GB914506A - Treatment of polyamide filaments - Google Patents

Treatment of polyamide filaments

Info

Publication number
GB914506A
GB914506A GB17843/61A GB1784361A GB914506A GB 914506 A GB914506 A GB 914506A GB 17843/61 A GB17843/61 A GB 17843/61A GB 1784361 A GB1784361 A GB 1784361A GB 914506 A GB914506 A GB 914506A
Authority
GB
United Kingdom
Prior art keywords
weight
emulsion
triglyceride
emulsifying agent
ethanols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17843/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Chemicals Ltd
Monsanto Chemical Co
Original Assignee
Monsanto Chemicals Ltd
Monsanto Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US34863A external-priority patent/US3160511A/en
Application filed by Monsanto Chemicals Ltd, Monsanto Chemical Co filed Critical Monsanto Chemicals Ltd
Publication of GB914506A publication Critical patent/GB914506A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D30/00Producing pneumatic or solid tyres or parts thereof
    • B29D30/06Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
    • B29D30/38Textile inserts, e.g. cord or canvas layers, for tyres; Treatment of inserts prior to building the tyre
    • B29D30/40Chemical pretreatment of textile inserts before building the tyre
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C9/00Reinforcements or ply arrangement of pneumatic tyres
    • B60C9/0042Reinforcements made of synthetic materials
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017Mixtures of compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/14Derivatives of phosphoric acid
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • D02J1/221Preliminary treatments
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D06M13/295Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing polyglycol moieties; containing neopentyl moieties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00Characterised by the use of unspecified rubbers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40Reduced friction resistance, lubricant properties; Sizing compositions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2964Artificial fiber or filament
    • Y10T428/2967Synthetic resin or polymer
    • Y10T428/2969Polyamide, polyimide or polyester

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

An aqueous emulsion contains a triglyceride having the structural formula:- <FORM:0914506/III/1> wherein R designates aliphatic radicals, two of which have 1-5 carbon atoms and at most one double carbon to carbon bond each and one of which has 11-23 carbon atoms and at most 5 double carbon to carbon bonds. Specified triglycerides include diaceto-ricinolein, -linolein and -linolenin, which are preferred, especially the latter, in an amount of 0,5-3,0% by weight, and diaceto-laurin, -myristin, -palmitin, -stearin, -arachidin, -behenin, -liquocerin, -laurolein, -myristolein, -palmitolein, -olein, -gadolein, -erucin, -elastostearin, -licanin, -arachidonin, and -clupanodonin, and the corresponding dipropiono-, dibutyro-, divalero-, dicapro-, and dicrotonocompounds. The lower fatty acid substituents can be either in the a b or a g positions. Mixtures of these compounds may be incorporated in the emulsion, which may also contain non-ionic surface-active emulsifying agents, especially polyethers, e.g. alkylaryl polyoxyethylene ethanols, alkyl polyoxyethylene ethanols, alkylaryl polyoxypropylene ethanols and alkyl polyoxypropylene ethanols, especially the products made by reacting C10-C24 alcohols with 5-30 moles of ethylene oxide or other alkylene oxide, or by reacting alkyl substituted phenols with 8-30 moles of an alkylene oxide. A number of suitable mono- and poly-hydric alcohols and condensation products therewith is specified. The emulsion may contain 10-50% by weight of emulsifying agent, based on the weight of ester plus emulsifying agent, and 0,5-20% of the triglyceride, based on the weight of the emulsion. Such an emulsion may be made by mixing at 25 DEG -50 DEG C. the triglyceride, a non-ionic surface-active emulsifying agent, and water, the triglyceride being present in an amount of 0,5-20% by weight, based on the weight of the emulsion, and the percentage of emulsifying agent being 10-50, based on the weight of the triglyceride and emulsifying agent, and agitating the resulting mixture vigorously at 0 DEG -100 DEG C. until a stable emulsion is formed.ALSO:Nylon filaments are impregnated with an aqueous emulsion containing a triglyceride having the structural formula <FORM:0914506/IV(a)/1> wherein R designates aliphatic radicals, two of which have 1-5 carbon atoms and at most one double carbon to carbon bond each and one of which has 11-23 carbon atoms and at most 5 double carbon to carbon bonds, and then stretched to increase their molecular orientation, the filaments during stretching having a triglyceride content of 0,05-3,0% by weight. The filaments may be made from nylon-66 or nylon-6, and the stretching may be carried at above 140 DEG C. but below the sticking temperature of the filaments. Specified triglycerides include diacetoricinolein, -linolein and -linolenin, which are preferred, especially the latter, in an amount of 0,5-3,0% by weight, and diaceto-laurin, -myristin, -palmitin, -stearin, -arachidin, -behenin, -lignocerin, -laurolein, -myristolein, -palmitolein, -olein, -gadolein, -erucin, -elastostearin, -licanin, -arachidonin, and clupanodonin, and the corresponding dipropiono-, dibutyro-, divalero-, dicapro-, and dicrotonocompounds. The lower fatty acid substituents can be either in the a b -or a g -positions. Mixtures of these compounds may also be used. The emulsion may also contain non-ionic surface active emulsifying agents, especially polyethers, e.g. alkylaryl polyoxyethylene ethanols, alkyl polyoxyethylene ethanols, alkylarylpolyoxy propylene ethanols and alkyl polyoxypropylene ethanols, especially the products made by reacting C10-C24 alcohols with 5-30 moles of ethylene oxide or other alkylene oxide, or by reacting alkyl substituted phenols with 8-30 moles of an alkylene oxide. A number of suitable compounds are specified. The emulsion may contain 10-50% by weight of emulsifying agent, based on the weight of ester plus emulsifying agent, and 0,5-20% of the triglyceride, based on the weight of the emulsion. In an example, freshly-spun nylon filaments are treated with an emulsion containing 18 parts by weight diaceto-ricinolein, two parts by weight of an emulsifying agent made by condensing a mixture of myristyl, cetyl, stearyl, arachyl, palmitoleyl, oleyl, and linoleyl alcohols with 20 moles ethylene oxide per mole of alcohol, and 180 parts by weight of water, and then hot-stretched at about 180 DEG C. to about five times on a conventional drawtwist machine. Filaments so treated are especially useful as tyre cords.
GB17843/61A 1960-06-09 1961-05-16 Treatment of polyamide filaments Expired GB914506A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US34863A US3160511A (en) 1960-06-09 1960-06-09 Treatment of polyamide filaments
US171616A US3279943A (en) 1960-06-09 1962-02-07 Polyamide filamentary yarn

