zahtjeva 1 do 5, naznačen time što se miješanje peroksodisulfata i klorita provodi na temperaturi u rasponu od oko 0°C do oko 25°C.
7. Vodena otopina klorovog dioksida, naznačena time što sadrži klorov dioksid u količini u rasponu od više od 0.3 do 4.5 masenih %, te pH otopine leži u rasponu od 2 do 3 i otopina ne sadrži pufer.
8. Upotreba vodene otopine klorovog dioksida prema zahtjevu 7 kao dezinfekcijskog sredstva, kao oksidacijskog sredstva ili sredstva za izbjeljivanje i/ili kao dezodoransa.
9. Upotreba prema zahtjevu 8, naznačen time što se otopina klorovog dioksida koristi u obliku trenutne dezinfekcije ili u obliku trajne dezinfekcije za uklanjanje biofilmova, legionele, ili drugih klica u cijevima za pitku vodu, sustavima klimatizacije, postrojenjima za obradu vode, kotlovima ili bazenima.
10. Uređaj (1) za pripravu vodene otopine klorovog dioksida prema zahtjevu 7, naznačen time što sadrži:
(a) najmanje jedan spremnik za pohranjivanje komponente klorita (2),
(b) barem jedan spremnik za pohranjivanje komponente peroksodisulfata (3),
(c) barem jedan spremnik za miješanje (4), koji je preko dovodne cijevi za komponentu klorita (5), spojen ili može biti spojen na barem jedan spremnik za pohranjivanje komponente klorita (2) i koji je preko dovodne cijevi za komponentu peroksodisulfata (6), spojen na ili može biti spojen na najmanje jedan spremnik za pohranjivanje komponente peroksodisulfata (3),
(d) barem jedan spremnik za pohranjivanje za otopinu klorovog dioksida (7), koji je, preko najmanje jednog dovoda za otopinu klorovog dioksida (16), je spojen ili može biti spojen na spremnik za miješanje (4),
(e) mjerni uređaj (18), koji je ugrađen na najmanje jedan spremnik za pohranjivanje otopine klorovog dioksida (7), i
(f) plutajuće tijelo (20) koje je prilagođeno da pokrije površinu otopine klorovog dioksida u spremniku za pohranjivanje (7).
11. Uređaj (1) za pripravu otopine klorovog dioksida prema zahtjevu 10, naznačen time što je prilagođen za uporabu kao malo postrojenje u stanu s jednom ili više obitelji ili kao veliki industrijski sustav.
12. Uređaj (1) za pripravu otopine klorovog dioksida prema zahtjevu 10, naznačen time što je prilagođen za uporabu na prijenosni način njegovim postavljanjem u kućište.
13. Uređaj (1) za pripravu otopine klorovog dioksida prema bilo kojem od zahtjeva 10 do 12, naznačen time što su dovodni vodovi (5) i (6) opremljeni mjernim uređajima (12) i (13), koji su raspoređeni da reguliraju količinu klorita i peroksodisulfata koji se unose na takav način da se peroksodisulfat i klorit dodaju u posudu za miješanje (4) u omjeru [S2O82-] / [ClO2-] koji je veći od 1.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE201010055982 DE102010055982A1 (de) | 2010-12-23 | 2010-12-23 | Verfahren zur Herstellung einer wässrigen Chlordioxidlösung |
| PCT/EP2011/006510 WO2012084247A1 (de) | 2010-12-23 | 2011-12-22 | Verfahren zur herstellung einer wässrigen stabilen chlordioxidlösung |
| EP11805787.6A EP2654940B1 (de) | 2010-12-23 | 2011-12-22 | Verfahren zur herstellung einer wässrigen stabilen chlordioxidlösung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20190741T1 true HRP20190741T1 (hr) | 2019-06-28 |
Family
ID=45464496
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20190741TT HRP20190741T1 (hr) | 2010-12-23 | 2019-04-18 | Postupak za proizvodnju stabilne vodene otopine klorovog dioksida |
Country Status (28)
| Country | Link |
|---|---|
| US (1) | US9630841B2 (hr) |
| EP (1) | EP2654940B1 (hr) |
| JP (2) | JP6141190B2 (hr) |
| KR (2) | KR101884219B1 (hr) |
| CN (1) | CN103402621B (hr) |
| AR (1) | AR084535A1 (hr) |
| AU (1) | AU2011348371B8 (hr) |
| BR (1) | BR112013015732B1 (hr) |
| CA (1) | CA2822508C (hr) |
| CL (1) | CL2013001792A1 (hr) |
| CY (1) | CY1121627T1 (hr) |
| DE (1) | DE102010055982A1 (hr) |
| DK (1) | DK2654940T3 (hr) |
| ES (1) | ES2725548T3 (hr) |
| HR (1) | HRP20190741T1 (hr) |
| HU (1) | HUE044881T2 (hr) |
| LT (1) | LT2654940T (hr) |
| ME (1) | ME03450B (hr) |
| MX (1) | MX348368B (hr) |
| NZ (1) | NZ612503A (hr) |
| PL (1) | PL2654940T3 (hr) |
| PT (1) | PT2654940T (hr) |
| RS (1) | RS58717B1 (hr) |
| RU (1) | RU2567937C2 (hr) |
| SI (1) | SI2654940T1 (hr) |
| TR (1) | TR201906103T4 (hr) |
