GB955730A - Preparation of metal borides - Google Patents
Preparation of metal boridesInfo
- Publication number
- GB955730A GB955730A GB1452761D GB1452761D GB955730A GB 955730 A GB955730 A GB 955730A GB 1452761 D GB1452761 D GB 1452761D GB 1452761 D GB1452761 D GB 1452761D GB 955730 A GB955730 A GB 955730A
- Authority
- GB
- United Kingdom
- Prior art keywords
- metal
- borides
- menstruum
- reactants
- boron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 8
- 239000002184 metal Substances 0.000 title abstract 8
- 238000002360 preparation method Methods 0.000 title abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 229910052796 boron Inorganic materials 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 3
- 239000000376 reactant Substances 0.000 abstract 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 150000001642 boronic acid derivatives Chemical class 0.000 abstract 1
- -1 by filtration Chemical class 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 230000029087 digestion Effects 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 230000004907 flux Effects 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/02—Boron; Borides
- C01B35/04—Metal borides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Products (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
A process for the preparation of metal borides, including mixtures of borides, comprises reacting at least one metal component selected from metals of Group IIB, IVB and VB of a specified Periodic chart, including the rare earths, and the actinide elements 90 to 94, and also Mg, Ca, Sr, Ba, Mn, Fe, Ni, Cr and W, and the alloys, halides, sulphides and oxides of these metals, with a boron component selected from elemental boron, metal borates and halides, oxides and hydrides of boron, under an inert atmosphere and at a temperature of at least 1500 DEG F. (except in the case of nickel when the temperature is at least 1200 DEG F.), while said reactants are contacted in a molten alkali metal selected from metallic sodium, potassium and mixtures thereof, and separating the metal boride so formed from said alkali metal, e.g. by filtration, distillation of the menstruum, or methanol digestion. Where the reaction temperature is in excess of the boiling-point of the metal menstruum superatmospheric pressure is maintained above the menstruum. A molten flux, e.g. NaCl, may be used to aid solution of the reactants. The borides produced by the process are microcrystalline and have an average particle size of less than 10 microns. Many specific reactants are mentioned, and the process is extensively exemplified.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2360660A | 1960-04-21 | 1960-04-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB955730A true GB955730A (en) | 1964-04-22 |
Family
ID=21816156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1452761D Expired GB955730A (en) | 1960-04-21 | 1961-04-21 | Preparation of metal borides |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1189055B (en) |
| GB (1) | GB955730A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3391999A (en) * | 1964-08-17 | 1968-07-09 | Texaco Inc | Preparation of metal aluminides |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2523423C2 (en) * | 1975-02-03 | 1981-12-10 | PPG Industries, Inc., 15222 Pittsburgh, Pa. | Submicron titanium diboride and process for its manufacture |
| SU617485A1 (en) * | 1975-06-26 | 1978-07-30 | Отделение Ордена Ленина Институт Химической Физик Ан Ссср | Method of obtaining refractory inorganic materials |
-
1961
- 1961-04-18 DE DEM48735A patent/DE1189055B/en active Pending
- 1961-04-21 GB GB1452761D patent/GB955730A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3391999A (en) * | 1964-08-17 | 1968-07-09 | Texaco Inc | Preparation of metal aluminides |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1189055B (en) | 1965-03-18 |
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