GB950844A - Alkylene oxide addition products - Google Patents

Alkylene oxide addition products

Info

Publication number
GB950844A
GB950844A GB26394/60A GB2639460A GB950844A GB 950844 A GB950844 A GB 950844A GB 26394/60 A GB26394/60 A GB 26394/60A GB 2639460 A GB2639460 A GB 2639460A GB 950844 A GB950844 A GB 950844A
Authority
GB
United Kingdom
Prior art keywords
ethylene oxide
mols
oxide
addition products
mol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26394/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boehme Fettchemie GmbH
Original Assignee
Boehme Fettchemie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boehme Fettchemie GmbH filed Critical Boehme Fettchemie GmbH
Publication of GB950844A publication Critical patent/GB950844A/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/16Amides, e.g. hydroxamic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01Preparation of ethers
    • C07C41/02Preparation of ethers from oxiranes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/42Ethers, e.g. polyglycol ethers of alcohols or phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Detergent Compositions (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Cosmetics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Liquid water-soluble alkylene oxide addition products are prepared by condensing propylene oxide with addition products of ethylene oxide and aliphatic or alicyclic compounds containing at least 8 carbon atoms containing replaceable hydrogen atoms linked via oxygen, sulphur, or nitrogen; the addition products containing 5-20 mols of ethylene oxide per mol of aliphatic compound and the ratio of propylene oxide to ethylene oxide being 0.4 to 2. Compounds specified include alcohols, amines, mercaptans, carboxylic acids, sulphonic acids and acid amides. Normally 0.5-1.5 mols of ethylene oxide are added per carbon atom present in the replaceable hydrogen containing compound. In Example 1, 1 mol of a C12-C14 fatty alcohol mixture is condensed with 9 mols of ethylene oxide at 120-148 DEG C. with sodium methylate present. 1 mol of this addition product is condensed with 10 mols of propylene oxide in the presence of sodium methylate at 125-144 DEG C. In Examples 2-7, under similar conditions, the following compounds are used: a mixture of lauryl and myristyl alcohols, coconut fatty acid monoethanolamide, coconut fatty acid diethanolamide, coconut oil amines, lauric acid and coconut fatty acids. The molar ratio of propylene to ethylene oxide used in these examples varies between 0.4 and 1.1, the initial adducts containing about 1 mole ethylene oxide.ALSO:Liquid water-soluble alkylene oxide addition products are prepared by condensing propylene oxide with addition products of ethylene oxide and aliphatic or alicyclic compounds containing at least 8 carbon atoms with replaceable hydrogen atoms linked via oxygen, sulphur or nitrogen; the addition products containing 5-20 mols of ethylene oxide per mol of aliphatic compound and the ratio of propylene oxide to ethylene oxide being 0.4 to 2. Compounds specified include alcohols, amines, mercaptans, carboxylic acids, sulphonic acids and acid amides. Normally 0.5-1.5 moles of ethylene oxide are added per carbon atom present in the replaceable hydrogen containing compound. In Example 1, 1 mol of a C12-C14 fatty alcohol mixture is condensed with 9 mols of ethylene oxide at 120-148 DEG C. with sodium methylate present. 1 mol of this addition product is condensed with 10 mols of propylene oxide in the presence of sodium methylate at 125-144 DEG C. In Examples 2-7, using similar conditions, the following compounds are used:-a mixture of lauryl and myristyl alcohols, coconut fatty acid mono-ethanolamide, coconut fatty acid diethanolamide, coconut oil amines, lauric acid and coconut fatty acids; and higher polymers are formed. The molar ratio of propylene to ethylene oxide used in the examples varies between 0.4 and 1.1.
GB26394/60A 1959-07-31 1960-07-29 Alkylene oxide addition products Expired GB950844A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB54255A DE1126140B (en) 1959-07-31 1959-07-31 Process for the production of alkylene oxide addition products with low foaming capacity

Publications (1)

