GB963294A - Process for the production of polyhydric diaryl-alkanes,-cycloalkanes and -aralkanes - Google Patents

Process for the production of polyhydric diaryl-alkanes,-cycloalkanes and -aralkanes

Info

Publication number
GB963294A
GB963294A GB41132/61A GB4113261A GB963294A GB 963294 A GB963294 A GB 963294A GB 41132/61 A GB41132/61 A GB 41132/61A GB 4113261 A GB4113261 A GB 4113261A GB 963294 A GB963294 A GB 963294A
Authority
GB
United Kingdom
Prior art keywords
phenol
methyl
phenols
weight
aralkanes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB41132/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB963294A publication Critical patent/GB963294A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
    • C07C39/17—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings containing other rings in addition to the six-membered aromatic rings, e.g. cyclohexylphenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
    • C07C39/14—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with at least one hydroxy group on a condensed ring system containing two rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
    • C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
    • C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
    • C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/24—Halogenated derivatives
    • C07C39/367—Halogenated derivatives polycyclic non-condensed, containing only six-membered aromatic rings as cyclic parts, e.g. halogenated poly-hydroxyphenylalkanes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Polyhydrioxy-diaryl-alkanes, -cycloalkanes and aralkanes are prepared by adding a mono- or polyhydric phenol to an alkenyl phenol of the formula: <FORM:0963294/C1/1> wherein R1, R2 and R3, which are the same or different, are hydrogen atoms or alkyl, cycloalkyl or aryl hydrocarbon radicals or R1 and R2 can be joined to form a 6-membered cycloaliphatic ring, in the presence of 0.001 to 20% by weight of an anhydrous acidic catalyst or of 0.01 to 20% by weight of an alkaline catalyst, said percentages being based on the total weight of the phenolic reaction components. The reaction is preferably carried out under anhydrous conditions, at between 0 DEG and 40 DEG C. in the case of acidic catalysts, and at from 50 DEG to 200 DEG C. in the case of alkaline catalysts. Inert solvents such as aromatic hydrocarbons, chlorinated hydrocarbons, ethers or alcohols may be used if desired. Phenols and alkenyl phenols used in the examples are: phenol, o-, m- and p-cresols, o-chlorophenol, o-cyclohexylphenol, 2, 6-diethylphenol, resorcinol, 2, 6-dichlorophenol and a -naphthol; and p-isopropenylphenol, p-(1-phenyl vinyl)-phenol and p-(1-methyl -2- methylvinyl)-phenol. Other starting materials mentioned include octyl- and decyl-phenols, bromophenols, guaiacol and pyrogallol; 2-methyl -4- (1-methyl-vinyl)-phenol and p-(1, 2-cyclohexenyl)-phenol. Specification 905,994 is referred to.
GB41132/61A 1960-12-27 1961-11-16 Process for the production of polyhydric diaryl-alkanes,-cycloalkanes and -aralkanes Expired GB963294A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF32855A DE1150093B (en) 1960-12-27 1960-12-27 Process for the preparation of di- or polyhydroxydiarylalkanes

Publications (1)

Publication Number Publication Date
GB963294A true GB963294A (en) 1964-07-08

Family

ID=7094826

Family Applications (1)

Application Number Title Priority Date Filing Date
GB41132/61A Expired GB963294A (en) 1960-12-27 1961-11-16 Process for the production of polyhydric diaryl-alkanes,-cycloalkanes and -aralkanes

Country Status (4)

Country Link
BE (1) BE611184A (en)
CH (1) CH420193A (en)
DE (1) DE1150093B (en)
GB (1) GB963294A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4239918A (en) * 1978-12-06 1980-12-16 General Electric Company Meta, para-substituted isopropylidene bisphenols and methods for making

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3288864A (en) * 1962-05-11 1966-11-29 Union Carbide Corp Reaction products of isopropenyl phenols and of linear dimers thereof
DE1197469B (en) * 1962-09-19 1965-07-29 Bayer Ag Process for the production of polynuclear polyphenols
DE1495793C3 (en) * 1964-04-17 1974-04-11 Bayer Ag Process for the production of epoxy polyadducts

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2714120A (en) * 1950-05-23 1955-07-26 Goodrich Co B F Method of preparing aralkylated phenolic compounds
US2882322A (en) * 1957-01-23 1959-04-14 Allied Chem Production of cumylphenol from alpha-methylstyrene dimer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4239918A (en) * 1978-12-06 1980-12-16 General Electric Company Meta, para-substituted isopropylidene bisphenols and methods for making

Also Published As

Publication number Publication date
DE1150093B (en) 1963-06-12
BE611184A (en) 1962-03-30
CH420193A (en) 1966-09-15

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