Publications (1)

Publication Number Publication Date
GB914506A true GB914506A (en) 1963-01-02

Family

ID=26711472

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17843/61A Expired GB914506A (en) 1960-06-09 1961-05-16 Treatment of polyamide filaments

Country Status (7)

Country Link
US (1) US3279943A (en)
BE (2) BE604833A (en)
CH (1) CH421375A (en)
DE (1) DE1204617B (en)
GB (1) GB914506A (en)
NL (3) NL265793A (en)
SE (1) SE308499B (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU46327A1 (en) * 1963-06-20 1972-01-01
US3525206A (en) * 1965-01-19 1970-08-25 Monsanto Co Nylon tire cord
NL6600642A (en) * 1965-02-09 1966-08-10
US3459251A (en) * 1965-03-31 1969-08-05 Firestone Tire & Rubber Co Rubber tires with nylon reinforcement cord containing dispersed therein the reaction product of boric acid and an aliphatic alcohol
US4343616A (en) * 1980-12-22 1982-08-10 Union Carbide Corporation Lubricant compositions for finishing synthetic fibers
JPS60231873A (en) * 1984-04-26 1985-11-18 帝人株式会社 Aromatic polyamide fiber
US5096778A (en) * 1986-09-26 1992-03-17 E. I. Du Pont De Nemours And Company Dip penetration regulators for tire yarns
US4900496A (en) * 1986-09-26 1990-02-13 E. I. Du Pont De Nemours And Company Process for making a tire cord using yarns containing a dip penetration regulator
JP2006335874A (en) * 2005-06-02 2006-12-14 Kao Corp Plasticizer for biodegradable resin

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19364C (en) * G. eiffel in Levaillois-Perret bei Paris Dismountable bridge girder
US2164235A (en) * 1936-01-21 1939-06-27 Garner Walter Treating textiles and oils therefor
US2944920A (en) * 1955-11-07 1960-07-12 Emery Industries Inc Process for lubricating and promoting the cohesion of textile fibers
US2808421A (en) * 1955-12-13 1957-10-01 Eastman Kodak Co Method for preparing mixed triglyceride compositions
US2932078A (en) * 1958-11-12 1960-04-12 Goodrich Co B F Process for treating cords
US3113369A (en) * 1960-05-02 1963-12-10 Monsanto Chemicals Yarn manufacture and products obtained thereby

Also Published As

Publication number Publication date
BE604833A (en)
BE588311A (en)
NL249022A (en)
NL123623C (en)
CH421375A (en) 1966-09-30
NL265793A (en)
SE308499B (en) 1969-02-17
DE1204617B (en) 1965-11-11
US3279943A (en) 1966-10-18

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