GB918950A - Improvements in or relating to the hardening of a colloid composition, specificaliy a gelatin-containing composition - Google Patents
Improvements in or relating to the hardening of a colloid composition, specificaliy a gelatin-containing compositionInfo
- Publication number
- GB918950A GB918950A GB417060A GB417060A GB918950A GB 918950 A GB918950 A GB 918950A GB 417060 A GB417060 A GB 417060A GB 417060 A GB417060 A GB 417060A GB 918950 A GB918950 A GB 918950A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diethylenimino
- phosphate
- layer
- composition
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 9
- 239000000084 colloidal system Substances 0.000 title abstract 5
- 108010010803 Gelatin Proteins 0.000 title abstract 3
- 229920000159 gelatin Polymers 0.000 title abstract 3
- 239000008273 gelatin Substances 0.000 title abstract 3
- 235000019322 gelatine Nutrition 0.000 title abstract 3
- 235000011852 gelatine desserts Nutrition 0.000 title abstract 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 4
- 229910052698 phosphorus Inorganic materials 0.000 abstract 4
- 239000011574 phosphorus Substances 0.000 abstract 4
- 229910052709 silver Inorganic materials 0.000 abstract 4
- 239000004332 silver Substances 0.000 abstract 4
- -1 silver halide Chemical class 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 3
- 239000000839 emulsion Substances 0.000 abstract 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 2
- AZGKRBITGGDMLR-UHFFFAOYSA-N bis(aziridin-1-yl) butylamino phosphate Chemical compound P(=O)(ONCCCC)(ON1CC1)ON1CC1 AZGKRBITGGDMLR-UHFFFAOYSA-N 0.000 abstract 2
- NPJBMJIBFFEURW-UHFFFAOYSA-N bis(aziridin-1-yl) ethyl phosphate Chemical compound P(=O)(OCC)(ON1CC1)ON1CC1 NPJBMJIBFFEURW-UHFFFAOYSA-N 0.000 abstract 2
- SPQUQHIEGIWXHV-UHFFFAOYSA-N bis(aziridin-1-yl) ethyl phosphite Chemical compound P(OCC)(ON1CC1)ON1CC1 SPQUQHIEGIWXHV-UHFFFAOYSA-N 0.000 abstract 2
- 238000009792 diffusion process Methods 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 abstract 2
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- MBHOBPBLMOUSKA-UHFFFAOYSA-N tris(aziridin-1-yl) phosphate Chemical compound C1CN1OP(ON1CC1)(=O)ON1CC1 MBHOBPBLMOUSKA-UHFFFAOYSA-N 0.000 abstract 2
- YZBOZNXACBQJHI-UHFFFAOYSA-N 1-dichlorophosphoryloxyethane Chemical compound CCOP(Cl)(Cl)=O YZBOZNXACBQJHI-UHFFFAOYSA-N 0.000 abstract 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 abstract 1
- ZJQXMHGRCWYEDA-UHFFFAOYSA-N N-dichlorophosphoryloxybutan-1-amine Chemical compound P(=O)(ONCCCC)(Cl)Cl ZJQXMHGRCWYEDA-UHFFFAOYSA-N 0.000 abstract 1
- HICIBSHTEGYCOD-UHFFFAOYSA-N bis(aziridin-1-yl) diethylamino phosphate Chemical compound P(=O)(ON(CC)CC)(ON1CC1)ON1CC1 HICIBSHTEGYCOD-UHFFFAOYSA-N 0.000 abstract 1
- MKZQOWUROVLKJT-UHFFFAOYSA-N bis(aziridin-1-yl) diethylamino phosphite Chemical compound P(ON(CC)CC)(ON1CC1)ON1CC1 MKZQOWUROVLKJT-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- PVCINRPAXRJLEP-UHFFFAOYSA-N dichloro(ethoxy)phosphane Chemical compound CCOP(Cl)Cl PVCINRPAXRJLEP-UHFFFAOYSA-N 0.000 abstract 1
- QOKOOWDYGVOQKA-UHFFFAOYSA-N n-dichlorophosphanyloxy-n-ethylethanamine Chemical compound CCN(CC)OP(Cl)Cl QOKOOWDYGVOQKA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/564—Three-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
