GB906055A - Process and catalysts for the polymerisation of dienes - Google Patents
Process and catalysts for the polymerisation of dienesInfo
- Publication number
- GB906055A GB906055A GB20741/60A GB2074160A GB906055A GB 906055 A GB906055 A GB 906055A GB 20741/60 A GB20741/60 A GB 20741/60A GB 2074160 A GB2074160 A GB 2074160A GB 906055 A GB906055 A GB 906055A
- Authority
- GB
- United Kingdom
- Prior art keywords
- halide
- friedel
- crafts
- alkyl
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 150000001993 dienes Chemical class 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 abstract 5
- 239000004215 Carbon black (E152) Substances 0.000 abstract 4
- 238000005727 Friedel-Crafts reaction Methods 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 4
- 150000004820 halides Chemical class 0.000 abstract 4
- 229930195733 hydrocarbon Natural products 0.000 abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 abstract 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 3
- -1 cobalt halide Chemical class 0.000 abstract 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 2
- 101100058670 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) bsr gene Proteins 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 2
- 125000005234 alkyl aluminium group Chemical group 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- 239000003085 diluting agent Substances 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 229910001507 metal halide Inorganic materials 0.000 abstract 2
- 150000005309 metal halides Chemical class 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011592 zinc chloride Substances 0.000 abstract 2
- 235000005074 zinc chloride Nutrition 0.000 abstract 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 abstract 1
- ZZLCFHIKESPLTH-UHFFFAOYSA-N 4-Methylbiphenyl Chemical compound C1=CC(C)=CC=C1C1=CC=CC=C1 ZZLCFHIKESPLTH-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 229910006644 SnIV Inorganic materials 0.000 abstract 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US742016A US3066125A (en) | 1958-06-16 | 1958-06-16 | Diene polymerization and catalysts therefor |
| US759858A US3066126A (en) | 1958-06-16 | 1958-09-09 | Diene polymerization catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB906055A true GB906055A (en) | 1962-09-19 |
Family
ID=27113954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20741/60A Expired GB906055A (en) | 1958-06-16 | 1959-06-15 | Process and catalysts for the polymerisation of dienes |
Country Status (6)
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3170904A (en) * | 1959-11-28 | 1965-02-23 | Bridgestone Tire Co Ltd | Production of cis-1, 4 polybutadiene with a ni-bf3 etherate-air3 catalyst |
| US3170907A (en) * | 1959-12-31 | 1965-02-23 | Bridgestone Tire Co Ltd | Production of cis-1, 4 polybutadiene with a nickel carboxylic acid salt-boron trifluoride etherate-aluminum trialkyl catalyst |
| GB906334A (en) * | 1959-12-31 | 1962-09-19 | Bridgestone Tire Co Ltd | Method of manufacturing cis-1,4-polybutadiene |
| NL260825A (US07282526-20071016-C00003.png) * | 1960-02-03 | |||
| NL266379A (US07282526-20071016-C00003.png) * | 1960-06-27 | |||
| US3159691A (en) * | 1960-12-05 | 1964-12-01 | Phillips Petroleum Co | Cis-polybutadiene compositions |
| DE1268397B (de) * | 1961-05-10 | 1968-05-16 | Basf Ag | Verfahren zur Herstellung von kautschukelastischen Polymeren aus 1, 3-Dienen |
| NL267161A (US07282526-20071016-C00003.png) * | 1961-07-17 | |||
| BE625158A (US07282526-20071016-C00003.png) * | 1961-11-29 | |||
| NL296064A (US07282526-20071016-C00003.png) * | 1962-08-07 | |||
| US3352839A (en) * | 1962-08-10 | 1967-11-14 | Goodrich Gulf Chem Inc | Diolefin polymerization catalysts using a metalliferous component, a catalyst regulator and aix |
| US3185741A (en) * | 1962-11-19 | 1965-05-25 | Phillips Petroleum Co | Diene trimerization |
| US3463766A (en) * | 1963-12-09 | 1969-08-26 | Snam Progetti | Process for preparing 1,4 cis polybutadiene using aibr3,an aluminum monohydride and a cobalt compound |
| DE1570525B1 (de) * | 1964-11-02 | 1970-01-22 | Exxon Research Engineering Co | Verfahren zur Herstellung von Polymerisaten konjugierter Diolefine |
| GB1090455A (en) * | 1964-11-27 | 1967-11-08 | Internat Synthetic Rubber Comp | Novel nickel-containing substances and their use as polymerisation catalysts in the preparation of polyolefins |
