HRP20151242T1 - Novi herbicidi - Google Patents

Novi herbicidi Download PDF

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Publication number
HRP20151242T1
HRP20151242T1 HRP20151242TT HRP20151242T HRP20151242T1 HR P20151242 T1 HRP20151242 T1 HR P20151242T1 HR P20151242T T HRP20151242T T HR P20151242TT HR P20151242 T HRP20151242 T HR P20151242T HR P20151242 T1 HRP20151242 T1 HR P20151242T1
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HR
Croatia
Prior art keywords
compound
formula
pyridyl
methyl
pyrimidyl
Prior art date
Application number
HRP20151242TT
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English (en)
Inventor
John Benjamin Taylor
Jeffrey Steven Wailes
Stephane André Marie JEANMART
Mangala Govenkar
Original Assignee
Syngenta Participations Ag
Syngenta Limited
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Application filed by Syngenta Participations Ag, Syngenta Limited filed Critical Syngenta Participations Ag
Publication of HRP20151242T1 publication Critical patent/HRP20151242T1/hr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/08—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
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    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A—HUMAN NECESSITIES
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    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
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    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
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    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
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Claims (19)

1. Spoj s formulom I [image] naznačen time da G je vodik ili poljoprivredno prihvatljiv metal, sulfonij, amonijak ili latentna skupina; R1 je metil, etil, n-propil, izopropil, ciklopropil, halometil, haloetil, vinil, etinil, halogen, C1-C2alkoksi ili C1-C2haloalkoksi; R2 i R3 su međusobno neovisno vodik, metil, etil, n-propil, izopropil, ciklopropil, halometil, haloetil, vinil, propenil, etinil, propinil, halogen, C1-C2alkoksi, C1-C2haloalkoksi, proizvoljno supstituiran aril ili proizvoljno supstituiran heteroaril; i pri čemu, u R2 i R3, kada su prisutni, proizvoljni supstituenti na arilu su neovisno izabrani iz skupa koji čine: halogen, nitro, cijano, rodano, izotiocijanato, C1-C6alkil, C1-C6haloalkil, C1-C6alkoksi(C1-C6) alkil, C2-C6alkenil, C2-C6haloalkenil, C2-C6alkinil, C3-C7cikloalkil (sam je proizvoljno supstituiran s C1-C6alkilom ili halogenom), C5-7cikloalkenil (sam je proizvoljno supstituiran s C1-C6alkilom ili halogenom), hidroksi, C1-C10alkoksi, C1-C10alkoksi(C1-C10)alkoksi, tri(C1-C4)alkilsilil(C1-C6)alkoksi, C1-C6alkoksikarbonil(C1-C10)alkoksi, C1-C10haloalkoksi, aril(C1-C4)alkoksi (gdje je aril skupina proizvoljno supstituirana s halogenom ili C1-C6alkil), C3-C7cikloalkiloksi (gdje je cikloalkil skupina proizvoljno supstituirana s C1-C6alkilom ili halogenom), C3-C10alkeniloksi, C3-C10alkiniloksi, merkapto, C1-C10alkiltio, C1-C10haloalkiltio, aril(C1-C4)alkiltio, C3-C7cikloalkiltio (gdje je cikloalkil skupina proizvoljno supstituirana s C1-C6alkilom ili halogenom), tri(C1-C4)-alkilsilil(C1-C6)alkiltio, ariltio, C1-C6alkilsulfonil, C1-C6haloalkilsulfonil, C1-C6alkilsulfinil, C1-C6haloalkilsulfinil, arilsulfonil, tri(C1-C4)alkilsilil, arildi(C1-C4)alkilsilil, C1-C4alkildiarilsilil, triarilsilil, C1-C10alkilkarbonil, HO2C, C1-C10alkoksikarbonil, aminokarbonil, C1-C6alkilaminokarbonil, di(C1-C6alkil)-aminokarbonil, N-(C1-C3 alkil)-N-(C1-C3alkoksi)aminokarbonil, C1-C6alkilkarboniloksi, arilkarboniloksi, di(C1-C6)alkilaminokarboniloksi, aril (sam je proizvoljno supstituiran s C1-C6alkilom ili halogenom), heterociklil (sam je proizvoljno supstituiran s C1-C6alkilom ili halogenom), ariloksi (gdje je aril skupina proizvoljno supstituirana s C1-C6alkilom ili halogenom), heterocikliloksi (gdje je heterociklil skupina proizvoljno supstituirana s C1-C6alkilom ili halogenom), amino, C1-C6alkilamino, di(C1-C6)alkilamino, C1-C6alkilkarbonilamino, N-(C1-C6)alkilkarbonil-N-(C1-C6)alkilamino, ili arilkarbonil (gdje je aril skupina sama proizvoljno supstituirana s halogenom ili C1-C6alkilom); ili dvije susjedne pozicije na aril sustavu su ciklizirane da tvore 5, 6 ili 7 člani karbociklički ili heterociklički prsten, koji je sam proizvoljno supstituiran s halogenom ili C1-C6alkilom; i pri čemu, u R2 i R3, kada su prisutni, heteroaril je proizvoljno supstituiran s C1-C4alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, cijano, nitro, halogenom, C1-C3alkiltio, C1-C3alkilsulfinilom ili C1-C3alkilsulfonilom; R4 je metil, etil, n-propil, izopropil, ciklopropil, halometil, haloetil, vinil, propenil, etinil, propinil, halogen, C1-C2alkoksi ili C1-C2haloalkoksi; i R5, R6, R7, R8 i R9 su neovisno vodik, halogen, C1-C6alkil, C1-C6haloalkil, C1-C6alkoksi, C1-C6haloalkoksi, C2-C6alkenil, C2-C6haloalkenil, C2-C6alkinil, C3-C6alkeniloksi, C3-C6haloalkeniloksi, C3-C6alkiniloksi, C3-C6cikloalkil, C1-C6alkiltio, C1-C6alkilsulfinil, C1-C6alkilsulfonil, C1-C6alkoksisulfonil, C1-C6haloalkoksisulfonil, cijano, nitro, fenil, fenil supstituiran s C1-C4alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, cijano, nitro, halogen, C1-C3alkiltio, C1-C3alkilsulfinil ili C1-C3alkilsulfonil, ili heteroaril ili heteroaril supstituiran s C1-C4alkilom, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, cijano, nitro, halogen, C1-C3alkiltio, C1-C3alkilsulfinil ili C1-C3alkilsulfonil; ili R6 i R7 ili R8 i R9 zajedno s atomima ugljika na koje su oni spojeni tvore proizvoljno supstituirani karbociklički prsten, ili heterociklil proizvoljno supstituiran s C1-C6alkilom ili C1-C6haloalkilom; pri čemu "karbociklički prsten" predstavlja cikloalkil ili cikloalkenil skupinu; te pri čemu, kada su prisutni, proizvoljni supstituenti na cikloalkilu ili cikloalkenilu su C1-C3alkil; ili R5 i R6 zajedno tvore vezu; i HetAr je heteroaril ili heteroaril supstituiran s C1-C4alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, cijano, nitro, halogenom, C1-C3alkiltio, C1-C3alkilsulfinilom ili C1-C3alkilsulfonilom; i pri čemu kada je G latentna skupina tada je G izabran iz skupina fenilC1-C8alkil (pri čemu je fenil proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogenom, cijano ili s nitro), heteroarilC1-C8alkil (pri čemu je heteroaril proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3 alkilsulfonil, halogen, cijano ili s nitro), C3-C8alkenil, C3-C8haloalkenil, C3-C8alkinil, C(Xa)-Ra, C(Xb)-Xc-Rb, C(Xd)-N(Rc)-Rd, -SO2-Re, -P(Xe)(Rf)-R9 i CH2-Xf-Rh; pri čemu Xa, Xb, Xc, Xd, Xe i Xf su međusobno neovisno kisik ili sumpor; te pri čemu Ra je H, C1-C18alkil, C2-C18alkenil, C2-C18alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilamino(C1-C5)alkil, C2-C8dialkilamino(C1-C5)alkil, C3-C7cikloalkil(C1-C5)alkil, C1-C5alkoksi(C1-C5)alkil, C3-C5alkeniloksi(C1-C5)alkil, C1-C5alkiltio(C1-C5)alkil, C1-C5alkilsulfinil(C1-C5)alkil, C1-C5alkilsulfonil(C1-C5)alkil, C2-C8alkilidenaminoksi(C1-C5)alkil, C1-C5alkilkarbonil(C1-C5)alkil, C1-C5alkoksikarbonil(C1-C5)alkil, aminokarbonil(C1-C5)alkil, C1-C5alkilaminokarbonil(C1-C5)alkil, C2-C8dialkilaminokarbonil(C1-C5)alkil, C1-C5alkilkarbonilamino(C1-C5)alkil, N-(C1-C5)alkilkarbonil-N-(C1-C5)alkilamino(C1-C5)alkil, C3-C6trialkilsilil(C1-C5)alkil, fenil(C1-C5)alkil (pri čemu je fenil proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili s nitro), heteroaril(C1-C5)alkil (pri čemu heteroaril je proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili sa nitro), C2-C5haloalkenil, C3-C8cikloalkil; fenil ili fenil supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; ili heteroaril ili heteroaril supstituiran s C1-C3 alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro; Rb je