GB906324A - Improvements in or relating to cellulosic textiles - Google Patents

Improvements in or relating to cellulosic textiles

Info

Publication number
GB906324A
GB906324A GB4298459A GB4298459A GB906324A GB 906324 A GB906324 A GB 906324A GB 4298459 A GB4298459 A GB 4298459A GB 4298459 A GB4298459 A GB 4298459A GB 906324 A GB906324 A GB 906324A
Authority
GB
United Kingdom
Prior art keywords
substances
roentgen
condensable
dimethylol
electromagnetic radiation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4298459A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heberlein and Co AG
Original Assignee
Heberlein and Co AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Heberlein and Co AG filed Critical Heberlein and Co AG
Priority claimed from CH7144459A external-priority patent/CH368465A/en
Publication of GB906324A publication Critical patent/GB906324A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D06M10/10—Macromolecular compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/08—Decorating textiles by fixation of mechanical effects, e.g. calendering, embossing or Chintz effects, using chemical means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/918—Material abnormally transparent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/18—Grafting textile fibers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2965—Cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2971—Impregnation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2369—Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
    • Y10T442/2393—Coating or impregnation provides crease-resistance or wash and wear characteristics

Abstract

Cellulosic textile materials, i.e. yarns, fibres, threads, woven and knitted fabrics and goods made wholly or partly from natural or regenerated cellulose, are impregnated with a condensable substance which can be condensed with itself to form a resinous condensate or with a mixture of two or more substances which inter-condense to form a resinous condensate and then subjected to the influence of an ionizing electromagnetic radiation at a low dosage to effect condensation of the condensable substance or substances without causing substantial loss of fibre strength. Dosages of ionizing electromagnetic radiation, e.g. gamma rays and X-rays, of less than 107 Roentgen and of at least 103 Roentgen are used, e.g. 0,5 X 106-3 X 106 Roentgen at 15 DEG -25 DEG C., convenient sources for gamma radiation being 60Co and fission products of 235U or 137Cs. Suitable condensable substances which may be used in the form of dispersions or solutions in water or one or more organic solvents are methylol urea, methylol melamines, dimethylol ethylene urea, 2,6-dimethylol triazin-4-ane, diglycidyl ether, aziridinyl phosphonium oxide and 1-carbonyl-2,5-dimethylol-4-ethyltriazine-2,4,6 and mixture thereof. The condensable substance may be used with or without the addition of one or more catalysts, e.g. boron trifluoride, zinc nitrate and light or heavy metal halides, and the textile material may be irradiated in moist or dry condition. The treating solution may also contain a softener, e.g. polyethylene or octadecyl ethylene urea, polyvinyl alcohol or a silicane.ALSO:The crease resistance, dimensional stability and permanency of surface effects, e.g. goffering, ripple, schreiner, moire and calender effects, of cellulosic textile materials, i.e. yarns, fibres, threads, woven and knitted fabrics and goods made wholly or partly from natural or regenerated cellulose, are improved without reducing their tensile strength, tear resistance and hand by impregnating them with a condensable substance which can be condensed with itself to form a resinous condensate or with a mixture of two or more substances which inter-condense to form a resinous condensate and then subjecting them to the influence of an ionising electromagnetic radiation at a low dosage to effect condensation of the condensable substance or substances without causing substantial loss of fibre strength. Dosages of ionising electromagnetic radiation, e.g. gamma rays and X-rays, of less than 107 Roentgen and of at least 103 Roentgen are used, e.g. 0.5 x 106-3 x 106 Roentgen at 15-25 DEG C., convenient sources for gamma radiation being 60Co and fission products of 235U or 137Cs. Suitable condensable substances which may be used in the form of dispersions or solutions in water or one or more organic solvents are methylolurea, methylol melamines, dimethylol ethylene urea, 2,6-dimethyloltriazin-4-one, diglycidyl ether, aziridinyl phosphonium oxide and 1-carbonyl- 2,5-dimethylol- 4-ethyl-triazine-2,4,6 and mixtures thereof. The condensable substances may be used with or without the addition of one or more catalysts, e.g. borontrifluoride, zinc nitrate and light or heavy metal halides, and the textile material may be irradiated in moist or dry condition. Prior to treatment with the condensable substance, cellulosic fabrics, e.g. cotton and regenerated cellulose, may be stiffened and transparentised by treatment with concentrated sulphuric acid, a cuprammonium hydroxide solution or a sodium zincate cellulose solution. The treating solution may also contain a softener, e.g. polyethylene or octadecylethyleneurea, polyvinyl alcohol or a silicone.
GB4298459A 1959-04-01 1958-12-17 Improvements in or relating to cellulosic textiles Expired GB906324A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH7144459A CH368465A (en) 1959-04-01 1959-04-01 Process for improving the mechanical properties of textiles
CH7815959A CH383326A (en) 1959-04-01 1959-10-01 Process for improving the mechanical properties of textiles
CH839860A CH386384A (en) 1959-04-01 1960-07-22 Process for improving the textile properties of textiles

Publications (1)

Publication Number Publication Date
GB906324A true GB906324A (en) 1962-09-19

Family

ID=27175988

Family Applications (2)

