HRP20110774T1 - Obrađena mineralna punila, postupak za njihovu pripremu i njihova uporaba - Google Patents
Obrađena mineralna punila, postupak za njihovu pripremu i njihova uporaba Download PDFInfo
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- HRP20110774T1 HRP20110774T1 HR20110774T HRP20110774T HRP20110774T1 HR P20110774 T1 HRP20110774 T1 HR P20110774T1 HR 20110774 T HR20110774 T HR 20110774T HR P20110774 T HRP20110774 T HR P20110774T HR P20110774 T1 HRP20110774 T1 HR P20110774T1
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- 239000012764 mineral filler Substances 0.000 title claims abstract 27
- 238000000034 method Methods 0.000 title claims abstract 25
- 238000002360 preparation method Methods 0.000 title claims 4
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims abstract 58
- 150000003839 salts Chemical class 0.000 claims abstract 26
- -1 C24 aliphatic carboxylic acid Chemical class 0.000 claims abstract 19
- 229920006395 saturated elastomer Polymers 0.000 claims abstract 4
- 238000010438 heat treatment Methods 0.000 claims abstract 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 13
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 6
- AOHAPDDBNAPPIN-UHFFFAOYSA-N 3-Methoxy-4,5-methylenedioxybenzoic acid Chemical compound COC1=CC(C(O)=O)=CC2=C1OCO2 AOHAPDDBNAPPIN-UHFFFAOYSA-N 0.000 claims 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 4
- 150000001768 cations Chemical class 0.000 claims 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims 4
- 235000021314 Palmitic acid Nutrition 0.000 claims 3
- 235000021355 Stearic acid Nutrition 0.000 claims 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Chemical class CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 3
- 239000005639 Lauric acid Substances 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims 2
- 239000010459 dolomite Substances 0.000 claims 2
- 229910000514 dolomite Inorganic materials 0.000 claims 2
- 239000000194 fatty acid Substances 0.000 claims 2
- 229930195729 fatty acid Natural products 0.000 claims 2
- 150000004665 fatty acids Chemical class 0.000 claims 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 239000004579 marble Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000011707 mineral Substances 0.000 claims 2
- 239000004033 plastic Substances 0.000 claims 2
- 229920003023 plastic Polymers 0.000 claims 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- 229920001155 polypropylene Polymers 0.000 claims 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 2
- 229910021532 Calcite Inorganic materials 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 235000019738 Limestone Nutrition 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 159000000007 calcium salts Chemical class 0.000 claims 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims 1
- 239000008116 calcium stearate Substances 0.000 claims 1
- 235000013539 calcium stearate Nutrition 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 238000007765 extrusion coating Methods 0.000 claims 1
- 238000001746 injection moulding Methods 0.000 claims 1
- 239000006028 limestone Substances 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 159000000003 magnesium salts Chemical class 0.000 claims 1
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Substances [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims 1
- 235000019359 magnesium stearate Nutrition 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- 239000010453 quartz Substances 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- 239000008117 stearic acid Substances 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 239000012815 thermoplastic material Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
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Abstract
Postupak za pripremu obrađenih mineralnih punila, naznačen time da se navedeni postupak sastoji od sljedećih koraka: (a) pripreme najmanje jednog suhog mineralnog punila; (b) pripreme najmanje jedne zasićene C8 do C24 alifatske karboksilne kiseline (c) pripreme najmanje jedne dvovalentne i/ili trovalentne soli kationa jedne ili više zasićenih C8 do C24 alifatskih karboksilnih kiselina; (d) kontakta navedenog(ih) mineralnog(ih) punila iz koraka (a), u jednom ili više koraka uz grijanje, sa: a. "alifatskom karboksilnom kiselinom odnosno alifatskim karboksilnim kiselinama" iz koraka (b); b. "soli alifatske karboksilne kiseline odnosno solima alifatskih karboksilnih kiselina" iz koraka (c); te nakon toga (e) stvaranja na površini navedenog(ih) mineralnog(ih) punila obrađenog sloja koji sadrži navedenu alifatsku karboksilnu kiselinu odnosno alifatske karboksilne kiseline i navedenu sol alifatske karboksilne kiseline odnosno soli alifatskih karboksilnih kiselina, što dovodi do obrađenog mineralnog punila kao produkta; naznačen time da: - težinski omjer svih navedenih soli alifatskih karboksilnih kiselina pripremljenih u koraku (c) prema svim navedenim alifatskim karboksilnim kiselinama pripremljenim u koraku (b) je od 51:49 do 75:25; - ukupna težina svih navedenih soli alifatskih karboksilnih kiselina i svih navedenih alifatskih karboksilnih kiselina koje se nalaze na površini mineralnog punila je barem 2.5 mg/m mineralnog punila pripremljenog u koraku (a); - tijekom koraka (d), temperatura je podešena tako da su rastaljene sve alifatske karboksilne kiseline i sve soli alifatskih karboksilnih kiselina. Patent sadrži još 22 patentna zahtjeva.
