GB979270A - Titanium pigments - Google Patents
Titanium pigmentsInfo
- Publication number
- GB979270A GB979270A GB665862A GB665862A GB979270A GB 979270 A GB979270 A GB 979270A GB 665862 A GB665862 A GB 665862A GB 665862 A GB665862 A GB 665862A GB 979270 A GB979270 A GB 979270A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphoric acid
- titanium
- heated
- precipitate
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000001038 titanium pigment Substances 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 13
- 235000011007 phosphoric acid Nutrition 0.000 abstract 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 4
- 239000002244 precipitate Substances 0.000 abstract 4
- 150000003839 salts Chemical class 0.000 abstract 4
- 229910052719 titanium Inorganic materials 0.000 abstract 4
- 239000010936 titanium Substances 0.000 abstract 4
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 abstract 4
- 239000007864 aqueous solution Substances 0.000 abstract 3
- 238000010438 heat treatment Methods 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 abstract 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 abstract 1
- -1 NH4H2PO4 Chemical compound 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910001310 TiP2O7 Inorganic materials 0.000 abstract 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 abstract 1
- 235000011180 diphosphates Nutrition 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910000160 potassium phosphate Inorganic materials 0.000 abstract 1
- 235000011009 potassium phosphates Nutrition 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/60—Compounds characterised by their crystallite size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/84—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by UV- or VIS- data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
- Glass Compositions (AREA)
Abstract
Titanium phosphate, believed to be the pyrophosphate TiP2O7, is prepared by simultaneously introducing a titanium tetrahalide and phosphoric acid or soluble salt of phosphoric acid, e.g. NH4H2PO4, into an aqueous liquid; recovering the titanium phosphate precipitate thus formed and then heating the precipitate. The titanium tetrahalide is preferably the tetrachloride, the pH of the aqueous liquid is preferably below 7, the precipitation being performed in the presence of excess phosphoric acid or soluble salt thereof, e.g. 1-50 gm./litre estimated as H3PO4. The titanium tetrahalide, the phosphoric acid, and the salt of phosphoric acid may be introduced as aqueous solutions, and are preferably introduced into the aqueous liquid at a rate such that no local excess of titanium tetrahalide occurs in the solution. The aqueous solution may be heated preferably to its b.pt. during the addition of the reactants or the reactants may be added and the solution subsequently heated. The halide solution used has a concentration of preferably 25-220 gms./litre (estimated as TiO2) and the precipitate produced may before separation be mixed with phosphoric acid or an aqueous solution of a salt thereof and boiled. The ppt. is then separated, dried and ground and heated at a temperature in the range 750 DEG to 1100 DEG C. and subsequently milled to produce a mean crystal size of 0.1 to 2 microns. After recovery but before heating, a compound which reduces the temperature to which the titanium phosphate must be heated to form a pigment may be added to the titanium phosphate precipitate. The preferred compound is potassium phosphate and it is added in an amount sufficient to give a concentration before heating (estimated as potassium) of at least 0.05% by weight, preferably 0.1% to 2% by weight.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB665862A GB979270A (en) | 1962-02-21 | 1962-02-21 | Titanium pigments |
DE19631223349 DE1223349C2 (en) | 1962-02-21 | 1963-02-13 | PROCESS FOR THE PRODUCTION OF A TITANIUM PYROPHOSHATE SUITABLE AS A PIGMENT |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB665862A GB979270A (en) | 1962-02-21 | 1962-02-21 | Titanium pigments |
Publications (1)
Publication Number | Publication Date |
---|---|
GB979270A true GB979270A (en) | 1965-01-01 |
Family
ID=9818442
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB665862A Expired GB979270A (en) | 1962-02-21 | 1962-02-21 | Titanium pigments |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1223349C2 (en) |
GB (1) | GB979270A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4889199A (en) * | 1972-03-01 | 1973-11-21 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2159342C2 (en) * | 1971-11-30 | 1984-12-20 | Mizusawa Kagaku Kogyo K.K., Osaka | New white pigment |
-
1962
- 1962-02-21 GB GB665862A patent/GB979270A/en not_active Expired
-
1963
- 1963-02-13 DE DE19631223349 patent/DE1223349C2/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4889199A (en) * | 1972-03-01 | 1973-11-21 | ||
JPS516000B2 (en) * | 1972-03-01 | 1976-02-24 |
Also Published As
Publication number | Publication date |
---|---|
DE1223349B (en) | 1974-02-07 |
DE1223349C2 (en) | 1974-02-07 |
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