GB758735A - Improved pigment-printed textile and other fibrous materials - Google Patents
Improved pigment-printed textile and other fibrous materialsInfo
- Publication number
- GB758735A GB758735A GB33995/53A GB3399553A GB758735A GB 758735 A GB758735 A GB 758735A GB 33995/53 A GB33995/53 A GB 33995/53A GB 3399553 A GB3399553 A GB 3399553A GB 758735 A GB758735 A GB 758735A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- styrene
- polyethylene
- monomeric
- printed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The cracking and colour-fastness of pigment-printed textiles and other fibrous materials such as paper sheets is improved by printing the material with a composition comprising a pigment, a resinous or cellulose derivative-carrying agent and a binder, the binder being a monomeric polymerizable compound or a polymeric compound or a mixture thereof which is convertible by high-energy electrons to a higher molecular weight product, and then irradiating the printed material with high-energy electrons. Specified binders are monomeric materials such as styrene, ethyl acrylate, n-butyl acrylate, ethylene glycol dimethacrylate, tetraethylene glycol diacrylate and dimethacrylate, acrylonitrile, diethylene glycol maleate and maleate-adipate and mixtures thereof and mixtures of unsaturated monomeric alkyds with other copolymerizable monomers such as styrene; and polymeric materials such as homopolymers of butadiene and chlorobutadiene, copolymers of butadiene with styrene or with acrylonitrile, natural rubber, polyacrylonitrile, nylon, polyalkyl acrylates, silicone-rubbers and resins, polyethylene and modified polyethylene such as chlorinated and chloro-sulphonated polyethylene. Specified pigments are phthalocyanine blue and green, cadmium red, benzidine yellow, earth oxides such as red iron oxide, prussian blue, carbon black and chrome green. The carrying agent comprises a water-in-oil or oil-in-water emulsion containing, for example, an alkyd resin, if desired modified with oils, alcohols or monocarboxylic acids; or a cellulose derivative such as ethyl cellulose or cellulose acetate or acetobutyrate; or an oil modified phenol-formaldehyde resin or a urea-, butylated urea-, melamine- or aniline-formaldehyde resin. Fabrics of cotton, wool, silk, rayon and of nylon, polyacrylonitrile and polyester fibres may be printed.ALSO:The crocking- and colour-fastness of pigment-printed textiles and other fibrous materials such as paper sheets is improved by printing the material with a composition comprising a pigment, a resinous or cellulose derivative carrying agent and a binder, the binder being a monomeric polymerizable compound or a polymeric compound or a mixture thereof which is convertible by high-energy electrons to a higher molecular weight product, and then irradiating the printed material with high-energy electrons. Specified binders are monomeric materials such as styrene, ethyl acrylate, n-butyl acrylate, ethylene glycol dimethacrylate, tetraethylene glycol diacrylate and dimethacrylate, acrylonitrile, diethylene glycol maleate and maleate-adipate and mixtures thereof and mixtures of unsaturated monomeric alkyds with other co-polymerizable monomers such as styrene; and polymeric materials such as homopolymers of butadiene and chlorobutadiene, copolymers of butadiene with styrene or with acrylonitrile, natural rubber, polyacrylonitrile, nylon, polyalkyl acrylates, silicone-rubbers and -resins, polyethylene and modified polyethylene such as chlorinated and chlorosulphonated polyethylene. Specified pigments are phthalocyanine blue and green, cadmium red, benzidene yellow, earth oxides such as red iron oxide, prussian blue, carbon black and chrome green. The carrying agent comprises a water-in-oil or oil-in-water emulsion containing, for example, an alkyd resin, if desired modified with oil, alcohols or monocarboxylic acids; or a cellulose derivative such as ethyl cellulose or cellulose acetate or acetobutyrate; or an oil-modified phenol-formaldehyde resin or a urea-, butylated urea-melamine- or aniline-formaldehyde resin. Fabrics of cotton, wool, silk and rayon and of nylon, polyacrylonitrile and polyester fibres may be printed.ALSO:The