Publication Number Publication Date
GB950844A true GB950844A (en) 1964-02-26

Family

ID=6970543

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26394/60A Expired GB950844A (en) 1959-07-31 1960-07-29 Alkylene oxide addition products

Country Status (3)

Country Link
CH (1) CH423265A (en)
DE (1) DE1126140B (en)
GB (1) GB950844A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3340309A (en) * 1965-06-28 1967-09-05 Wyandotte Chemicals Corp Biodegradable, liquid, water-miscible alkylene oxide condensation products
US3943178A (en) * 1973-06-18 1976-03-09 Henkel & Cie Gmbh Secondary alcohol ether ethoxylates
US3969134A (en) * 1971-02-12 1976-07-13 Henkel & Cie G.M.B.H. Process for using clear rinsing agents in mechanical dishwashing
US4134854A (en) * 1973-05-05 1979-01-16 Texaco Development Corp. Nonionic surfactant with low pour point
US4207421A (en) * 1977-11-21 1980-06-10 Olin Corporation Biodegradable, alkali stable, non-ionic surfactants
US4288639A (en) * 1979-10-22 1981-09-08 Basf Wyandotte Corporation Alpha-olefin oxide-modified liquid polyether thickeners
US4354956A (en) * 1979-10-22 1982-10-19 Basf Wyandotte Corporation Thickening aqueous systems with alpha-olefin oxide-modified liquid polyether thickeners
GB2175911A (en) * 1985-04-19 1986-12-10 Sherex Chem Liquid biodegradable surfactant and use thereof
GB2221916A (en) * 1988-08-19 1990-02-21 Petrolite Corp Aqueous dispersions of alkoxylated alcohols and printing inks containing the dispersions
US5634971A (en) * 1995-10-25 1997-06-03 Petrolite Corporation Process for dispersing pigments with polyoxyalkylated ethers

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3393219A (en) * 1965-01-27 1968-07-16 Union Carbide Corp Process for producing ethoxy and sulfate surface-active agents

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2174761A (en) * 1935-04-13 1939-10-03 Ig Farbenindustrie Ag Condensation products derived from hydroxy compounds and method of producing them
US2629706A (en) * 1952-05-24 1953-02-24 Petrolite Corp Certain oxyalkylated derivatives of fusible resins
US2674619A (en) * 1953-10-19 1954-04-06 Wyandotte Chemicals Corp Polyoxyalkylene compounds

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3340309A (en) * 1965-06-28 1967-09-05 Wyandotte Chemicals Corp Biodegradable, liquid, water-miscible alkylene oxide condensation products
US3969134A (en) * 1971-02-12 1976-07-13 Henkel & Cie G.M.B.H. Process for using clear rinsing agents in mechanical dishwashing
JPS5425043B1 (en) * 1971-02-12 1979-08-25
US4134854A (en) * 1973-05-05 1979-01-16 Texaco Development Corp. Nonionic surfactant with low pour point
US3943178A (en) * 1973-06-18 1976-03-09 Henkel & Cie Gmbh Secondary alcohol ether ethoxylates
US4207421A (en) * 1977-11-21 1980-06-10 Olin Corporation Biodegradable, alkali stable, non-ionic surfactants
US4288639A (en) * 1979-10-22 1981-09-08 Basf Wyandotte Corporation Alpha-olefin oxide-modified liquid polyether thickeners
US4354956A (en) * 1979-10-22 1982-10-19 Basf Wyandotte Corporation Thickening aqueous systems with alpha-olefin oxide-modified liquid polyether thickeners
GB2175911A (en) * 1985-04-19 1986-12-10 Sherex Chem Liquid biodegradable surfactant and use thereof
GB2221916A (en) * 1988-08-19 1990-02-21 Petrolite Corp Aqueous dispersions of alkoxylated alcohols and printing inks containing the dispersions
US5634971A (en) * 1995-10-25 1997-06-03 Petrolite Corporation Process for dispersing pigments with polyoxyalkylated ethers

Also Published As

Publication number Publication date
CH423265A (en) 1966-10-31
DE1126140B (en) 1962-03-22

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