C1-C18alkil, C3-C18alkenil, C3-C18alkinil, C2-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C2-C10aminoalkil, C1-C5alkilamino(C1-C5)alkil, C2-C8dialkilamino(C1-C5)alkil, C3-C7cikloalkil(C1-C5)alkil, C1-C5alkoksi(C1-C5)alkil, C3-C5alkeniloksi(C1-C5)alkil, C3-C5alkiniloksi(C1-C5)alkil, C1-C5alkiltio(C1-C5)alkil, C1-C5alkilsulfinil(C1-C5)alkil, C1-C5alkilsulfonil(C1-C5)alkil, C2-C8alkilidenaminoksi(C1-C5)alkil, C1-C5alkilkarbonil(C1-C5)alkil, C1-C5alkoksikarbonil(C1-C5)alkil, aminokarbonil(C1-C5)alkil, C1-C5alkilaminokarbonil(C1-C5)alkil, C2-C8dialkilaminokarbonil(C1-C5)alkil, C1-C5alkilkarbonilamino(C1-C5)alkil, N-(C1-C5)alkilkarbonil-N-(C1-C5)alkilamino(C1-C5)alkil, C3-C6trialkilsilil(C1-C5)alkil, fenil(C1-C5)alkil (pri čemu je fenil proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3habatkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili s nitro), heteroarilC1-C5alkil (pri čemu heteroaril je proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkil-tio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili s nitro), C3-C5haloalkenil, C3-C8cikloalkil; fenil ili fenil supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; ili heteroaril ili heteroaril supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; i Rc i Rd su svaki međusobno neovisno vodik, C1-C10alkil, C3-C10alkenil, C3-C10alkinil, C2-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilamino(C1-C5)alkil, C2-C8dialkilamino(C1-C5)alkil, C3-C7cikloalkil(C1-C5)alkil, C1-C5alkoksi(C1-C5)alkil, C3-C5alkeniloksi(C1-C5)alkil, C3-C5alkiniloksi(C1-C5)alkil, C1-C5alkiltio(C1-C5)alkil, C1-C5alkilsulfinil(C1-C5)alkil, C1-C5alkilsulfonil(C1-C5)alkil, C2-C8alkilidenaminoksi(C1-C5)alkil, C1-C5alkilkarbonil(C1-C5)alkil, C1-C5alkoksikarbonil(C1-C5)alkil, aminokarbonil(C1-C5)alkil, C1-C5alkilaminokarbonil(C1-C5)alkil, C2-C8dialkilaminokarbonil(C1-C5)alkil, C1-C5alkilkarbonilamino(C1-C5)alkil, N-(C1-C5)alkilkarbonil-N-(C2-C5)alkilaminoalkil, C3-C6trialkilsilil(C1-C5)alkil, fenil(C1-C5)alkil (pri čemu je fenil proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili s nitro), heteroaril(C1-C5)alkil (pri čemu heteroaril je proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili s nitro), C2-C5haloalkenil, C3-C8cikloalkil; fenil ili fenil supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; heteroaril ili heteroaril supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; heteroarilamino ili heteroarilamino supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; diheteroarilamino ili diheteroarilamino supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; fenilamino ili fenilamino supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili s nitro; difenilamino ili difenilamino supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili s nitro; ili C3-C7cikloalkilamino, di-C3-C7cikloalkilamino ili C3-C7cikloalkoksi; ili Rc i Rd se mogu spojiti zajedno da tvore 3-7 člani prsten, koji proizvoljno sadrži jedan heteroatom izabran od O ili S; i Re je C1-C10alkil, C2-C10alkenil, C2-C10alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilamino(C1-C5)alkil, C2-C8dialkilamino(C1-C5)alkil, C3-C7cikloalkil(B1-C5)alkil, C1-C5alkoksi(C1-C5)alkil, C3-C5alkeniloksi(C1-C5)alkil, C3-C5alkiniloksi(C1-C5)alkil, C1-C5alkiltio(C1-C5)alkil, C1-C5alkilsulfinil(C1-C5)alkil, C1-C5alkilsulfonil(C1-C5)alkil, C2-C8alkilidenaminoksi(C1-C5)alkil, C1-C5alkilkarbonil(C1-C5)alkil, C1-C5alkoksikarbonil(C1-C5)alkil, aminokarbonil(C1-C5)alkil, C1-C5alkilaminokarbonil(C1-C5)alkil, C2-C8dialkilaminokarbonil(C1-C5)alkil, C1-C5alkilkarbonilamino(C1-C5)alkil, N-(C1-C5)alkilkarbonil-N-(C1-C5)alkilamino(C1-C5)alkil, C3-C6trialkilsilil(C1-C5)alkil, fenil(C1-C5)alkil (pri čemu je fenil proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili s nitro), heteroaril(C1-C5)alkil (pri čemu heteroaril je proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili s nitro), C2-C5haloalkenil, C3-C8cikloalkil; fenil ili fenil supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; heteroaril ili heteroaril supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili s nitro; heteroarilamino ili heteroarilamino supstituiran s C1-C3 alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili s nitro; diheteroarilamino ili diheteroarilamino supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; fenilamino ili fenilamino supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; difenilamino ili difenilamino supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; ili C3-C7cikloalkilamino, diC3-C7cikloalkilamino, C3-C7cikloalkoksi, C1-C10alkoksi, C1-C10haloalkoksi, C1-C5alkilamino ili C2-C8dialkilamino; Rf i Rg su svaki međusobno neovisno C1-C10alkil, C2-C10alkenil, C2-C10alkinil, C1-C10alkoksi, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilamino(C1-C5)alkil, C2-C8dialkilamino(C1-C5)alkil, C3-C7cikloalkil(C1-C5)alkil, C1-C5alkoksi(C1-C5)alkil. C3-C5alkeniloksi(C1-C5)alkil, C3-C5alkiniloksi(C1-C5)alkil, C1-C5alkiltio(C1-C5)alkil, C1-C5alkilsulfinil(C1-C5)alkil, C1-C5alkilsulfonil(C1-C5)alkil, C2-C8alkilidenaminoksi(C1-C5)alkil, C1-C5alkilkarbonil(C1-C5)alkil, C1-C5alkoksikarbonil(C1-C5)alkil, aminokarbonil(C1-C5)alkil, C1-C5alkilaminokarbonil(C1-C5)alkil, C2-C8dialkilaminokarbonil(C1-C5)alkil, C1-C5alkilkarbonilamino(C1-C5)alkil, N-(C1-C5)alkilkarbonil-N-(C2-C5)alkilaminoalkil, C3-C6trialkilsilil(C1-C5)alkil, fenil(C1-C5)alkil (pri čemu je fenil proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili s nitro), heteroaril(C1-C5)alkil (pri čemu heteroaril je proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3alkilsulfonil, halogen, cijano, ili s nitro), C2-C5haloalkenil, C3-C8cikloalkil; fenil ili fenil supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; heteroaril ili heteroaril supstituiran s C1-C3 alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili s nitro; heteroarilamino ili heteroarilamino supstituiran s C1-C3 alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili s nitro; diheteroarilamino ili diheteroarilamino supstituiran s C1-C3 alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; fenilamino ili fenilamino supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; difenilamino ili difenilamino supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro; ili C3-C7cikloalkilamino, diC3-C7cikloalkilamino, C3-C7cikloalkoksi, C1-C10haloalkoksi, C1-C5alkilamino ili C2-C8dialkilamino; ili benziloksi ili fenoksi, pri čemu benzil i fenil skupine mogu zauzvrat biti supstituirane s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro; i Rh je C1-C10alkil, C3-C10alkenil, C3-C10alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C2-C10aminoalkil, C1-C5alkilamino(C1-C5)alkil, C2-C8dialkilamino(C1-C5)alkil, C3-C7cikloalkil(C1-C5)alkil, C1-C5alkoksi(C1-C5)alkil, C3-C5alkeniloksi(C1-C5)alkil, C3-C5alkiniloksi(C1-C5)alkil, C1-C5alkiltio(C1-C5)alkil, C1-C5alkilsulfinil(C1-C5)alkil, C1-C5alkilsulfonil(C1-C5)alkil, C2-C8alkilidenaminoksi(C1-C5)alkil, C1-C5alkilkarbonil(C1-C5)alkil, C1-C5alkoksikarbonil(C1-C5)alkil, aminokarbonil(C1-C5)alkil, C1-C5alkilaminokarbonil(C1-C5)alkil, C2-C8dialkilaminokarbonil(C1-C5)alkil, C1-C5alkilkarbonilamino(C1-C5)alkil, N-(C1-C5)alkilkarbonil-N-(C1-C5)alkilamino(C1-C5)alkil, C3-C6trialkilsilil(C1-C5)alkil, fenil(C1-C5)alkil (pri čemu je fenil proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3 alkilsulfonil, halogen, cijano ili s nitro), heteroaril(C1-C5)alkil (pri čemu heteroaril je proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3 alkilsulfonil, halogen, cijano ili s nitro), fenoksi(C1-C5)alkil (pri čemu je fenil proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3 alkilsulfonil, halogen, cijano ili s nitro), heteroariloksi(C1-C5)alkil (pri čemu heteroaril je proizvoljno supstituiran C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinil, C1-C3 alkilsulfonil, halogen, cijano ili s nitro), C3-C5haloalkenil, C3-C8cikloalkil; fenil ili fenil supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen ili s nitro; ili heteroaril, ili heteroaril supstituiran s C1-C3alkil, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili s nitro; i pri čemu "aril" znači fenil; pri čemu "heteroaril" znači 6-člani heteroarilni prsten koji je je proizvoljno benzaneliran; te pri čemu "heterociklil" znači ne-aromatski monociklički ili biciklički prstenasti sustav koji sadrži do 7 atoma uključujući jedan ili dva heteroatoma odabrana od O, S i N.
