GB957149A - Piperidyl-(4)-ethers - Google Patents
Piperidyl-(4)-ethersInfo
- Publication number
- GB957149A GB957149A GB85/63A GB8563A GB957149A GB 957149 A GB957149 A GB 957149A GB 85/63 A GB85/63 A GB 85/63A GB 8563 A GB8563 A GB 8563A GB 957149 A GB957149 A GB 957149A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethers
- ether
- ruthenium
- oxide
- pyridyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D455/00—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine
- C07D455/02—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing not further condensed quinolizine ring systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Hydrogenated Pyridines (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
The invention comprises piperidyl-4-ethers of the general formula: <FORM:0957149/C2/1> in which R is an alkyl radical containing at least 2 carbon atoms. These compounds and the methyl ether are prepared by hydrogenating the corresponding pyridyl-4-ethers in the presence of a ruthenium catalyst, at an increased pressure and elevated temperature. Alternatively, the pyridyl-4-ether may be used as its N-oxide. The catalyst may be ruthenium metal, an oxide or a salt of ruthenium, or a ruthenate. The hydrogenation may be performed in the presence of small amounts of water and/or an alcohol, preferably corresponding to the alkoxy group in the ether. Compounds prepared include those in which R is methyl, ethyl, n-propyl and isopropyl.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB65401A DE1234726B (en) | 1962-01-03 | 1962-01-03 | Process for the preparation of piperidyl (4) ethers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB957149A true GB957149A (en) | 1964-05-06 |
Family
ID=6974760
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB85/63A Expired GB957149A (en) | 1962-01-03 | 1963-01-01 | Piperidyl-(4)-ethers |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3287460A (en) |
| CH (1) | CH407122A (en) |
| DE (1) | DE1234726B (en) |
| GB (1) | GB957149A (en) |
| NL (1) | NL287395A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3408354A (en) * | 1965-10-04 | 1968-10-29 | Engelhard Ind Inc | Catalytic hydrogenation of 3-and 4-hydroxy pyridines |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2831862A (en) * | 1956-02-27 | 1958-04-22 | Lakeside Lab Inc | Ethers of n-alkyl-3-hydroxypiperidine and salts thereof |
| US2915505A (en) * | 1957-05-22 | 1959-12-01 | Du Pont | Condensation polymers of 4-hydroxy-piperidine |
| US2932646A (en) * | 1957-08-30 | 1960-04-12 | Lakeside Lab Inc | Nu-amino-nitrogen containing heterocyclic compounds |
-
0
- NL NL287395D patent/NL287395A/xx unknown
-
1962
- 1962-01-03 DE DEB65401A patent/DE1234726B/en active Pending
- 1962-12-28 US US247842A patent/US3287460A/en not_active Expired - Lifetime
- 1962-12-29 CH CH1528562A patent/CH407122A/en unknown
-
1963
- 1963-01-01 GB GB85/63A patent/GB957149A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US3287460A (en) | 1966-11-22 |
| DE1234726B (en) | 1967-02-23 |
| NL287395A (en) | |
| CH407122A (en) | 1966-02-15 |
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