Claims (23)
1. Postupak za pripremu obrađenih mineralnih punila, naznačen time da se navedeni postupak sastoji od sljedećih koraka:
(a) pripreme najmanje jednog suhog mineralnog punila;
(b) pripreme najmanje jedne zasićene C8 do C24 alifatske karboksilne kiseline
(c) pripreme najmanje jedne dvovalentne i/ili trovalentne soli kationa jedne ili više zasićenih C8 do C24 alifatskih karboksilnih kiselina;
(d) kontakta navedenog(ih) mineralnog(ih) punila iz koraka (a), u jednom ili više koraka uz grijanje, sa:
a. "alifatskom karboksilnom kiselinom odnosno alifatskim karboksilnim kiselinama" iz koraka (b);
b. "soli alifatske karboksilne kiseline odnosno solima alifatskih karboksilnih kiselina" iz koraka (c); te nakon toga
(e) stvaranja na površini navedenog(ih) mineralnog(ih) punila obrađenog sloja koji sadrži navedenu alifatsku karboksilnu kiselinu odnosno alifatske karboksilne kiseline i navedenu sol alifatske karboksilne kiseline odnosno soli alifatskih karboksilnih kiselina, što dovodi do obrađenog mineralnog punila kao produkta;
naznačen time da:
- težinski omjer svih navedenih soli alifatskih karboksilnih kiselina pripremljenih u koraku (c) prema svim navedenim alifatskim karboksilnim kiselinama pripremljenim u koraku (b) je od 51:49 do 75:25;
- ukupna težina svih navedenih soli alifatskih karboksilnih kiselina i svih navedenih alifatskih karboksilnih kiselina koje se nalaze na površini mineralnog punila je barem 2.5 mg/m mineralnog punila pripremljenog u koraku (a);
- tijekom koraka (d), temperatura je podešena tako da su rastaljene sve alifatske karboksilne kiseline i sve soli alifatskih karboksilnih kiselina.
2. Postupak prema zahtjevu 1, naznačen time da navedeni težinski omjer svih navedenih soli alifatskih karboksilnih kiselina prema svim navedenim alifatskim karboksilnim kiselinama je od 55:45 do 75:25, još poželjnije je od oko 60:40 do 70:30, npr. od 64:36 do 67:33.
3. Postupak prema zahtjevu 1 ili 2, naznačen time da mineralno punilo odnosno punila u koraku (a) su mineralna punila koja sadrže kalcij karbonat i/ili mineralna punila koja sadrže pločasti mineral i/ili mineralna punila koja sadrže kvarc i/ili mineralna punila koja sadrže glinu, te su poželjno mineralna punila koja sadrže kalcij karbonat.
