GB997821A - Process for treating cellulosic textile materials and products therefor - Google Patents

Process for treating cellulosic textile materials and products therefor

Info

Publication number
GB997821A
GB997821A GB10004/62A GB1000462A GB997821A GB 997821 A GB997821 A GB 997821A GB 10004/62 A GB10004/62 A GB 10004/62A GB 1000462 A GB1000462 A GB 1000462A GB 997821 A GB997821 A GB 997821A
Authority
GB
United Kingdom
Prior art keywords
textile
dimethylol
urea
resin
textile materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB10004/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deering Milliken Research Corp
Milliken Research Corp
Original Assignee
Deering Milliken Research Corp
Milliken Research Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deering Milliken Research Corp, Milliken Research Corp filed Critical Deering Milliken Research Corp
Publication of GB997821A publication Critical patent/GB997821A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C317/18—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/262—Sulfated compounds thiosulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/272—Unsaturated compounds containing sulfur atoms
    • D06M13/278—Vinylsulfonium compounds; Vinylsulfone or vinylsulfoxide compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)

Abstract

Polyfunctional organic compounds suitable for use in the creaseproofing of cellulosic textile materials are produced by the reaction of a polymethylol aminoplast resin precondensate, e.g. dimethylol urea, tetra- or penta-methylol melamine, acrolein - urea - formaldehyde, dimethylol cyclic ethylene urea, dimethylol-dihydroxy-cyclic ethylene urea, trimethylol-acetylene diurea, tetramethylolacetylene diurea, dimethylol - N - ethyl - triazane, dimethylol - N - hydroxyethyl - triazane, N,N1-ethylene - bis - dimethyloltriazane or dimethyloluran resin precondensates, with a monoester of a compound of the formula HO-CH2CH2S(O)x-CH2CH2OH in which x is 1 or 2, the monoester preferably being the sulphate, phosphate or thiosulphate which may be in the form of their alkali metal salts, or an organic ester containing 1-12 carbon atoms, preferably at 80-190 DEG C.ALSO:Cellulosic textile materials, e.g. fibres, yarns and fabrics comprising cotton, linen, jute, flax or regenerated cellulose fibres alone or in admixture with glycol-terephthalate, polyacrylic or nylon fibres, are crease-proofed by impregnating them with a textile resin catalyst and a polyfunctional organic compound having at least one functional group reactive to cellulose under textile resin curing conditions and at least one functional group substantially inert under the curing conditions but reactive to cellulose in the presence of a strong aqueous base and heating the textile materials in a dry unswollen condition to chemically fix the polyfunctional compound to the textile materials by reaction of the functional group reactive to cellulose under textile resin curing conditions and then, if desired, impregnating them with a strong aqueous base to further chemically fix the compound to the textile materials by reaction of the functional group reactive to cellulose in the presence of a strong aqueous base while the textile materials are in a wet swollen condition. Suitable acid reactive groups reactive with the cellulose under textile resin curing conditions are methylol, acetal, allcylated methylol and aldehyde groups and suitable base reactive groups are epoxy, halohydrin and carbonyl, acetylenic, sulphone and sulphoxide activated groups, e.g. -CH2CH2-R-R1 in which R is a carbonyl, sulphone, sulphoxide or acetylenic group and R1 is sulphatoethyl, alkalimetal sulphatoethyl, phosphatoethyl, alkali metal phosphatoethyl, thiosulphatoethyl or alkali-metal thiosulphatoethyl, quaternary ammonium ethyl halides, vinyl or substituted vinyl. The polyfunctional compound may be produced either before application to the textile material or in situ by the reaction of a polymethylol textile resin precondensate, e.g. dimethylol urea, tetra-or pentamethylol melamine, acrolein-urea-formaldehyde resin, dimethylol cyclic ethylene urea, dimethyloldihydroxy cyclic ethylene urea, trimethylolacetylene diurea, tetramethylolacetylene diurea, dimethylol-N-ethyl-triazone, dimethylol-N-hydroxyethyl-triazone, N, N1-ethylene-bio-dimethyloltriazone and dimethyloluron, or an epoxy or acetal textile resin and mono-ester of di-b -hydroxyethyl-sulphone or di-b -hydroxyethyl-sulphoxide monoester being the sulphate, phosphate or thiosulphate preferably in the form of their alkali metal salts or an organic ester containing 1-12 carbon atoms. The polyfunctional compound may be applied to the textile materials as an aqueous solution which may also contain a poly-ethylene softener and the textile resin catalyst, e.g. magnesium chloride, zinc nitrate, zinc fluoroborate, monoethanolamine hydrochloride and 2-amino-2-methyl-propanol nitrate, and the textile material then dried and heated to 100-200 DEG C. It may then be washed and treated at 20-100 DEG C. with the aqueous solution of the base which has a pH of at least 10 as a 1% by weight aqueous solution, suitable bases being sodium silicate, hydroxide or carbonate and potassium carbonate. Specification 997,822 is referred to.
GB10004/62A 1961-03-20 1962-03-15 Process for treating cellulosic textile materials and products therefor Expired GB997821A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US9667361A 1961-03-20 1961-03-20

Publications (1)

Publication Number Publication Date
GB997821A true GB997821A (en) 1965-07-07

Family

ID=22258517

Family Applications (2)

Application Number Title Priority Date Filing Date
GB4050/65A Expired GB997822A (en) 1961-03-20 1962-03-15 Mono-esters of hydroxyalkyl sulphones and sulphoxides
GB10004/62A Expired GB997821A (en) 1961-03-20 1962-03-15 Process for treating cellulosic textile materials and products therefor

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB4050/65A Expired GB997822A (en) 1961-03-20 1962-03-15 Mono-esters of hydroxyalkyl sulphones and sulphoxides

Country Status (9)

Country Link
US (1) US3418067A (en)
BE (1) BE615318A (en)
CH (1) CH467898A (en)
DE (1) DE1419427A1 (en)
DK (1) DK109134C (en)
ES (1) ES275579A1 (en)
FR (1) FR1318939A (en)
GB (2) GB997822A (en)
NL (1) NL276161A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1222015B (en) * 1963-05-09 1966-08-04 Basf Ag Process for finishing textile goods
DE1242550B (en) * 1964-09-16 1967-06-22 Tootal Ltd Process for making cellulosic textiles crease-proof
US3521994A (en) * 1968-04-08 1970-07-28 Celanese Corp Process for manufacturing durable press garments
US4336023A (en) * 1980-12-30 1982-06-22 Rohm And Haas Company Formaldehyde-free durable press finish fabrics

Also Published As

Publication number Publication date
ES275579A1 (en) 1962-07-16
DK109134C (en) 1968-03-25
GB997822A (en) 1965-07-07
FR1318939A (en) 1963-02-22
CH331362A4 (en) 1968-10-15
DE1419427A1 (en) 1968-10-03
NL276161A (en)
BE615318A (en)
US3418067A (en) 1968-12-24
CH467898A (en) 1969-03-14

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