crocking and colour-fastness of pigment-printed textiles and other fibrous materials such as paper sheets is improved by printing the material with a composition comprising a pigment, a resinous or cellulose derivative carrying agent and a binder, the binder being a monomeric polymersizable compound or a polymeric compound or a mixture thereof which is convertible by high-energy electrons to a higher molecular weight product, and then irradiating the printed material with highenergy electrons. Specified binders are monomeric materials such as styrene, ethyl acrylate, n-butyl acrylate, ethylene glycol dimethacrylate, tetraethylene glycoldiacrylate and dimethacrylate, acrylonitrile, diethylene glycol maleate and maleate-adipate and mixtures thereof and mixtures of unsaturated monomeric alkyds with other co-polymerizable monomers such as styrene; and polymeric materials such as homopolymers of butadiene and chlorobutadiene, copolymers of butadiene with styrene or with acrylonitrile, natural rubber, polyacrylonitrile, nylon, polyalkyl acrylates, silicone rubbers and resins, polyethylene and modified polyethylene such as chlorinated and chloro-sulphonated polyethylene. Specified pigments are phthalocyanine blue and green, cadmium red, benzidine yellow, earth oxides such as red iron oxide, prussian blue, carbon black and chrome green. The carrying agent comprises a water-in-oil or oil-in-water emulsion containing, for example, and alkyd resin, if desired modified with oils, alcohols or monocarboxylic acids; or a cellulose derivative such as ethyl cellulose or cellulose acetate or acetobutyrate; or an oil modified phenol-formaldehyde resin or a urea-, butylated urea-, melamine- or aniline-formaldehyde resin. Fabrics of cotton, wool, silk and rayon and of nylon, polyacrylonitrile and polyester fibres may be printed.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US758735XA | 1952-12-06 | 1952-12-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB758735A true GB758735A (en) | 1956-10-10 |
Family
ID=22128507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB33995/53A Expired GB758735A (en) | 1952-12-06 | 1953-12-07 | Improved pigment-printed textile and other fibrous materials |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB758735A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3206273A (en) * | 1959-04-01 | 1965-09-14 | Heberlein & Co Ag | Cellulosic textile finishing |
| US3252750A (en) * | 1960-07-29 | 1966-05-24 | Heberlein & Co Ag | Cellulosic textile finishing |
| US3254939A (en) * | 1965-02-01 | 1966-06-07 | Herberlein & Co Ag | Process of modifying cellulosic materials with ionizing radiation |
| US3254940A (en) * | 1960-09-21 | 1966-06-07 | Heberlein & Co Ag | Cellulosic textile finishing process and product |
| US3281263A (en) * | 1961-03-17 | 1966-10-25 | Dow Chemical Co | Method for modifying polymeric substances with high energy radiation |
| US3284156A (en) * | 1961-09-28 | 1966-11-08 | Du Pont | Synthetic polyamide textile material having a polyorganosiloxane grafted thereto |
| US3617187A (en) * | 1966-07-18 | 1971-11-02 | Hakuyosha Co Ltd | Process for preparation of silicone graft copolymerized fiber or cloth |
-
1953
- 1953-12-07 GB GB33995/53A patent/GB758735A/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3206273A (en) * | 1959-04-01 | 1965-09-14 | Heberlein & Co Ag | Cellulosic textile finishing |
| US3252750A (en) * | 1960-07-29 | 1966-05-24 | Heberlein & Co Ag | Cellulosic textile finishing |
| US3254940A (en) * | 1960-09-21 | 1966-06-07 | Heberlein & Co Ag | Cellulosic textile finishing process and product |
| US3281263A (en) * | 1961-03-17 | 1966-10-25 | Dow Chemical Co | Method for modifying polymeric substances with high energy radiation |
| US3284156A (en) * | 1961-09-28 | 1966-11-08 | Du Pont | Synthetic polyamide textile material having a polyorganosiloxane grafted thereto |
| US3254939A (en) * | 1965-02-01 | 1966-06-07 | Herberlein & Co Ag | Process of modifying cellulosic materials with ionizing radiation |
| US3617187A (en) * | 1966-07-18 | 1971-11-02 | Hakuyosha Co Ltd | Process for preparation of silicone graft copolymerized fiber or cloth |
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