4. Postupak prema zahtjevu 3, naznačen time da su mineralna punila koja sadrže kalcij karbonat, istaloženi kalcij karbonat (PCC), odnosno jedan ili više od aragonitnih, vateritnih i kalcitnih mineraloških kristalnih oblika, i/ili prirodni kalcij karbonat (NGCC), odnosno jedan ili više od mramora, vapnenca ili krede i/ili dolomita.
5. Postupak prema zahtjevu 4, naznačen time da mineralna punila koja sadrže kalcij karbonat su mramor i/ili dolomit.
6. Postupak prema zahtjevu 3, naznačen time da pločasto mineralno punilo je talk.
7. Postupak prema bilo kojem od zahtjeva 1 do 6, naznačen time da su dvovalentna i/ili trovalentna sol kationa jedne ili više C8 do C24 alifatskih karboksilnih kiselina odabrane između kalcijevih, magnezijevih, stroncijevih i aluminijevih soli, te njihovih mješavina, te su poželjno odabrane između kalcijevih soli, magnezijevih soli i njihovih mješavina.
8. Postupak prema bilo kojem od zahtjeva 1 do 7, naznačen time da dvovalentna i/ili trovalentna sol kationa jedne ili više C8 do C24 alifatske karboksilne kiseline odnosno alifatskih karboksilnih kiselina su dvovalentna i/ili trovalentna sol kationa jedne ili više C10 do C18 alifatskih karboksilnih kiselina, a poželjno su dvovalentna i/ili trovalentna sol kationa jedne ili više C12 do C18 alifatske karboksilne kiseline odnosno alifatskih karboksilnih kiselina.
9. Postupak prema bilo kojem od zahtjeva 1 do 8, naznačen time da dvovalentna i/ili trovalentna sol kationa jedne ili više C8 do C24 alifatske karboksilne kiseline odnosno alifatskih karboksilnih kiselina su soli dvovalentne i/ili trovalentne soli kationa jedne ili više alifatskih monokarboksilne kiseline (monokarboksilnih kiselina).
10. Postupak prema bilo kojem od zahtjeva 1 do 9, naznačen time da dvovalentna i/ili trovalentna sol kationa jedne ili više C8 do C24 alifatske karboksilne kiseline odnosno alifatskih karboksilnih kiselina su soli jedne ili više masne(ih) kiseline(a), posebice stearinska i/ili palmitinska i/ili miristinska i/ili laurinska kiselina, te su najpoželjnije soli stearinske i/ili palmitinske kiseline.
11. Postupak prema bilo kojem od zahtjeva 1 do 10, naznačen time da dvovalentna i/ili trovalentna sol kationa C8 do C24 alifatske karboksilne kiseline ima ekvivalentnu izoliranu viskoznost od više od 100000 mPa s, te poželjno od više od 1000000 mPa s, kod 180°C kada je mjereno sa PHYSICA MCR 300 opremljenim sa CP50-1 instrumentima uz smičnu brzinu od 5 s-1 i temperature skeniranja od 200 do 130 °C.
12. Postupak prema bilo kojem od zahtjeva 1 do 11, naznačen time da C8 do C24 alifatska karboksilna kiselina (alifatske karboksilne kiseline) je C10 do C18, te poželjno C12 do C18 alifatska karboksilna kiselina (alifatske karboksilne kiseline).
13. Postupak prema bilo kojem od zahtjeva 1 do 12, naznačen time da C8 do C24 alifatska karboksilna kiselina odnosno alifatske karboksilne kiseline su masne kiseline, posebice stearinska i/ili palmitinska i/ili miristinska i/ili laurinska kiselina ili njihove mješavine, te su najpoželjnije stearinska i/ili palmitinska kiselina.
14. Postupak prema bilo kojem od zahtjeva 1 do 13, naznačen time da je ukupna količina alifatske karboksilne kiseline (alifatskih karboksilnih kiselina) i soli alifatske karboksilne kiseline veća od 2.7, još poželjnije barem 3, odnosno barem 3.2, npr. 3.5 mg ukupne količine alifatske karboksilne kiseline (alifatskih karboksilnih kiselina) i soli alifatske karboksilne kiseline/m mineralnog odnosno mineralnih punila.
