GB907673A - Production of yarns of polymers based on acrylonitrile - Google Patents
Production of yarns of polymers based on acrylonitrileInfo
- Publication number
- GB907673A GB907673A GB37013/60A GB3701360A GB907673A GB 907673 A GB907673 A GB 907673A GB 37013/60 A GB37013/60 A GB 37013/60A GB 3701360 A GB3701360 A GB 3701360A GB 907673 A GB907673 A GB 907673A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vapour
- polyacrylonitrile
- drawn
- filaments
- mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 5
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 4
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 abstract 3
- 238000009835 boiling Methods 0.000 abstract 3
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 229920000578 graft copolymer Polymers 0.000 abstract 1
- 229940117955 isoamyl acetate Drugs 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
- D02J1/222—Stretching in a gaseous atmosphere or in a fluid bed
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
Abstract
Filamentary yarns and tows of polyacrylonitrile, free from contained solvent, are drawn in a medium comprising the vapour of n-amyl alcohol, isoamyl alcohol, or mixtures thereof, n-amyl acetate, isoamyl acetate, or mixtures thereof, or of cyclohexanone. The term "polyacrylonitrile" includes polymers, copolymers, grafted polymers and mixtures thereof containing 85-100% polyacrylonitrile and up to 15% of one or more copolymerizable ethylenic compounds. The vapour may be maintained at a temperature close to the boiling point of the liquid of which it is the vapour, usually slightly below the boiling point, so that drawing may be effected in the vapour of the boiling liquid. In Examples (1), (3), a polyacrylonitrile untwisted yarn is drawn up to 16,5x in cyclohexanone vapour at 153 DEG C., (2) a yarn of filaments of 85% polyacrylonitrile and 15% polyvinyl acetate twisted 50 turns per metre is drawn 11,4x in amyl alcohol vapour at 131 DEG C., (4) a tow of filaments of a copolymer of 92% acrylonitrile and 8% methyl methacrylate is drawn in saturated isoamyl acetate vapour at 145 DEG C. The process of the invention enables filaments to be drawn to a higher draw ratio than is possible by conventional methods, and for a given draw ratio the process yields filaments of higher tenacity.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR809190A FR1248484A (en) | 1959-11-03 | 1959-11-03 | Improvement in the manufacture of acrylonitrile-based polymer yarns |
Publications (1)
Publication Number | Publication Date |
---|---|
GB907673A true GB907673A (en) | 1962-10-10 |
Family
ID=8720846
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB37013/60A Expired GB907673A (en) | 1959-11-03 | 1960-10-27 | Production of yarns of polymers based on acrylonitrile |
Country Status (7)
Country | Link |
---|---|
US (1) | US3150223A (en) |
CH (1) | CH389154A (en) |
DE (1) | DE1209241B (en) |
ES (1) | ES262136A1 (en) |
FR (1) | FR1248484A (en) |
GB (1) | GB907673A (en) |
NL (2) | NL125916C (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3426117A (en) * | 1966-12-14 | 1969-02-04 | Japan Exlan Co Ltd | Method for treating acrylic composite fiber |
US4013753A (en) * | 1973-10-09 | 1977-03-22 | Bayer Aktiengesellschaft | Process for the production of spontaneously crimping polyacrylonitrile composite fibres with improved crimp properties |
US11555964B1 (en) | 2021-06-30 | 2023-01-17 | Globalfoundries U.S. Inc. | Optical device with low-loss thermally tunable closed-curve optical waveguide |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2499477A (en) * | 1945-06-07 | 1950-03-07 | Union Carbide & Carbon Corp | Vinyl resin textile article |
US2476069A (en) * | 1947-02-08 | 1949-07-12 | Wingfoot Corp | Delustering copolymer filaments |
US2768057A (en) * | 1950-02-08 | 1956-10-23 | Phrix Werke Ag | Drawing of organic high polymers |
-
0
- NL NL247497D patent/NL247497A/xx unknown
- NL NL125916D patent/NL125916C/xx active
-
1959
- 1959-11-03 FR FR809190A patent/FR1248484A/en not_active Expired
-
1960
- 1960-10-27 GB GB37013/60A patent/GB907673A/en not_active Expired
- 1960-10-27 US US65294A patent/US3150223A/en not_active Expired - Lifetime
- 1960-10-27 CH CH1202460A patent/CH389154A/en unknown
- 1960-10-31 DE DEC22645A patent/DE1209241B/en active Pending
- 1960-11-02 ES ES0262136A patent/ES262136A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL247497A (en) | |
CH389154A (en) | 1965-03-15 |
ES262136A1 (en) | 1960-12-16 |
NL125916C (en) | |
US3150223A (en) | 1964-09-22 |
DE1209241B (en) | 1966-01-20 |
FR1248484A (en) | 1960-12-16 |
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