GB1120427A - Process for the preparation of 1,6-hexanediols - Google Patents
Process for the preparation of 1,6-hexanediolsInfo
- Publication number
- GB1120427A GB1120427A GB3336765A GB3336765A GB1120427A GB 1120427 A GB1120427 A GB 1120427A GB 3336765 A GB3336765 A GB 3336765A GB 3336765 A GB3336765 A GB 3336765A GB 1120427 A GB1120427 A GB 1120427A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogenolysis
- hexanediols
- preparation
- hexanediol
- atm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/26—Hexahydroxylic alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,6-Hexanediols are prepared by hydrogenolysis in the liquid phase of polyesters containing up to 40 recurrent groups of general formula <FORM:1120427/C2/1> where R represents a hydrogen atom, a C1- 6 alkyl radical or a cycloalkyl radical, in the presence of an ester hydrogenolysis catalyst, particularly copper chromite, under conditions known for hydrogenolysis, particularly under a pressure of at least 150 atm. and at a temperature between 200 DEG and 300 DEG C. Examples describe the production of 1,6-hexanediol.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR984984A FR1411860A (en) | 1964-08-12 | 1964-08-12 | Process for preparing hexanediols-1-6 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1120427A true GB1120427A (en) | 1968-07-17 |
Family
ID=8836567
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3336765A Expired GB1120427A (en) | 1964-08-12 | 1965-08-04 | Process for the preparation of 1,6-hexanediols |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE668036A (en) |
DE (1) | DE1255650B (en) |
FR (1) | FR1411860A (en) |
GB (1) | GB1120427A (en) |
NL (1) | NL6510371A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6844447B2 (en) | 2001-12-18 | 2005-01-18 | Metabolix Inc. | Methods of making intermediates from polyhydroxyalkanoates |
CN102388008A (en) * | 2009-04-08 | 2012-03-21 | 巴斯夫欧洲公司 | Method for producing 1,6-hexanediol by hydrogenation of oligo- and polyesters |
US10786064B2 (en) | 2010-02-11 | 2020-09-29 | Cj Cheiljedang Corporation | Process for producing a monomer component from a genetically modified polyhydroxyalkanoate biomass |
-
1964
- 1964-08-12 FR FR984984A patent/FR1411860A/en not_active Expired
-
1965
- 1965-08-02 DE DES98588A patent/DE1255650B/en active Pending
- 1965-08-04 GB GB3336765A patent/GB1120427A/en not_active Expired
- 1965-08-09 BE BE668036D patent/BE668036A/xx unknown
- 1965-08-10 NL NL6510371A patent/NL6510371A/xx unknown
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6844447B2 (en) | 2001-12-18 | 2005-01-18 | Metabolix Inc. | Methods of making intermediates from polyhydroxyalkanoates |
US6897338B2 (en) | 2001-12-18 | 2005-05-24 | Metabolix, Inc. | Methods of making intermediates from polyhydroxyalkanoates |
US6933404B2 (en) | 2001-12-18 | 2005-08-23 | Metabolix Inc. | Methods of making intermediates from polyhydroxyalkanoates |
US7001969B2 (en) | 2001-12-18 | 2006-02-21 | Metabolix Inc. | Methods of making intermediates from polyhydroxyalkanoates |
US7166743B2 (en) | 2001-12-18 | 2007-01-23 | Metabolix, Inc. | Methods of making intermediates from polyhydroxyalkanoates |
US7230144B2 (en) * | 2001-12-18 | 2007-06-12 | Metabolix Inc. | Methods of making intermediates from polyhydroxyalkanoates |
CN102388008A (en) * | 2009-04-08 | 2012-03-21 | 巴斯夫欧洲公司 | Method for producing 1,6-hexanediol by hydrogenation of oligo- and polyesters |
CN102388008B (en) * | 2009-04-08 | 2014-09-24 | 巴斯夫欧洲公司 | Method for producing 1,6-hexanediol by hydrogenation of oligo- and polyesters |
US10786064B2 (en) | 2010-02-11 | 2020-09-29 | Cj Cheiljedang Corporation | Process for producing a monomer component from a genetically modified polyhydroxyalkanoate biomass |
Also Published As
Publication number | Publication date |
---|---|
FR1411860A (en) | 1965-09-24 |
BE668036A (en) | 1965-12-01 |
NL6510371A (en) | 1966-02-14 |
DE1255650B (en) | 1967-12-07 |
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