2. Spoj prema zahtjevu 1, naznačen time da "heteroaril" znači piridil, pirimidinil, piridazinil, kinolinil, izokinolinil, cinolinil, ftalazinil, kinazolinil ili kinoksalinil.
3. Spoj prema zahtjevu 1, naznačen time da: "cikloalkil" je ciklopropil, ciklobutil, ciklopentil ili cikloheksil; "cikloalkilalkil" je ciklopropilmetil; i "cikloalkenil" je ciklopentenil ili cikloheksenil.
4. Spoj prema zahtjevu 1, naznačen time da R1 je metil, etil, n-propil, vinil, etinil, halogen, C1-C2alkoksi ili C1-C2haloalkoksi; R2 je metil, halogen, C1-C2alkoksi ili C1-C2haloalkoksi, ili proizvoljno supstituiran fenil; R3 je vodik; R4 je metil, etil, n-propil, vinil, etinil ili metoksi; i R5, R6, R7, R8 i R9 su neovisno vodik, halogen, C1-C4alkil, C1-C4haloalkil, C1-C4alkoksi, C1-C4haloalkoksi, C2-C4alkenil, C2-C4haloalkenil, ili C2-C4alkinil; ili R6 i R7 ili R8 i R9 zajedno s atomima ugljika na koje su oni spojeni tvore proizvoljno supstituiran karbociklički prsten kako je definirano u zahtjevu 1 ili proizvoljno supstituiran heterociklil kako je definirano u zahtjevu 1; ili R5 i R6 zajedno tvore vezu; i HetAr je heteroaril ili heteroaril supstituiran jednom do tri puta s fluoro, kloro, bromo, metilom, metoksi, cijano ili trifluorometilom.
5. Spoj prema zahtjevu 4, naznačen time da R1 je metil ili etil, R2 je metil ili kloro, R3 je vodik, i R4 je metil, etil ili metoksi, i R5, R6, R7, R8 i R9 su vodik, ili R5 i R6 zajedno tvore vezu; i HetAr je 6-člani heteroaril ili je 6-člani heteroaril koji je supstituiran jednom do tri puta s fluoro, kloro, bromo, metilom, metoksi, cijano ili trifluorometilom.
6. Spoj prema zahtjevu 1, 4 ili 5, naznačen time da HetAr je piridil, pirimidinil, piridazinil, kinolinil, izokinolinil, cinolinil, ftalazinil, kinazolinil ili kinoksalinil, gdje su navedeni prsteni proizvoljno supstituirani jednom ili dva puta s fluoro, kloro, bromo, metilom, metoksi, cijano ili trifluorometilom.
7. Spoj prema zahtjevu 1, naznačen time da, kada G je latentna skupina, G je skupina -C(Xa)-Ra ili -C(Xb)-Xc-Rb, i značenja za Xa, Ra, Xb, Xc i Rb su kako je definirano u zahtjevu 1.
8. Spoj prema zahtjevu 1, naznačen time da G je vodik.
9. Spoj prema zahtjevu 1, naznačen time da je jedan od slijedećih spojeva: [image] [image] [image] [image] [image] [image] [image] [image] [image] [image] [image] [image] [image] [image] [image] [image] [image]
10. Spoj prema zahtjevu 1, naznačen time da je spoj strukturnog tipa T-1: ili [image] pri čemu R5, R6, R7, R8 i R9 su H; i pri čemu HetAr je 2-piridil, 3-fluoro-2-piridil, 4-fluoro-2-piridil, 5-fluoro-2-piridil, 6-fluoro-2-piridil, 3-kloro-2-piridil, 4-kloro-2-piridil, 5-kloro-2-piridil, 6-kloro-2-piridil, 3-metil-2-piridil, 4-metil-2-piridil, 5-metil-2-piridil, 6-metil-2-piridil, 3-trifluorometil-2-piridil, 4-trifluorometil-2-piridil, 5-trifluorometil-2-piridil, 6-trifluorometil-2-piridil, 3-metoksi-2-piridil, 4-metoksi-2-piridil, 5-metoksi-2-piridil, 6-metoksi-2-piridil, 3-trifluorometoksi-2-piridil, 4-trifluorometoksi-2-piridil, 5-trifluorometoksi-2-piridil, 6-trifluorometoksi-2-piridil, 3-cijano-2-piridil, 4-cijano-2-piridil, 5-cijano-2-piridil, 6-cijano-2-piridil, 3-nitro-2-piridil, 4-nitro-2-piridil, 5-nitro-2-piridil, 6-nitro-2-piridil, 3-metansulfonil-2-piridil, 4-metansulfonil-2-piridil, 5-metansulfonil-2-piridil, 6-metansulfonil-2-piridil, 3-piridil, 2-fluoro-3-piridil, 4-fluoro-3-piridil, 5-fluoro-3-piridil, 6-fluoro-3-piridil, 2-kloro-3-piridil, 4-kloro-3-piridil, 5-kloro-3-piridil, 6-kloro-3-piridil, 2-bromo-3-piridil, 4-bromo-3-piridil, 5-bromo-3-piridil, 6-bromo-3-piridil, 2-metoksi-3-piridil, 4-metoksi-3-piridil, 5-metoksi-3-piridil, 6-metoksi-3-piridil, 2-trifluorometoksi-3-piridil, 4-trifluorometoksi-3-piridil, 5-trifluorometoksi-3-piridil, 6-trifluorometoksi-3-piridil, 2-metil-3-piridil, 4-metil-3-piridil, 5-metil-3-piridil, 6-metil-3-piridil, 2-trifluorometil-3-piridil, 4-trifluorometil-3-piridil, 5- trifluorometil-3-piridil, 6-trifluorometil-3-piridil, 2-cijano-3-piridil, 4-cijano-3-piridil, 5-cijano-3-piridil, 6-cijano-3-piridil, 2-nitro-3-piridil, 4-nitro-3-piridil, 5-nitro-3-piridil, 6-nitro-3-piridil, 2-metansulfonil-3-piridil, 4-metansulfonil-3-piridil, 5-metansulfonil-3-piridil, 6-metansulfonil-3-piridil, 4-piridil, 2-fluoro-4-piridil, 3-fluoro-4-piridil, 2-kloro-4-piridil, 3-kloro-4-piridil, 2-bromo-4-piridil, 3-bromo-4-piridil, 2-metoksi-4-piridil, 3-metoksi-4-piridil, 2-trifluorometoksi-4-piridil, 3-trifluorometoksi-4-piridil, 2-metil-4-piridil, 3-metil-4-piridil, 2-trifluorometil-4-piridil, 3-trifluorometil-4-piridil, 2-cijano-4-piridil, 3-cijano-4-piridil, 2-nitro-4-piridil, 3-nitro-4-piridil, 2-metansulfonil-4-piridil, 3- metansulfonil-4-piridil, 2-piridazinil, 4-fluoro-2-piridazinil, 5-fluoro-2-piridazinil, 6-fluoro-2-piridazinil, 4-kloro-2-piridazinil, 5-kloro-2-piridazinil, 6-kloro-2-piridazinil, 4-bromo-2-piridazinil, 5-bromo-2-piridazinil, 6-bromo-2-piridazinil, 4-metoksi-2-piridazinil, 5-metoksi-2-piridazinil, 6-metoksi-2-piridazinil, 4-trifluorometoksi-2-piridazinil, 5-trifluorometoksi-2-piridazinil, 6-trifluorometoksi-2-piridazinil, 4-metil-2-piridazinil, 5-metil-2-piridazinil, 6-metil-2-piridazinil, 4-trifluorometil-2-piridazinil, 5-trifluorometil-2-piridazinil, 6-trifluorometil-2-piridazinil, 4-cijano-2-piridazinil, 5-cijano-2-piridazinil, 6-cijano-2-piridazinil, 4-nitro-2-piridazinil, 5-nitro-2-piridazinil, 6-nitro-2-piridazinil, 4-metansulfonil-2-piridazinil, 5-metansulfonil-2-piridazinil, 6-metansulfonil-2-piridazinil, 3-piridazinil, 2-fluoro-3-piridazinil, 5-fluoro-3-piridazinil, 6-fluoro-3-piridazinil, 2-kloro-3-piridazinil, 5-kloro-3-piridazinil, 6-kloro-3-piridazinil, 2-bromo-3-piridazinil, 5-bromo-3-piridazinil, 6-bromo-3-piridazinil, 2-metoksi-3-piridazinil, 5-metoksi-3-piridazinil, 6-metoksi-3-piridazinil, 2-trifluorometoksi-3-piridazinil, 5-trifluorometoksi-3-piridazinil, 6-trifluorometoksi-3-piridazinil, 2-metil-3-piridazinil, 5-metil-3-piridazinil, 6-metil-3-piridazinil, 2-trifluorometil-3-piridazinil, 5-trifluorometil-3-piridazinil, 6-trifluorometil-3-piridazinil, 2-cijano-3-piridazinil, 5-cijano-3-piridazinil, 6-cijano-3-piridazinil, 2-nitro-3-piridazinil, 5-nitro-3-piridazinil, 6-nitro-3-piridazinil, 2-metansulfonil-3-piridazinil, 5-metansulfonil-3-piridazinil, 6-metansulfonil-3-piridazinil, 2-pirimidil, 4-fluoro-2-pirimidil, 5-fluoro-2-pirimidil, 4-kloro-2-pirimidil, 5-kloro-2-pirimidil, 4-bromo-2-pirimidil, 5-bromo-2-pirimidil, 4-metoksi-2-pirimidil, 5-metoksi-2-pirimidil, 4-trifluorometoksi-2-pirimidil, 5-trifluorometoksi-2-pirimidil, 4-metil-2-pirimidil, 5-metil-2-pirimidil, 4-trifluorometil-2-pirimidil, 