Application Number Title Priority Date Filing Date
GB4298459A Expired GB906324A (en) 1959-04-01 1958-12-17 Improvements in or relating to cellulosic textiles
GB2510561A Expired GB917151A (en) 1959-04-01 1961-07-11 Improvements in or relating to cellulosic textiles

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB2510561A Expired GB917151A (en) 1959-04-01 1961-07-11 Improvements in or relating to cellulosic textiles

Country Status (6)

Country Link
US (2) US3140197A (en)
BE (2) BE587866A (en)
CH (2) CH383326A (en)
DE (2) DE1113677B (en)
GB (2) GB906324A (en)
NL (2) NL266456A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3374111A (en) * 1964-06-30 1968-03-19 Ibm Method for depositing thin dielectric polymer films
EP0120316A2 (en) * 1983-03-01 1984-10-03 Akzo GmbH Fibres, yarns, textile materials, foils and similar products with improved properties

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1034131A (en) * 1961-10-17 1966-06-29 British Celanese Improvements in the production of embossed cellulose triacetate fabrics
US3320088A (en) * 1963-10-04 1967-05-16 Hercules Inc Stereoregular polypropylene coated with an insolubilized ethylene oxide polymer
US3326788A (en) * 1964-01-29 1967-06-20 Union Carbide Corp Cross-linked and epoxidized cellulosic products
CH407034A (en) * 1964-03-13 1965-09-15 Heberlein & Co Ag Process for removing energy from cellulosic textile material treated with ionizing radiation
US3434161A (en) * 1965-10-05 1969-03-25 Research Corp Textile fabric treatment
US3652212A (en) * 1967-04-17 1972-03-28 Deering Milliken Res Corp Multi-step in situ polymer formation to produce fabric having improved soiling characteristics
US4100147A (en) * 1975-10-14 1978-07-11 Texaco Inc. Polymerization of aliphatic nitriles
WO1980000142A1 (en) * 1978-07-06 1980-02-07 A Akesson A method of manufacturing bonded products of cellulose or cellulose derivatives
DE2933998C2 (en) * 1979-08-22 1987-05-27 Otto Dürr Anlagenbau GmbH, 7000 Stuttgart Method and device for the production of an impregnated paper or non-woven substrate
US4376802A (en) * 1980-01-24 1983-03-15 Allied Corporation Finish composition for polyester yarn
US4382847A (en) * 1980-03-06 1983-05-10 Arne Akesson Method of manufacturing bonded products of cellulose or cellulose derivatives

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1818073A (en) * 1931-08-11 And one-third to
FR66034E (en) *
BE392420A (en) * 1931-11-23
US2373135A (en) * 1942-04-14 1945-04-10 Du Pont Treatment of hydroxylated polymers
FR1070401A (en) * 1945-07-04 1954-07-26 New construction process using independent articulated elements superimposed, without ligature or sealing, intimately combined with construction elements
US2545540A (en) * 1949-02-21 1951-03-20 Coin J Beuck Fountain pen holder
US2670483A (en) * 1951-10-05 1954-03-02 United Shoe Machinery Corp Stiffening portion of shoes
BE520401A (en) * 1952-06-03
GB758735A (en) * 1952-12-06 1956-10-10 Gen Electric Improved pigment-printed textile and other fibrous materials
DE1042521B (en) * 1955-04-07 1958-11-06 Du Pont Process for the modification of fibers or films made from natural or regenerated natural polymers
US2833674A (en) * 1955-06-21 1958-05-06 Rohm & Haas Compositions for the treatment of textiles, the textiles obtained and processes for the treatment thereof
GB802620A (en) * 1956-05-22 1958-10-08 Du Pont Improvements in or relating to the production of coatings
US2940869A (en) * 1956-07-12 1960-06-14 Du Pont Process of adhering an organic compound to a shaped organic polymer
US2950553A (en) * 1957-01-16 1960-08-30 Rohm & Haas Method of producing wrinkle resistant garments and other manufactured articles of cotton-containing fabrics
NL229381A (en) * 1957-07-08
US2998329A (en) * 1957-08-05 1961-08-29 Dow Chemical Co Modification of cellulosic articles

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3374111A (en) * 1964-06-30 1968-03-19 Ibm Method for depositing thin dielectric polymer films
EP0120316A2 (en) * 1983-03-01 1984-10-03 Akzo GmbH Fibres, yarns, textile materials, foils and similar products with improved properties
EP0120316A3 (en) * 1983-03-01 1987-03-04 Akzo GmbH Fibres, yarns, textile materials, foils and similar products with improved properties

Also Published As

Publication number Publication date
CH386384A (en) 1964-09-30
US3206273A (en) 1965-09-14
DE1174740B (en) 1964-07-30
BE606332A (en) 1900-01-01
NL244572A (en) 1900-01-01
US3140197A (en) 1964-07-07
BE587866A (en) 1900-01-01
GB917151A (en) 1963-01-30
CH7815959A4 (en) 1964-07-15
NL266456A (en) 1900-01-01
DE1113677B (en) 1961-09-14
CH383326A (en) 1964-12-31

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