| WO (1) | WO2012084247A1 (hr) |
| ZA (1) | ZA201304645B (hr) |
Families Citing this family (36)
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|---|---|---|---|---|
| WO2010151543A1 (en) * | 2009-06-23 | 2010-12-29 | Rosenblatt Aaron A | Aqueous solutions of chlorine dioxide with enhanced stability and methods for producing and packaging them |
| DE102012207472C5 (de) * | 2012-05-04 | 2018-05-03 | Fritz Küke | Vorrichtung und Verfahren zur Herstellung wässriger Chlordioxidlösungen sowie Vorratseinheiten und Kits zur entsprechenden Verwendung |
| DE102012220580B4 (de) * | 2012-11-12 | 2014-07-10 | Jürgen Löhrke GmbH | Chlordioxidanlage |
| JP6298620B2 (ja) * | 2013-11-22 | 2018-03-20 | 高砂熱学工業株式会社 | 二酸化塩素ガスの発生停止方法および二酸化塩素ガス発生装置 |
| US9414611B2 (en) | 2013-12-20 | 2016-08-16 | Ica Trinova, Llc | Methods for treating an object with chlorine dioxide |
| BE1021008B1 (nl) * | 2014-03-12 | 2015-10-13 | Aqua Ecologic | Stabiele chloordioxidesamenstelling en bereidingswijze |
| WO2015136478A1 (en) * | 2014-03-12 | 2015-09-17 | Aqua Ecologic | Stable chlorine dioxide composition and method of preparation |
| JP6317623B2 (ja) * | 2014-05-16 | 2018-04-25 | セントラルフィルター工業株式会社 | 亜塩素酸および二酸化塩素を含有した殺菌水の生成装置 |
| CA2956181A1 (en) * | 2014-08-01 | 2016-02-04 | Gordon & Rosenblatt, Llc | Methods for treating premise plumbing |
| US9862603B1 (en) * | 2014-09-02 | 2018-01-09 | Bio-Cide International, Inc. | Device for quenching reaction at variable time points |
| BE1023120B1 (nl) * | 2015-09-16 | 2016-11-24 | Aqua Ecologic | Werkwijze en systeem voor het desinfecteren met chloordioxide gas |
| EP3153184A3 (en) * | 2015-09-16 | 2017-07-12 | Aqua Ecologic | Method and system for disinfecting with chlorine dioxide gas |
| JP6080281B1 (ja) * | 2016-03-04 | 2017-02-15 | 株式会社 エースネット | 炭化水素またはその誘導体の酸化反応生成物の製造方法 |
| JP6236057B2 (ja) * | 2015-12-18 | 2017-11-22 | 株式会社 エースネット | 薬剤 |
| CN108430624A (zh) | 2015-12-18 | 2018-08-21 | 株式会社Acenet | 自由基产生催化剂、自由基的制造方法、氧化反应产物的制造方法、药剂及农业畜牧业用药剂 |
| US10947190B2 (en) | 2015-12-18 | 2021-03-16 | Acenet Inc. | Method for producing oxidation reaction product of hydrocarbon or derivative thereof, and method for producing oxidation reaction product of olefin |
| JP6268151B2 (ja) * | 2015-12-18 | 2018-01-24 | 株式会社 エースネット | ラジカル発生触媒、ラジカルの製造方法および酸化反応生成物の製造方法 |
| JP6268152B2 (ja) * | 2015-12-18 | 2018-01-24 | 株式会社 エースネット | ラジカルの製造方法および酸化反応生成物の製造方法 |
| DE102016103675A1 (de) | 2016-03-01 | 2017-09-07 | a.p.f.Aqua System AG | Spülvorrichtung zum Aufnehmen einer Spüllösung aus einer Rohrleitung sowie Verfahren zum Spülen der Rohrleitung |
| CN106550941B (zh) * | 2016-11-08 | 2020-11-06 | 东北大学秦皇岛分校 | 一种稳定二氧化氯消毒液 |
| CN110088176B (zh) * | 2016-12-16 | 2022-05-03 | 阿斯制药株式会社 | 聚合物的改性方法、使用其的改性聚合物的制造方法和改性聚合物 |
| TWI631071B (zh) * | 2017-01-25 | 2018-08-01 | 劉德輝 | Method and system for reducing concentration of chlorine by-products in aqueous chlorine dioxide solution |
| US10850981B2 (en) | 2017-04-25 | 2020-12-01 | Ica Trinova, Llc | Methods of producing a gas at a variable rate |
| KR101977036B1 (ko) | 2017-12-28 | 2019-05-10 | 주식회사 이노푸스 | 가스, 용액 및 거품을 선택적으로 분사할 수 있는 이산화염소 분사 장치 |
| US11912568B2 (en) | 2018-03-14 | 2024-02-27 | Ica Trinova, Llc | Methods of producing a gas at a controlled rate |
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| CN110102165B (zh) * | 2019-04-29 | 2022-01-04 | 上海交通大学 | 垃圾渗滤液浓缩液制备除臭剂的方法 |
| DE102019117728B4 (de) | 2019-07-01 | 2021-11-25 | Prominent Gmbh | Verfahren und Vorrichtung zur Erzeugung von Chlordioxid |
| JP2021080140A (ja) * | 2019-11-21 | 2021-05-27 | ネオシーエル カンパニー リミテッド | 常温長期濃度保持二酸化塩素水溶液組成物及びその製造方法 |
| CN111232928A (zh) * | 2020-03-05 | 2020-06-05 | 山东德洋计量检测有限公司 | 一种二氧化氯制备和纯化装置及其制备方法 |
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| DE102006060578A1 (de) * | 2006-12-19 | 2008-06-26 | Bwt Wassertechnik Gmbh | Verfahren und Vorrichtung zur Erzeugung und Dosierung von Chlordioxid in eine Wasserleitung |
| WO2010151543A1 (en) * | 2009-06-23 | 2010-12-29 | Rosenblatt Aaron A | Aqueous solutions of chlorine dioxide with enhanced stability and methods for producing and packaging them |
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2010
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