GB909208A - A process for the production of alkali metal and alkaline earth metal borohydrides - Google Patents
A process for the production of alkali metal and alkaline earth metal borohydridesInfo
- Publication number
- GB909208A GB909208A GB2419959A GB2419959A GB909208A GB 909208 A GB909208 A GB 909208A GB 2419959 A GB2419959 A GB 2419959A GB 2419959 A GB2419959 A GB 2419959A GB 909208 A GB909208 A GB 909208A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- alkaline earth
- earth metal
- sodium
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicon Compounds (AREA)
Abstract
Alkali or alkaline earth metal boro-hydrides are prepared by reducing either (a) a compound consisting of boron, oxygen, and an alkali or alkaline earth metal or (b) a mixture of an oxidic boron compound (which may contain an alkali or alkaline earth metal) and an alkali or alkaline earth metal or a hydride, carbide, oxide, or hydroxide thereof, with silicon per se or with silicon in the form of an alloy or a metal silicide in the presence of hydrogen at superatmospheric pressure, e.g. 10-300 atms., and 200 DEG -800 DEG C. The reaction may be in liquid or solid phase and powdered reactants may be compressed with a temporary binder and sintered. The Specification refers to the action of silicon and hydrogen on sodium orthoborate, on a mixture of potassium metaborate and calcium oxide or hydride, on a mixture of sodium metaborate and calcium carbide, on a mixture of boron trioxide and barium oxide or sodium, or on a mixture of metaboric acid and strontium oxide, and to the reaction of sodium metaborate, calcium silicide, and hydrogen, or potassium metaborate, aluminium silicide and hydrogen. The Specification also refers to the reaction of silicon with a mixture of sodium metaborate and sodium hydroxide, and of metaboric acid and lithium hydroxide, when the hydrogen atmosphere is produced in the reaction.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF26372A DE1078098B (en) | 1958-08-09 | 1958-08-09 | Process for the production of boranates |
Publications (1)
Publication Number | Publication Date |
---|---|
GB909208A true GB909208A (en) | 1962-10-31 |
Family
ID=7092000
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2419959A Expired GB909208A (en) | 1958-08-09 | 1959-07-14 | A process for the production of alkali metal and alkaline earth metal borohydrides |
Country Status (3)
Country | Link |
---|---|
CH (1) | CH420076A (en) |
DE (1) | DE1078098B (en) |
GB (1) | GB909208A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1047311A (en) * | 1963-11-26 | |||
DE1300523B (en) * | 1964-07-10 | 1969-08-07 | Degussa | Process for the preparation of sodium borate or mixtures containing it |
-
1958
- 1958-08-09 DE DEF26372A patent/DE1078098B/en active Pending
-
1959
- 1959-07-10 CH CH7560959A patent/CH420076A/en unknown
- 1959-07-14 GB GB2419959A patent/GB909208A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CH420076A (en) | 1966-09-15 |
DE1078098B (en) | 1960-03-24 |
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