5-trifluorometil-2-pirimidil, 4-cijano-2-pirimidil, 5-cijano-2-pirimidil, 4-nitro-2-pirimidil, 5-nitro-2-pirimidil, 4-metansulfonil-2-pirimidil, 5-metansulfonil-2-pirimidil, 4-pirimidil, 2-fluoro-4-pirimidil, 5-fluoro-4-pirimidil, 6-fluoro-4-pirimidil, 2-kloro-4-pirimidil, 5-kloro-4-pirimidil, 6-kloro-4-pirimidil, 2-bromo-4-pirimidil, 5-bromo-4-pirimidil, 6-bromo-4-pirimidil, 2-metoksi-4-pirimidil, 5-metoksi-4-pirimidil, 6-metoksi-4-pirimidil, 2-trifluorometoksi-4-pirimidil, 5-trifluorometoksi-4-pirimidil, 6-trifluorometoksi-4-pirimidil, 2-metil-4-pirimidil, 5-metil-4-pirimidil, 6-metil-4-pirimidil, 2-trifluorometil-4-pirimidil, 5-trifluorometil-4-pirimidil, 6-trifluorometil-4-pirimidil, 2-cijano-4-pirimidil, 5-cijano-4-pirimidil, 6-cijano-4-pirimidil, 2-nitro-4-pirimidil, 5-nitro-4-pirimidil, 6-nitro-4-pirimidil, 2-metansulfonil-4-pirimidil, 5-metansulfonil-4-pirimidil, 6-metansulfonil-4-pirimidil, 5-pirimidil, 2-fluoro-5-pirimidil, 4-fluoro-5-pirimidil, 2-kloro-5-pirimidil, 4-kloro-5-pirimidil, 2-bromo-5-pirimidil, 4-bromo-5-pirimidil, 2-metoksi-5-pirimidil, 4-metoksi-5-pirimidil, 2-trifluorometoksi-5-pirimidil, 4-trifluorometoksi-5-pirimidil, 2-metil-5-pirimidil, 4-metil-5-pirimidil, 2-trifluorometil-5-pirimidil, 4-trifluorometil-5-pirimidil, 2-cijano-5-pirimidil, 4-cijano-5-pirimidil, 2-nitro-5-pirimidil, 4-nitro-5-pirimidil, 2-metansulfonil-5-pirimidil, 4-metansulfonil-5-pirimidil, 2-pirazinil, 3-fluoro-2-pirazinil, 5-fluoro-2-pirazinil, 6-fluoro-2-pirazinil, 3-kloro-2-pirazinil, 5-kloro-2-pirazinil, 6-kloro-2-pirazinil, 3-bromo-2-pirazinil, 5-bromo-2-pirazinil, 6-bromo-2-pirazinil, 3-metoksi-2-pirazinil, 5-metoksi-2-pirazinil, 6-metoksi-2-pirazinil, 3-trifluorometoksi-2-pirazinil, 5-trifluorometoksi-2-pirazinil, 6-trifluorometoksi-2-pirazinil, 3-metil-2-pirazinil, 5-metil-2-pirazinil, 6-metil-2-pirazinil, 3-trifluorometil-2-pirazinil, 5-trifluorometil-2-pirazinil, 6-trifluorometil-2-pirazinil, 3-cijano-2-pirazinil, 5-cijano-2-pirazinil, 6-cijano-2-pirazinil, 3-nitro-2-pirazinil, 5-nitro-2-pirazinil, 6-nitro-2-pirazinil, 3-metilsulfonat-2-pirazinil, 5-metilsulfonat-2-pirazinil, ili 6-metilsulfonat-2-pirazinil; i pri čemu: R1, R2 i R4 su metil i R3 je vodik; ili R1 i R4 su metil, R2 je klorid i R3 je vodik; ili R1 i R2 su metil, R4 je klorid i R3 je vodik; ili R1 i R4 su metil, R2 je bromid i R3 je vodik; ili R1 je metil, R2 je klorid, R3 je vodik, i R4 je metoksi; ili R1 je metil, R2 je bromid, R3 je vodik, i R4 je metoksi; ili R1 i R2 su metil, R4 je etenil, i R3 je vodik; ili R1 i R4 su metil, R2 je etinil, i R3 je vodik; ili R1 i R2 su metil, R4 je etinil, i R3 je vodik; ili R1 i R4 su metil, R2 je fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-fluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-kloro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-trifluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 4-fluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 4-kloro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 4-trifluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3,4-difluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-fluoro-4-kloro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-kloro-4-fluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3,4-dikloro-fenil, i R3 je vodik; ili R1 je etil, R2 i R4 su metil i R3 je vodik; ili R1 je etil, R4 je metil, R2 je klorid i R3 je vodik; ili R1 je etil, R2 je metil, R4 je klorid i R3 je vodik; ili R1 je etil, R4 je metil, R2 je bromid i R3 je vodik; ili R1 je etil, R2 je klorid, R3 je vodik, i R4 je metoksi; ili R1 je etil, R2 je bromid, R3 je vodik, i R4 je metoksi; ili R1 je etil, R2 je metil, R4 je etenil, i R3 je vodik; ili R1 je etil, R4 su metil, R2 je etinil, i R3 je vodik; ili R1 je etil, R2 je metil, R4 je etinil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-fluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-kloro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-trifluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 4-fluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 4-kloro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 4-trifluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3,4-difluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-fluoro-4-kloro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-kloro-4-fluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3,4-dikloro-fenil, i R3 je vodik; ili R1 i R4 je etil, R2 je metil i R3 je vodik.
11. Spoj prema zahtjevu 1, naznačen time da je spoj strukturnog tipa T-1: [image] pri čemu R5 je H, R6 je CH3, i R7, R8 i R9 su H; i pri čemu HetAr je 2-piridil, 3-fluoro-2-piridil, 4-fluoro-2-piridil, 5-fluoro-2-piridil, 6-fluoro-2-piridil, 3-kloro-2-piridil, 4-kloro-2-piridil, 5-kloro-2-piridil, 6-kloro-2-piridil, 3-metil-2-piridil, 4-metil-2-piridil, 5-metil-2-piridil, 6-metil-2-piridil, 3-trifluorometil-2-piridil, 4-trifluorometil-2-piridil, 5-trifluorometil-2-piridil, 6-trifluorometil-2-piridil, 3-metoksi-2-piridil, 4-metoksi-2-piridil, 5-metoksi-2-piridil, 6-metoksi-2-piridil, 3-trifluorometoksi-2-piridil, 4-trifluorometoksi-2-piridil, 5-trifluorometoksi-2-piridil, 6-trifluorometoksi-2-piridil, 3-cijano-2-piridil, 4-cijano-2-piridil, 5-cijano-2-piridil, 6-cijano-2-piridil, 3-nitro-2-piridil, 4-nitro-2-piridil, 5-nitro-2-piridil, 6-nitro-2-piridil, 3-metansulfonil-2-piridil, 4-metansulfonil-2-piridil, 5-metansulfonil-2-piridil, 6-metansulfonil-2-piridil, 3-piridil, 2-fluoro-3-piridil, 4-fluoro-3-piridil, 5-fluoro-3-piridil, 6-fluoro-3-piridil, 2-kloro-3-piridil, 4-kloro-3-piridil, 5-kloro-3-piridil, 6-kloro-3-piridil, 2-bromo-3-piridil, 4-bromo-3-piridil, 5-bromo-3-piridil, 6-bromo-3-piridil, 2-metoksi-3-piridil, 4-metoksi-3-piridil, 5-metoksi-3-piridil, 6-metoksi-3-piridil, 2-trifluorometoksi-3-piridil, 4-trifluorometoksi-3-piridil, 5-trifluorometoksi-3-piridil, 6-trifluorometoksi-3-piridil, 2-metil-3-piridil, 4-metil-3-piridil, 5-metil-3-piridil, 6-metil-3-piridil, 2-trifluorometil-3-piridil, 4-trifluorometil-3-piridil, 5- trifluorometil-3-piridil, 6-trifluorometil-3-piridil, 2-cijano-3-piridil, 4-cijano-3-piridil, 5-cijano-3-piridil, 6-cijano-3-piridil, 2-nitro-3-piridil, 4-nitro-3-piridil, 5-nitro-3-piridil, 6-nitro-3-piridil, 2-metansulfonil-3-piridil, 4-metansulfonil-3-piridil, 5-metansulfonil-3-piridil, 6-metansulfonil-3-piridil, 4-piridil, 2-fluoro-4-piridil, 3-fluoro-4-piridil, 2-kloro-4-piridil, 3-kloro-4-piridil, 2-bromo-4-piridil, 3-bromo-4-piridil, 2-metoksi-4-piridil, 3-metoksi-4-piridil, 2-trifluorometoksi-4-piridil, 3-trifluorometoksi-4-piridil, 2-metil-4-piridil, 