15. Postupak prema bilo kojem od zahtjeva 1 do 14, naznačen time da ekvivalentna izolirana mješavina soli alifatske karboksilne kiseline (alifatskih karboksilnih kiselina) i alifatske karboksilne kiseline (alifatskih karboksilnih kiselina) ima viskozitet od manje od 10000, poželjno manje od 1000, te još poželjnije manje od 500 mPa s pri 180°C.
16. Postupak prema bilo kojem od zahtjeva 1 do 15, naznačen time da je alifatska karboksilna kiselina mješavina u omjeru 1:1 stearinske kiseline i palmitinske kiseline, a soli alifatske karboksilne kiseline su magnezij ili kalcij stearat.
17. Postupak prema bilo kojem od zahtjeva 1 do 16, naznačen time da se alifatska karboksilna kiselina (alifatske karboksilne kiseline) pripremljena u koraku (b) nalazi u rastaljenom stanju.
18. Postupak prema bilo kojem od zahtjeva 1 do 17, naznačen time da su soli alifatske karboksilne kiseline (alifatskih karboksilnih kiselina) pripremljene u koraku (c) u rastaljenom stanju.
19. Postupak prema bilo kojem od zahtjeva 1 do 18, naznačen time da u koraku (d), sva ili dio navedene soli alifatske karboksilne kiseline (alifatskih karboksilnih kiselina) iz koraka (c) i sva ili dio navedene alifatske karboksilne kiseline (alifatskih karboksilnih kiselina) iz koraka (b), te poželjno sva navedena sol alifatske karboksilne kiseline (alifatskih karboksilnih kiselina) iz koraka (c) i sva navedena alifatska karboksilna kiselina (alifatske karboksilne kiseline) iz koraka (b), su prvo pomiješane jedna sa drugom, te su miješane da formiraju rastaljenu mješavinu prije dodavanja bilo kojeg od navedenih mineralnih punila.
20. Uporaba produkta dobivenog pomoću postupka prema bilo kojem od zahtjeva 1 do 19 naznačena time da je za postupak miješanja i/ili ekstruzije i/ili kombiniranja i/ili injekcijskog prešanja plastičnih materijala.
21. Uporaba prema zahtjevu 20, naznačena time da plastični materijali sadrže poliolefine ili termoplastične materijale kao što su polietileni (PE), polipropileni (PP) i/ili poliuretani (PU).
22. Filmovi naznačeni time da sadrže proizvode dobivene pomoću postupka prema bilo kojem od zahtjeva 1 do 19.
23. Filmovi prema zahtjevu 22, naznačeni time da su odabrani iz skupine koja sadrži razvučene i/ili orijentirane filmove, te poželjno prozračne filmove, ili filmove ekstruzijskih prevlaka.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08163012A EP2159258B1 (en) | 2008-08-26 | 2008-08-26 | Treated mineral filler products, process for the preparation thereof and uses of same |
Publications (1)
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HRP20110774T1 true HRP20110774T1 (hr) | 2011-12-31 |
Family
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HR20110774T HRP20110774T1 (hr) | 2008-08-26 | 2011-10-24 | Obrađena mineralna punila, postupak za njihovu pripremu i njihova uporaba |
Country Status (16)
Country | Link |
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US (3) | US20110237726A1 (hr) |
EP (1) | EP2159258B1 (hr) |
KR (2) | KR20150099876A (hr) |
CN (1) | CN102131853B (hr) |
AR (1) | AR076631A1 (hr) |
AT (1) | ATE517942T1 (hr) |