A colloid composition, such as a polyvinyl alcohol-containing composition, is hardened by adding to the composition, a phosphorus-containing compound of general formulae: <FORM:0918950/IV(a)/1> and <FORM:0918950/IV(a)/2> wherein R1, R2, R3, R4, R5, R6, R7 and R8 each represents a hydrogen atom or an alkyl group either substituted or not, any two or more of which may be the same or which may all be different, X represents a halogen atom, -OR9, <FORM:0918950/IV(a)/3> or <FORM:0918950/IV(a)/4> wherein R9, R10, R11, R12, R13 R14, and R15 each represents a hydrogen atom, an alkyl group either substituted or not, any two of which may be same or which may all be different, and may be the same as or different from one or more of the substituents R1, R2, R3, R4, R5, R6, R7 and R8. Phosphorus-containing compounds specified are triethylenimino phosphate, butylamino diethylenimino phosphate, diethylamino diethylenimino phosphite, ethyl diethylenimino phosphate and ethyl diethylenimino phosphite. The colloid may be a light sensitive silver halide emulsion and may, as a layer, form part of a photographic element for making positive images according to the silver halide diffusion transfer process, or a back-layer of a photographic light-sensitive material. Specifications 797,321, 869,632, and 891,221 are referred to.ALSO:A colloid or a gelatin-containing composition which is applied as a layer in a photographic element, is hardened by adding to the composition, before coating as a layer, a phosphorus-containing compound of general formulae: <FORM:0918950/IV (b)/1> <FORM:0918950/IV (b)/2> wherein R1, R2, R3, R4, R5, R6, R7 and R8 each represents a hydrogen atom or an alkyl group either substituted or not, any two or more of which may be the same or which may all be different, X represents a halogen atom, -OR9, <FORM:0918950/IV (b)/3> <FORM:0918950/IV (b)/4> wherein R9, R10, R11, R12, R13, R14 and R15 each represents a hydrogen atom, an alkyl group either substituted or not, any two of which may be the same or which may all be different, and may be the same or different from one or more of the substituents R1, R2, R3, R4 R5, R6, R7 and R8. The colloid which may be a polyvinyl alcohol-containing layer, or gelatin-containing composition, may be a light sensitive silver halide emulsion, and may form part of a photographic element for making positive images according to the silver halide diffusion transfer process, an emulsion layer or back layer of photographic light sensitive materials. Phosphorus containing compounds specified are (i) triethylenimino phosphate, (ii) butylamino diethylenimino phosphate, (iii) diethylamino diethylenimino phosphate, (iv) ethyl diethylenimino phosphate and (v) ethyl diethylenimino phosphite, prepared by the reaction of (i) phosphorus oxychloride, (ii) n-butylamino dichlorophosphate, (iii) diethylamino dichlorophosphite, (iv) ethyl dichlorophosphate, (v) ethyl dichlorophosphite, respectively, with a mixture of ethylenimine, triethylamine and hydroquinone in anhydrous benzene. Specifications 797,321, 869,632 and 891,221 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE2038655 | 1959-02-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB918950A true GB918950A (en) | 1963-02-20 |
Family
ID=3864701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB417060A Expired GB918950A (en) | 1959-02-06 | 1960-02-05 | Improvements in or relating to the hardening of a colloid composition, specificaliy a gelatin-containing composition |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB918950A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1285301B (en) * | 1964-04-17 | 1968-12-12 | Fuji Photo Film Co Ltd | Use of anti-fog agents for photographic gelatin-containing silver halide emulsion layers |
-
1960
- 1960-02-05 GB GB417060A patent/GB918950A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1285301B (en) * | 1964-04-17 | 1968-12-12 | Fuji Photo Film Co Ltd | Use of anti-fog agents for photographic gelatin-containing silver halide emulsion layers |
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