3-metil-4-piridil, 2-trifluorometil-4-piridil, 3-trifluorometil-4-piridil, 2-cijano-4-piridil, 3-cijano-4-piridil, 2-nitro-4-piridil, 3-nitro-4-piridil, 2-metansulfonil-4-piridil, 3- metansulfonil-4-piridil, 2-piridazinil, 4-fluoro-2-piridazinil, 5-fluoro-2-piridazinil, 6-fluoro-2-piridazinil, 4-kloro-2-piridazinil, 5-kloro-2-piridazinil, 6-kloro-2-piridazinil, 4-bromo-2-piridazinil, 5-bromo-2-piridazinil, 6-bromo-2-piridazinil, 4-metoksi-2-piridazinil, 5-metoksi-2-piridazinil, 6-metoksi-2-piridazinil, 4-trifluorometoksi-2-piridazinil, 5-trifluorometoksi-2-piridazinil, 6-trifluorometoksi-2-piridazinil, 4-metil-2-piridazinil, 5-metil-2-piridazinil, 6-metil-2-piridazinil, 4-trifluorometil-2-piridazinil, 5-trifluorometil-2-piridazinil, 6-trifluorometil-2-piridazinil, 4-cijano-2-piridazinil, 5-cijano-2-piridazinil, 6-cijano-2-piridazinil, 4-nitro-2-piridazinil, 5-nitro-2-piridazinil, 6-nitro-2-piridazinil, 4-metansulfonil-2-piridazinil, 5-metansulfonil-2-piridazinil, 6-metansulfonil-2-piridazinil, 3-piridazinil, 2-fluoro-3-piridazinil, 5-fluoro-3-piridazinil, 6-fluoro-3-piridazinil, 2-kloro-3-piridazinil, 5-kloro-3-piridazinil, 6-kloro-3-piridazinil, 2-bromo-3-piridazinil, 5-bromo-3-piridazinil, 6-bromo-3-piridazinil, 2-metoksi-3-piridazinil, 5-metoksi-3-piridazinil, 6-metoksi-3-piridazinil, 2-trifluorometoksi-3-piridazinil, 5-trifluorometoksi-3-piridazinil, 6-trifluorometoksi-3-piridazinil, 2-metil-3-piridazinil, 5-metil-3-piridazinil, 6-metil-3-piridazinil, 2-trifluorometil-3-piridazinil, 5-trifluorometil-3-piridazinil, 6-trifluorometil-3-piridazinil, 2-cijano-3-piridazinil, 5-cijano-3-piridazinil, 6-cijano-3-piridazinil, 2-nitro-3-piridazinil, 5-nitro-3-piridazinil, 6-nitro-3-piridazinil, 2-metansulfonil-3-piridazinil, 5-metansulfonil-3-piridazinil, 6-metansulfonil-3-piridazinil, 2-pirimidil, 4-fluoro-2-pirimidil, 5-fluoro-2-pirimidil, 4-kloro-2-pirimidil, 5-kloro-2-pirimidil, 4-bromo-2-pirimidil, 5-bromo-2-pirimidil, 4-metoksi-2-pirimidil, 5-metoksi-2-pirimidil, 4-trifluorometoksi-2-pirimidil, 5-trifluorometoksi-2-pirimidil, 4-metil-2-pirimidil, 5-metil-2-pirimidil, 4-trifluorometil-2-pirimidil, 5-trifluorometil-2-pirimidil, 4-cijano-2-pirimidil, 5-cijano-2-pirimidil, 4-nitro-2-pirimidil, 5-nitro-2-pirimidil, 4-metansulfonil-2-pirimidil, 5-metansulfonil-2-pirimidil, 4-pirimidil, 2-fluoro-4-pirimidil, 5-fluoro-4-pirimidil, 6-fluoro-4-pirimidil, 2-kloro-4-pirimidil, 5-kloro-4-pirimidil, 6-kloro-4-pirimidil, 2-bromo-4-pirimidil, 5-bromo-4-pirimidil, 6-bromo-4-pirimidil, 2-metoksi-4-pirimidil, 5-metoksi-4-pirimidil, 6-metoksi-4-pirimidil, 2-trifluorometoksi-4-pirimidil, 5-trifluorometoksi-4-pirimidil, 6-trifluorometoksi-4-pirimidil, 2-metil-4-pirimidil, 5-metil-4-pirimidil, 6-metil-4-pirimidil, 2-trifluorometil-4-pirimidil, 5-trifluorometil-4-pirimidil, 6-trifluorometil-4-pirimidil, 2-cijano-4-pirimidil, 5-cijano-4-pirimidil, 6-cijano-4-pirimidil, 2-nitro-4-pirimidil, 5-nitro-4-pirimidil, 6-nitro-4-pirimidil, 2-metansulfonil-4-pirimidil, 5-metansulfonil-4-pirimidil, 6-metansulfonil-4-pirimidil, 5-pirimidil, 2-fluoro-5-pirimidil, 4-fluoro-5-pirimidil, 2-kloro-5-pirimidil, 4-kloro-5-pirimidil, 2-bromo-5-pirimidil, 4-bromo-5-pirimidil, 2-metoksi-5-pirimidil, 4-metoksi-5-pirimidil, 2-trifluorometoksi-5-pirimidil, 4-trifluorometoksi-5-pirimidil, 2-metil-5-pirimidil, 4-metil-5-pirimidil, 2-trifluorometil-5-pirimidil, 4-trifluorometil-5-pirimidil, 2-cijano-5-pirimidil, 4-cijano-5-pirimidil, 2-nitro-5-pirimidil, 4-nitro-5-pirimidil, 2-metansulfonil-5-pirimidil, 4-metansulfonil-5-pirimidil, 2-pirazinil, 3-fluoro-2-pirazinil, 5-fluoro-2-pirazinil, 6-fluoro-2-pirazinil, 3-kloro-2-pirazinil, 5-kloro-2-pirazinil, 6-kloro-2-pirazinil, 3-bromo-2-pirazinil, 5-bromo-2-pirazinil, 6-bromo-2-pirazinil, 3-metoksi-2-pirazinil, 5-metoksi-2-pirazinil, 6-metoksi-2-pirazinil, 3-trifluorometoksi-2-pirazinil, 5-trifluorometoksi-2-pirazinil, 6-trifluorometoksi-2-pirazinil, 3-metil-2-pirazinil, 5-metil-2-pirazinil, 6-metil-2-pirazinil, 3-trifluorometil-2-pirazinil, 5-trifluorometil-2-pirazinil, 6-trifluorometil-2-pirazinil, 3-cijano-2-pirazinil, 5-cijano-2-pirazinil, 6-cijano-2-pirazinil, 3-nitro-2-pirazinil, 5-nitro-2-pirazinil, 6-nitro-2-pirazinil, 3-metilsulfonat-2-pirazinil, 5-metilsulfonat-2-pirazinil, ili 6-metilsulfonat-2-pirazinil; i pri čemu: R1, R2 i R4 su metil i R3 je vodik; ili R1 i R4 su metil, R2 je klorid i R3 je vodik; ili R1 i R2 su metil, R4 je klorid i R3 je vodik; ili R1 i R4 su metil, R2 je bromid i R3 je vodik; ili R1 je metil, R2 je klorid, R3 je vodik, i R4 je metoksi; ili R1 je metil, R2 je bromid, R3 je vodik, i R4 je metoksi; ili R1 i R2 su metil, R4 je etenil, i R3 je vodik; ili R1 i R4 su metil, R2 je etinil, i R3 je vodik; ili R1 i R2 su metil, R4 je etinil, i R3 je vodik; ili R1 i R4 su metil, R2 je fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-fluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-kloro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-trifluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 4-fluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 4-kloro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 4-trifluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3,4-difluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-fluoro-4-kloro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-kloro-4-fluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3,4-dikloro-fenil, i R3 je vodik; ili R1 je etil, R2 i R4 su metil i R3 je vodik; ili R1 je etil, R4 je metil, R2 je klorid i R3 je vodik; ili R1 je etil, R2 je metil, R4 je klorid i R3 je vodik; ili R1 je etil, R4 je metil, R2 je bromid i R3 je vodik; ili R1 je etil, R2 je klorid, R3 je vodik, i R4 je metoksi; ili R1 je etil, R2 je bromid, R3 je vodik, i R4 je metoksi; ili R1 je etil, R2 je metil, R4 je etenil, i R3 je vodik; ili R1 je etil, R4 su metil, R2 je etinil, i R3 je vodik; ili R1 je etil, R2 je metil, R4 je etinil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-fluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-kloro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-trifluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 4-fluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 4-kloro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 4-trifluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3,4-difluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-fluoro-4-kloro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-kloro-4-fluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3,4-dikloro-fenil, i R3 je vodik; ili R1 i R4 je etil, R2 je metil i R3 je vodik.