CA (1) | CA2734817C (hr) |
DK (1) | DK2159258T3 (hr) |
ES (1) | ES2370453T3 (hr) |
HR (1) | HRP20110774T1 (hr) |
MX (1) | MX2011001731A (hr) |
PL (1) | PL2159258T3 (hr) |
PT (1) | PT2159258E (hr) |
SI (1) | SI2159258T1 (hr) |
TW (1) | TWI429699B (hr) |
WO (1) | WO2010023144A1 (hr) |
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SI2770017T1 (sl) * | 2013-02-22 | 2015-11-30 | Omya International Ag | Nova površinska obdelava belih mineralnih snovi za uporabo pri plastiki |
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CN104086873B (zh) * | 2014-07-01 | 2016-03-23 | 安徽江威精密制造有限公司 | 一种耐热耐老化电容器薄膜专用填料及其制备方法 |
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PT3156369T (pt) | 2015-10-16 | 2018-10-31 | Omya Int Ag | Ccp com alto teor de sólidos com aditivo copolimérico |
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-
2008
- 2008-08-26 EP EP08163012A patent/EP2159258B1/en active Active
- 2008-08-26 PL PL08163012T patent/PL2159258T3/pl unknown
- 2008-08-26 ES ES08163012T patent/ES2370453T3/es active Active
- 2008-08-26 PT PT08163012T patent/PT2159258E/pt unknown
- 2008-08-26 DK DK08163012.1T patent/DK2159258T3/da active
- 2008-08-26 AT AT08163012T patent/ATE517942T1/de active
- 2008-08-26 SI SI200830408T patent/SI2159258T1/sl unknown
-
2009
- 2009-08-19 MX MX2011001731A patent/MX2011001731A/es active IP Right Grant
- 2009-08-19 CA CA2734817A patent/CA2734817C/en not_active Expired - Fee Related
- 2009-08-19 US US12/737,743 patent/US20110237726A1/en not_active Abandoned
- 2009-08-19 KR KR1020157022063A patent/KR20150099876A/ko not_active Application Discontinuation
- 2009-08-19 WO PCT/EP2009/060741 patent/WO2010023144A1/en active Application Filing
- 2009-08-19 CN CN200980133081XA patent/CN102131853B/zh not_active Expired - Fee Related
- 2009-08-19 KR KR1020117005589A patent/KR20110068999A/ko active Application Filing
- 2009-08-25 AR ARP090103261A patent/AR076631A1/es not_active Application Discontinuation
- 2009-08-26 TW TW098128630A patent/TWI429699B/zh not_active IP Right Cessation
-
2011
- 2011-10-24 HR HR20110774T patent/HRP20110774T1/hr unknown
-
2013
- 2013-06-07 US US13/912,392 patent/US20140021656A1/en not_active Abandoned
- 2013-06-07 US US13/912,451 patent/US20130338283A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
TWI429699B (zh) | 2014-03-11 |
TW201012859A (en) | 2010-04-01 |
CN102131853B (zh) | 2013-06-05 |
PL2159258T3 (pl) | 2012-01-31 |
CA2734817C (en) | 2015-08-11 |
KR20110068999A (ko) | 2011-06-22 |
US20110237726A1 (en) | 2011-09-29 |
PT2159258E (pt) | 2011-11-09 |
AR076631A1 (es) | 2011-06-29 |
ES2370453T3 (es) | 2011-12-16 |
EP2159258B1 (en) | 2011-07-27 |
CA2734817A1 (en) | 2010-03-04 |
MX2011001731A (es) | 2011-03-24 |
EP2159258A1 (en) | 2010-03-03 |
KR20150099876A (ko) | 2015-09-01 |
US20130338283A1 (en) | 2013-12-19 |
SI2159258T1 (sl) | 2011-12-30 |
WO2010023144A1 (en) | 2010-03-04 |
DK2159258T3 (da) | 2011-11-21 |
US20140021656A1 (en) | 2014-01-23 |
ATE517942T1 (de) | 2011-08-15 |
CN102131853A (zh) | 2011-07-20 |
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