12. Spoj prema zahtjevu 1, naznačen time da je spoj strukturnog tipa T-1: [image] pri čemu R5 je H, R6 i R7 su CH3, i R8 i R9 su H; i pri čemu HetAr je 2-piridil, 3-fluoro-2-piridil, 4-fluoro-2-piridil, 5-fluoro-2-piridil, 6-fluoro-2-piridil, 3-kloro-2-piridil, 4-kloro-2-piridil, 5-kloro-2-piridil, 6-kloro-2-piridil, 3-metil-2-piridil, 4-metil-2-piridil, 5-metil-2-piridil, 6-metil-2-piridil, 3-trifluorometil-2-piridil, 4-trifluorometil-2-piridil, 5-trifluorometil-2-piridil, 6-trifluorometil-2-piridil, 3-metoksi-2-piridil, 4-metoksi-2-piridil, 5-metoksi-2-piridil, 6-metoksi-2-piridil, 3-trifluorometoksi-2-piridil, 4-trifluorometoksi-2-piridil, 5-trifluorometoksi-2-piridil, 6-trifluorometoksi-2-piridil, 3-cijano-2-piridil, 4-cijano-2-piridil, 5-cijano-2-piridil, 6-cijano-2-piridil, 3-nitro-2-piridil, 4-nitro-2-piridil, 5-nitro-2-piridil, 6-nitro-2-piridil, 3-metansulfonil-2-piridil, 4-metansulfonil-2-piridil, 5-metansulfonil-2-piridil, 6-metansulfonil-2-piridil, 3-piridil, 2-fluoro-3-piridil, 4-fluoro-3-piridil, 5-fluoro-3-piridil, 6-fluoro-3-piridil, 2-kloro-3-piridil, 4-kloro-3-piridil, 5-kloro-3-piridil, 6-kloro-3-piridil, 2-bromo-3-piridil, 4-bromo-3-piridil, 5-bromo-3-piridil, 6-bromo-3-piridil, 2-metoksi-3-piridil, 4-metoksi-3-piridil, 5-metoksi-3-piridil, 6-metoksi-3-piridil, 2-trifluorometoksi-3-piridil, 4-trifluorometoksi-3-piridil, 5-trifluorometoksi-3-piridil, 6-trifluorometoksi-3-piridil, 2-metil-3-piridil, 4-metil-3-piridil, 5-metil-3-piridil, 6-metil-3-piridil, 2-trifluorometil-3-piridil, 4-trifluorometil-3-piridil, 5- trifluorometil-3-piridil, 6-trifluorometil-3-piridil, 2-cijano-3-piridil, 4-cijano-3-piridil, 5-cijano-3-piridil, 6-cijano-3-piridil, 2-nitro-3-piridil, 4-nitro-3-piridil, 5-nitro-3-piridil, 6-nitro-3-piridil, 2-metansulfonil-3-piridil, 4-metansulfonil-3-piridil, 5-metansulfonil-3-piridil, 6-metansulfonil-3-piridil, 4-piridil, 2-fluoro-4-piridil, 3-fluoro-4-piridil, 2-kloro-4-piridil, 3-kloro-4-piridil, 2-bromo-4-piridil, 3-bromo-4-piridil, 2-metoksi-4-piridil, 3-metoksi-4-piridil, 2-trifluorometoksi-4-piridil, 3-trifluorometoksi-4-piridil, 2-metil-4-piridil, 3-metil-4-piridil, 2-trifluorometil-4-piridil, 3-trifluorometil-4-piridil, 2-cijano-4-piridil, 3-cijano-4-piridil, 2-nitro-4-piridil, 3-nitro-4-piridil, 2-metansulfonil-4-piridil, 3- metansulfonil-4-piridil, 2-piridazinil, 4-fluoro-2-piridazinil, 5-fluoro-2-piridazinil, 6-fluoro-2-piridazinil, 4-kloro-2-piridazinil, 5-kloro-2-piridazinil, 6-kloro-2-piridazinil, 4-bromo-2-piridazinil, 5-bromo-2-piridazinil, 6-bromo-2-piridazinil, 4-metoksi-2-piridazinil, 5-metoksi-2-piridazinil, 6-metoksi-2-piridazinil, 4-trifluorometoksi-2-piridazinil, 5-trifluorometoksi-2-piridazinil, 6-trifluorometoksi-2-piridazinil, 4-metil-2-piridazinil, 5-metil-2-piridazinil, 6-metil-2-piridazinil, 4-trifluorometil-2-piridazinil, 5-trifluorometil-2-piridazinil, 6-trifluorometil-2-piridazinil, 4-cijano-2-piridazinil, 5-cijano-2-piridazinil, 6-cijano-2-piridazinil, 4-nitro-2-piridazinil, 5-nitro-2-piridazinil, 6-nitro-2-piridazinil, 4-metansulfonil-2-piridazinil, 5-metansulfonil-2-piridazinil, 6-metansulfonil-2-piridazinil, 3-piridazinil, 2-fluoro-3-piridazinil, 5-fluoro-3-piridazinil, 6-fluoro-3-piridazinil, 2-kloro-3-piridazinil, 5-kloro-3-piridazinil, 6-kloro-3-piridazinil, 2-bromo-3-piridazinil, 5-bromo-3-piridazinil, 6-bromo-3-piridazinil, 2-metoksi-3-piridazinil, 5-metoksi-3-piridazinil, 6-metoksi-3-piridazinil, 2-trifluorometoksi-3-piridazinil, 5-trifluorometoksi-3-piridazinil, 6-trifluorometoksi-3-piridazinil, 2-metil-3-piridazinil, 5-metil-3-piridazinil, 6-metil-3-piridazinil, 2-trifluorometil-3-piridazinil, 5-trifluorometil-3-piridazinil, 6-trifluorometil-3-piridazinil, 2-cijano-3-piridazinil, 5-cijano-3-piridazinil, 6-cijano-3-piridazinil, 2-nitro-3-piridazinil, 5-nitro-3-piridazinil, 6-nitro-3-piridazinil, 2-metansulfonil-3-piridazinil, 5-metansulfonil-3-piridazinil, 6-metansulfonil-3-piridazinil, 2-pirimidil, 4-fluoro-2-pirimidil, 5-fluoro-2-pirimidil, 4-kloro-2-pirimidil, 5-kloro-2-pirimidil, 4-bromo-2-pirimidil, 5-bromo-2-pirimidil, 4-metoksi-2-pirimidil, 5-metoksi-2-pirimidil, 4-trifluorometoksi-2-pirimidil, 5-trifluorometoksi-2-pirimidil, 4-metil-2-pirimidil, 5-metil-2-pirimidil, 4-trifluorometil-2-pirimidil, 5-trifluorometil-2-pirimidil, 4-cijano-2-pirimidil, 5-cijano-2-pirimidil, 4-nitro-2-pirimidil, 5-nitro-2-pirimidil, 4-metansulfonil-2-pirimidil, 5-metansulfonil-2-pirimidil, 4-pirimidil, 2-fluoro-4-pirimidil, 5-fluoro-4-pirimidil, 6-fluoro-4-pirimidil, 2-kloro-4-pirimidil, 5-kloro-4-pirimidil, 6-kloro-4-pirimidil, 2-bromo-4-pirimidil, 5-bromo-4-pirimidil, 6-bromo-4-pirimidil, 2-metoksi-4-pirimidil, 5-metoksi-4-pirimidil, 6-metoksi-4-pirimidil, 2-trifluorometoksi-4-pirimidil, 5-trifluorometoksi-4-pirimidil, 6-trifluorometoksi-4-pirimidil, 2-metil-4-pirimidil, 5-metil-4-pirimidil, 6-metil-4-pirimidil, 2-trifluorometil-4-pirimidil, 5-trifluorometil-4-pirimidil, 6-trifluorometil-4-pirimidil, 2-cijano-4-pirimidil, 5-cijano-4-pirimidil, 6-cijano-4-pirimidil, 2-nitro-4-pirimidil, 5-nitro-4-pirimidil, 6-nitro-4-pirimidil, 2-metansulfonil-4-pirimidil, 5-metansulfonil-4-pirimidil, 6-metansulfonil-4-pirimidil, 5-pirimidil, 2-fluoro-5-pirimidil, 4-fluoro-5-pirimidil, 2-kloro-5-pirimidil, 4-kloro-5-pirimidil, 2-bromo-5-pirimidil, 4-bromo-5-pirimidil, 2-metoksi-5-pirimidil, 4-metoksi-5-pirimidil, 2-trifluorometoksi-5-pirimidil, 4-trifluorometoksi-5-pirimidil, 2-metil-5-pirimidil, 4-metil-5-pirimidil, 2-trifluorometil-5-pirimidil, 4-trifluorometil-5-pirimidil, 2-cijano-5-pirimidil, 4-cijano-5-pirimidil, 2-nitro-5-pirimidil, 4-nitro-5-pirimidil, 2-metansulfonil-5-pirimidil, 4-metansulfonil-5-pirimidil, 2-pirazinil, 3-fluoro-2-pirazinil, 5-fluoro-2-pirazinil, 6-fluoro-2-pirazinil, 3-kloro-2-pirazinil, 5-kloro-2-pirazinil, 6-kloro-2-pirazinil, 3-bromo-2-pirazinil, 5-bromo-2-pirazinil, 6-bromo-2-pirazinil, 3-metoksi-2-pirazinil, 5-metoksi-2-pirazinil, 6-metoksi-2-pirazinil, 3-trifluorometoksi-2-pirazinil, 5-trifluorometoksi-2-pirazinil, 6-trifluorometoksi-2-pirazinil, 3-metil-2-pirazinil, 5-metil-2-pirazinil, 6-metil-2-pirazinil, 3-trifluorometil-2-pirazinil, 5-trifluorometil-2-pirazinil, 6-trifluorometil-2-pirazinil, 3-cijano-2-pirazinil, 5-cijano-2-pirazinil, 6-cijano-2-pirazinil, 3-nitro-2-pirazinil, 5-nitro-2-pirazinil, 6-nitro-2-pirazinil, 3-metilsulfonat-2-pirazinil, 5-metilsulfonat-2-pirazinil, ili 6-metilsulfonat-2-pirazinil; i pri čemu: R1, R2 i R4 su metil i R3 je vodik; ili R1 i R4 su metil, R2 je klorid i R3 je vodik; ili R1 i R2 su metil, R4 je klorid i R3 je vodik; ili R1 i R4 su metil, R2 je bromid i R3 je vodik; ili R1 je metil, R2 je klorid, R3 je vodik, i R4 je metoksi; ili R1 je metil, R2 je bromid, R3 je vodik, i R4 je metoksi; ili R1 i R2 su metil, R4 je etenil, i R3 je vodik; ili R1 i R4 su metil, R2 je etinil, i R3 je vodik; ili R1 i R2 su metil, R4 je etinil, i R3 je vodik; ili R1 i R4 su metil, R2 je fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-fluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-kloro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-trifluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 4-fluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 4-kloro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 4-trifluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3,4-difluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-fluoro-4-kloro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3-kloro-4-fluoro-fenil, i R3 je vodik; ili R1 i R4 su metil, R2 je 3,4-dikloro-fenil, i R3 je vodik; ili R1 je etil, R2 i R4 su metil i R3 je vodik; ili R1 je etil, R4 je metil, R2 je klorid i R3 je vodik; ili R1 je etil, R2 je metil, R4 je klorid i R3 je vodik; ili R1 je etil, R4 je metil, R2 je bromid i R3 je vodik; ili R1 je etil, R2 je klorid, R3 je vodik, i R4 je metoksi; ili R1 je etil, R2 je bromid, R3 je vodik, i R4 je metoksi; ili R1 je etil, R2 je metil, R4 je etenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je etinil, i R3 je vodik; ili R1 je etil, R2 je metil, R4 je etinil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-fluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-kloro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-trifluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 4-fluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 4-kloro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 4-trifluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3,4-difluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-fluoro-4-kloro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3-kloro-4-fluoro-fenil, i R3 je vodik; ili R1 je etil, R4 je metil, R2 je 3,4-dikloro-fenil, i R3 je vodik; ili R1 i R4 je etil, R2 je metil i R3 je vodik.
13. Herbicidna smjesa, koja je, pored toga što sadrži formulacijska pomoćna sredstva, naznačena time da sadrži herbicidno učinkovitu količinu spoja s formulom I kako je definirano u bilo kojem od zahtjeva 1 do 8.
14. Herbicidna smjesa prema zahtjevu 13, koja je, pored toga što sadrži formulacijska pomoćna sredstva, naznačena time da sadrži herbicidno učinkovitu količinu spoja s formulom I, dodatni herbicid, te proizvoljno zaštitnu supstancu.
15. Herbicidna smjesa prema zahtjevu 13, koja je, pored toga što sadrži formulacijska pomoćna sredstva, naznačena time da sadrži herbicidno učinkovitu količinu spoja s formulom I, zaštitnu supstancu, te proizvoljno dodatni herbicid.
16. Postupak suzbijanja trava i korova u usjevima korisnih biljaka, naznačen time da se sastoji od primjene herbicidno učinkovite količine spoja s formulom I kako je definirano u bilo kojem od zahtjeva 1 do 8, ili pripravka koji sadrži takav spoj, na biljke ili na njihov lokus.
17. Postupak prema zahtjevu 16, koji je postupak suzbijanja trava i korova u usjevima korisnih biljaka, naznačen time da se sastoji od primjene herbicidno učinkovite količine smjese koja sadrži spoj s formulom I na biljke ili na njihov lokus, te pri čemu su usjevi korisnih biljaka pšenica, ječam, riža, kukuruz, repica, šećerna repa, šećerna trska, soja, pamuk, suncokret, ili kikiriki.
18. Postupak prema zahtjevu 17, naznačen time da su usjevi korisnih biljaka pšenica ili ječam.
19. Smjesa spoja s formulom I, kako je definirano u bilo kojem od zahtjeva 1 do 8, u kombinaciji s dodatnim herbicidom, naznačena time da je smjesa spoja s formulom I izabrana iz skupa koji sadrži: spoj s formulom I + acetoklor, spoj s formulom I + acifluorfen, spoj s formulom I + acifluorfen-natrij, spoj s formulom I + aklonifen, spoj s formulom I + akrolein, spoj s formulom I + alaklor, spoj s formulom I + aloksidim, spoj s formulom I + alil alkohol, spoj s formulom I + ametrin, spoj s formulom I + amikarbazon, spoj s formulom I + amidosulfuron, spoj s formulom I + aminopiralid, spoj s formulom I + amitrol, spoj s formulom I + amonijev sulfamat, spoj s formulom I + anilofos, spoj s formulom I + asulam, spoj s formulom I + atraton, spoj s formulom I + atrazin, spoj s formulom I + azimsulfuron, spoj s formulom I + BCPC, spoj s formulom I + beflubutamid, spoj s formulom I + benazolin, spoj s formulom I + benfluralin, spoj s formulom I + benfuresat, spoj s formulom I + bensulfuron, spoj s formulom I + bensulfuron-metil, spoj s formulom I + bensulid, spoj s formulom I + bentazon, spoj s formulom I + benzfendizon, spoj s formulom I + benzobiciklon, spoj s formulom I + benzofenap, spoj s formulom I + bifenoks, spoj s formulom I + bilanafos, spoj s formulom I + bispiribak, spoj s formulom I + bispiribak-natrij, spoj s formulom I + boraks, spoj s formulom I + bromacil, spoj s formulom I + bromobutid, spoj s formulom I + bromoksinil, spoj s formulom I + butaklor, spoj s formulom I + butafenacil, spoj s formulom I + butamifos, spoj s formulom I + butralin, spoj s formulom I + butroksidim, spoj s formulom I + butilat, spoj s formulom I + kakodilna kiselina, spoj s formulom I + kalcijev klorat, spoj s formulom I + kafenstrol, spoj s formulom I + karbetamid, spoj s formulom I + karfentrazon, spoj s formulom I + karfentrazon-etil, spoj s formulom I + CDEA, spoj s formulom I + CEPC, spoj s formulom I + klorflurenol, spoj s formulom I + klorflurenol-metil, spoj s formulom I + kloridazon, spoj s formulom I + klorimuron, spoj s formulom I + klorimuron-etil, spoj s formulom I + klorooctena kiselina, spoj s formulom I + klorotoluron, spoj s formulom I + klorprofam, spoj s formulom I + klorsulfuron, spoj s formulom I + klortal, spoj s formulom I + klortal-dimetil, spoj s formulom I + cinidon-etil, spoj s formulom I + cinmetilin, spoj s formulom I + cinosulfuron, spoj s formulom I + cisanilid, spoj s formulom I + cletodim, spoj s formulom I + klodinafop, spoj s formulom I + klodinafop-propargil, spoj s formulom I + klomazon, spoj s formulom I + klomeprop, spoj s formulom I + klopiralid, spoj s formulom I + kloransulam, spoj s formulom I + kloransulam-metil, spoj s formulom I + CMA, spoj s formulom I + 4-CPB, spoj s formulom I + CPMF, spoj s formulom I + 4-CPP, spoj s formulom I + CPPC, spoj s formulom I + kresol, spoj s formulom I + kumiluron, spoj s formulom I + cijanamid, spoj s formulom I + cijanazin, spoj s formulom I + cikloat, spoj s formulom I + ciklosulfamuron, spoj s formulom I + cikloksidim, spoj s formulom I + cihalofop, spoj s formulom I + cihalofop-butil, spoj s formulom I + 2,4-D, spoj s formulom I + 3,4-DA, spoj s formulom I + daimuron, spoj s formulom I + dalapon, spoj s formulom I + dazomet, spoj s formulom I + 2,4-DB, spoj s formulom I + 3,4-DB, spoj s formulom I + 2,4-DEB, spoj s formulom I + desmedifam, spoj s formulom I + dikamba, spoj s formulom I + diklobenil, spoj s formulom I + orto-diklorobenzen, spoj s formulom I + para-diklorobenzen, spoj s formulom I + diklorprop, spoj s formulom I + diklorprop-P, spoj s formulom I + diklofop, spoj s formulom I + diklofop-metil, spoj s formulom I + diklosulam, spoj s formulom I + difenzokvat, spoj s formulom I + difenzokvat metilsulfat, spoj s formulom I + diflufenican, spoj s formulom I + diflufenzopir, spoj s formulom I + dimefuron, spoj s formulom I + dimepiperat, spoj s formulom I + dimetaklor, spoj s formulom I + dimetametrin, spoj s formulom I + dimetenamid, spoj s formulom I + dimetenamid-P, spoj s formulom I + dimetipin, spoj s formulom I + dimetilarsinska kiselina, spoj s formulom I + dinitramin, spoj s formulom I + dinoterb, spoj s formulom I + difenamid, spoj s formulom I + dikvat, spoj s formulom I + dikvat dibromid, spoj s formulom I + ditiopir, spoj s formulom I + diuron, spoj s formulom I + DNOC, spoj s formulom I + 3,4-DP, spoj s formulom I + DSMA, spoj s formulom I + EBEP, spoj s formulom I + endotal, spoj s formulom I + EPTC, spoj s formulom I + esprokarb, spoj s formulom I + etalfluralin, spoj s formulom I + etametsulfuron, spoj s formulom I + etametsulfuron-metil, spoj s formulom I + etofumesat, spoj s formulom I + etoksifen, spoj s formulom I + etoksisulfuron, spoj s formulom I + etobenzanid, spoj s formulom I + fenoksaprop-P, spoj s formulom I + fenoksaprop-P-etil, spoj s formulom I + fentrazamid, spoj s formulom I + željezni sulfat, spoj s formulom I + flamprop-M, spoj s formulom I + flazasulfuron, spoj s formulom I + florasulam, spoj s formulom I + fluazifop, spoj s formulom I + fluazifop-butil, spoj s formulom I + fluazifop-P, spoj s formulom I + fluazifop-P-butil, spoj s formulom I + flukarbazon, spoj s formulom I + flukarbazon-natrij, spoj s formulom I + flucetosulfuron, spoj s formulom I + flukloralin, spoj s formulom I + flufenacet, spoj s formulom I + flufenpir, spoj s formulom I + flufenpir-etil, spoj s formulom I + flumetsulam, spoj s formulom I + flumiklorak, spoj s formulom I + flumiklorak-pentil, spoj s formulom I + flumioksazin, spoj s formulom I + fluometuron, spoj s formulom I + fluoroglikofen, spoj s formulom I + fluoroglikofen-etil, spoj s formulom I + flupropanat, spoj s formulom I + flupirsulfuron, spoj s formulom I + flupirsulfuron-metil-natrij, spoj s formulom I + flurenol, spoj s formulom I + fluridon, spoj s formulom I + flurokloridon, spoj s formulom I + fluroksipir, spoj s formulom I + flurtamon, spoj s formulom I + flutiacet, spoj s formulom I + flutiacet-metil, spoj s formulom I + fomesafen, spoj s formulom I + foramsulfuron, spoj s formulom I + fosamin, spoj s formulom I + glufosinat, spoj s formulom I + glufosinat-amonij, spoj s formulom I + glifosat, spoj s formulom I + halosulfuron, spoj s formulom I + halosulfuron-metil, spoj s formulom I + haloksifop, spoj s formulom I + haloksifop-P, spoj s formulom I + HC-252, spoj s formulom I + heksazinon, spoj s formulom I + imazametabenz, spoj s formulom I + imazametabenz-metil, spoj s formulom I + imazamoks, spoj s formulom I + imazapik, spoj s formulom I + imazapir, spoj s formulom I + imazakvin, spoj s formulom I + imazetapir, spoj s formulom I + imazosulfuron, spoj s formulom I + indanofan, spoj s formulom I + jodometan, spoj s formulom I + jodosulfuron, spoj s formulom I + jodosulfuron-metil-natrij, spoj s formulom I + ioksinil, spoj s formulom I + izoproturon, spoj s formulom I + izouron, spoj s formulom I + izoksaben, spoj s formulom I + izoksaklortol, spoj s formulom I + izoksaflutol, spoj s formulom I + karbutilat, spoj s formulom I + laktofen, spoj s formulom I + lenacil, spoj s formulom I + linuron, spoj s formulom I + MAA, spoj s formulom I + MAMA, spoj s formulom I + MCPA, spoj s formulom I + MCPA-tioetil, spoj s formulom I + MCPB, spoj s formulom I + mekoprop, spoj s formulom I + mekoprop-P, spoj s formulom I + mefenacet, spoj s formulom I + mefluidid, spoj s formulom I + mezosulfuron, spoj s formulom I + mezosulfuron-metil, spoj s formulom I + mezotrion, spoj s formulom I + metam, spoj s formulom I + metamifop, spoj s formulom I + metamitron, spoj s formulom I + metazaklor, spoj s formulom I + metabenztiazuron, spoj s formulom I + metilarsonska kiselina, spoj s formulom I + metildimron, spoj s formulom I + metil izotiocijanat, spoj s formulom I + metobenzuron, spoj s formulom I + metolaklor, spoj s formulom I + S-metolaklor, spoj s formulom I + metosulam, spoj s formulom I + metoksuron, spoj s formulom I + metribuzin, spoj s formulom I + metsulfuron, spoj s formulom I + metsulfuron-metil, spoj s formulom I + MK-616, spoj s formulom I + molinat, spoj s formulom I + monolinuron, spoj s formulom I + MSMA, spoj s formulom I + naproanilid, spoj s formulom I + napropamid, spoj s formulom I + naptalam, spoj s formulom I + neburon, spoj s formulom I + nikosulfuron, spoj s formulom I + nonanska kiselina, spoj s formulom I + norflurazon, spoj s formulom I + oleinska kiselina (masne kiseline), spoj s formulom I + orbenkarb, spoj s formulom I + ortosulfamuron, spoj s formulom I + orizalin, spoj s formulom I + oksadiargil, spoj s formulom I + oksadiazon, spoj s formulom I + oksasulfuron, spoj s formulom I + oksaziklomefon, spoj s formulom I + oksifluorfen, spoj s formulom I + parakvat, spoj s formulom I + parakvat diklorid, spoj s formulom I + pebulat, spoj s formulom I + pendimetalin, spoj s formulom I + penokssulam, spoj s formulom I + pentaklorofenol, spoj s formulom I + pentanoklor, spoj s formulom I + pentoksazon, spoj s formulom I + petoksamid, spoj s formulom I + naftna ulja, spoj s formulom I + fenmedifam, spoj s formulom I + fenmedifam-etil, spoj s formulom I + pikloram, spoj s formulom I + pikolinafen, spoj s formulom I + pinoksaden, spoj s formulom I + piperofos, spoj s formulom I + kalijev arsenit, spoj s formulom I + kalijev azid, spoj s formulom I + pretilaklor, spoj s formulom I + primisulfuron, spoj s formulom I + primisulfuron-metil, spoj s formulom I + prodiamin, spoj s formulom I + profluazol, spoj s formulom I + profoksidim, spoj s formulom I + prometon, spoj s formulom I + prometrin, spoj s formulom I + propaklor, spoj s formulom I + propanil, spoj s formulom I + propakvizafop, spoj s formulom I + propazin, spoj s formulom I + propam, spoj s formulom I + propizoklor, spoj s formulom I + propoksikarbazon, spoj s formulom I + propoksikarbazon-natrij, spoj s formulom I + propizamid, spoj s formulom I + prosulfokarb, spoj s formulom I + prosulfuron, spoj s formulom I + piraklonil, spoj s formulom I + piraflufen, spoj s formulom I + piraflufen-etil, spoj s formulom I + pirazolinat, spoj s formulom I + pirazosulfuron, spoj s formulom I + pirazosulfuron-etil, spoj s formulom I + pirazoksifen, spoj s formulom I + piribenzoksim, spoj s formulom I + piributikarb, spoj s formulom I + piridafol, spoj s formulom I + piridat, spoj s formulom I + piriftalid, spoj s formulom I + piriminobak, spoj s formulom I + piriminobak-metil, spoj s formulom I + pirimisulfan, spoj s formulom I + piritiobak, spoj s formulom I + piritiobak-natrij, spoj s formulom I + kvinklorak, spoj s formulom I + kvinmerak, spoj s formulom I + kvinoklamin, spoj s formulom I + kvizalofop, spoj s formulom I + kvizalofop-P, spoj s formulom I + rimsulfuron, spoj s formulom I + setoksidim, spoj s formulom I + siduron, spoj s formulom I + simazin, spoj s formulom I + simetrin, spoj s formulom I + SMA, spoj s formulom I + natrijev arsenit, spoj s formulom I + natrijev azid, spoj s formulom I + natrijev klorat, spoj s formulom I + sulkotrion, spoj s formulom I + sulfentrazon, spoj s formulom I + sulfometuron, spoj s formulom I + sulfometuron-metil, spoj s formulom I + sulfosat, spoj s formulom I + sulfosulfuron, spoj s formulom I + sumporna kiselina, spoj s formulom I + katranska ulja, spoj s formulom I + 2,3,6-TBA, spoj s formulom I + TCA, spoj s formulom I + TCA-natrij, spoj s formulom I + tebutiuron, spoj s formulom I + tepraloksidim, spoj s formulom I + terbacil, spoj s formulom I + terbumeton, spoj s formulom I + terbutilazin, spoj s formulom I + terbutrin, spoj s formulom I + tenilklor, spoj s formulom I + tiazopir, spoj s formulom I + tifensulfuron, spoj s formulom I + tifensulfuron-metil, spoj s formulom I + tiobenkarb, spoj s formulom I + tiokarbazil, spoj s formulom I + topramezon, spoj s formulom I + tralkoksidim, spoj s formulom I + tri-alat, spoj s formulom I + triasulfuron, spoj s formulom I + triaziflam, spoj s formulom I + tribenuron, spoj s formulom I + tribenuron-metil, spoj s formulom I + trikamba, spoj s formulom I + triklopir, spoj s formulom I + trietazin, spoj s formulom I + trifloksisulfuron, spoj s formulom I + trifloksisulfuron-natrij, spoj s formulom I + trifluralin, spoj s formulom I + triflusulfuron, spoj s formulom I + triflusulfuron-metil, spoj s formulom I + trihidroksitriazin, spoj s formulom I + tritosulfuron, spoj s formulom I + etil ester [3-[2-kloro-4-fluoro-5-(1-metil-6-trifluorometil-2,4-diokso-1,2,3,4-tetrahidropirimidin-3-il)fenoksi]-2-piridiloksi]octene kiseline, spoj s formulom I + 4-[(4,5-dihidro-3-metoksi-4-metil-5-okso)-1H-1,2,4-triazol-1-ilkarbonilsulfamoil]-5-metiltiofen-3-karboksilna kiselina, spoj s formulom I + BAY747 koji ima CAS referentni broj 335104-84-2, spoj s formulom I + topramezon, spoj s formulom I + 4-hidroksi-3-[[2-[(2-metoksietoksi)metil]-6-(trifluorometil)-3-piridinil]karbonil]-biciklo[3.2.1]okt-3-en-2-on, i spoj s formulom I + 4-hidroksi-3-[[2-(3-metoksipropil)-6-(difluorometil)-3-piridinil]karbonil]-biciklo[3.2.1]okt-3-en-2-on; i pri čemu je partner u smjesi za spoj s formulom I proizvoljno u obliku estera ili soli.
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