| GB1171281A (en) * | 1966-01-04 | 1969-11-19 | British Petroleum Co | Dimerisation Process |
| US3678025A (en) * | 1970-05-22 | 1972-07-18 | Dow Chemical Co | Preparation of linear alpha olefin polymers having broad molecular weight distributions |
| US4198315A (en) * | 1978-09-05 | 1980-04-15 | The Dow Chemical Company | High efficiency catalyst for polymerizing olefins |
| US4224186A (en) * | 1979-04-09 | 1980-09-23 | The Dow Chemical Company | High efficiency catalyst for polymerizing olefins |
| US4238355A (en) * | 1979-09-10 | 1980-12-09 | The Dow Chemical Company | High efficiency catalyst for polymerizing olefins |
| US4269733A (en) * | 1979-09-28 | 1981-05-26 | The Dow Chemical Company | Ultra high efficiency catalyst for polymerizing olefins |
| US4399053A (en) * | 1980-12-24 | 1983-08-16 | The Dow Chemical Company | High efficiency catalyst containing titanium, zirconium and zinc for polymerizing olefins |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2092295A (en) * | 1935-01-30 | 1937-09-07 | Shell Dev | Production of synthetic resins and resinous materials |
| US2476416A (en) * | 1942-01-07 | 1949-07-19 | Universal Oil Prod Co | Isomerization of paraffin hydrocarbons by contact with catalyst comprising aluminum chloride and ferric chloride |
| DE874215C (de) * | 1943-12-18 | 1953-04-20 | Basf Ag | Verfahren zur Herstellung von festen Polymerisaten aus AEthylen oder aethylenreichenGasen |
| GB611157A (en) * | 1946-04-23 | 1948-10-26 | Standard Oil Dev Co | Process for the production of styrene co-polymers |
| US2865841A (en) * | 1953-09-21 | 1958-12-23 | Universal Oil Prod Co | Hydrocracking with a catalyst comprising aluminum, or aluminum chloride, titanium tetrachloride, and hydrogen chloride |
| DE1012460B (de) * | 1953-11-17 | 1957-07-18 | Dr Dr E H Karl Ziegler | Verfahren zur Herstellung von hochmolekularen Polyaethylenen |
| IT553429A (US07282526-20071016-C00003.png) * | 1954-12-02 | |||
| IT549626A (US07282526-20071016-C00003.png) * | 1955-01-05 | |||
| NL206073A (US07282526-20071016-C00003.png) * | 1955-04-07 | 1900-01-01 | Hercules Powder Co Ltd | |
| BE638937A (US07282526-20071016-C00003.png) * | 1955-12-16 | |||
| US2910461A (en) * | 1956-05-14 | 1959-10-27 | Phillips Petroleum Co | Continuous process for the production of high molecular weight olefin polymers |
| US2868771A (en) * | 1956-07-17 | 1959-01-13 | Ethyl Corp | Polymerization of olefins |
| US2953554A (en) * | 1956-08-07 | 1960-09-20 | Goodrich Gulf Chem Inc | Method of removing heavy metal catalyst from olefinic polymers by treatment with an aqueous solution of a complexing agent |
| US2977349A (en) * | 1956-11-07 | 1961-03-28 | Goodrich Gulf Chem Inc | Process for polymerizing dienes |
| US2928818A (en) * | 1957-07-01 | 1960-03-15 | Eastman Kodak Co | Process of polymerizing ethylene with aluminum-titanium halide catalyst |
| US2953556A (en) * | 1957-07-18 | 1960-09-20 | Goodrich Gulf Chem Inc | Polymer recovery process |
| US2928820A (en) * | 1957-10-30 | 1960-03-15 | Grace W R & Co | Polyethylene process |
| US2933485A (en) * | 1957-10-30 | 1960-04-19 | Grace W R & Co | Polyethylene process |
| US2925410A (en) * | 1958-04-03 | 1960-02-16 | Eastman Kodak Co | Catalyst containing aluminum, titanium tetrahalide, and alkali metal fluoride and olefin polymerization therewith |
| NL238472A (US07282526-20071016-C00003.png) * | 1958-04-25 |
-
0
- NL NL240204D patent/NL240204A/xx unknown
-
1958
- 1958-06-16 US US742016A patent/US3066125A/en not_active Expired - Lifetime
- 1958-09-09 US US759858A patent/US3066126A/en not_active Expired - Lifetime
-
1959
- 1959-06-15 FR FR797543A patent/FR1235599A/fr not_active Expired
- 1959-06-15 NL NL240204A patent/NL113827C/xx active
- 1959-06-15 BE BE579689D patent/BE579689A/xx unknown
- 1959-06-15 GB GB20741/60A patent/GB906055A/en not_active Expired
- 1959-06-15 DE DES63478A patent/DE1148384B/de active Pending
-
1965
- 1965-01-08 NL NL6500176A patent/NL134445C/xx active
Also Published As
| Publication number | Publication date |
|---|---|
| FR1235599A (fr) | 1960-11-04 |
| US3066125A (en) | 1962-11-27 |
| NL134445C (US07282526-20071016-C00003.png) | 1972-06-15 |
| NL240204A (US07282526-20071016-C00003.png) | 1959-06-15 |
| DE1148384B (de) | 1963-05-09 |
| BE579689A (US07282526-20071016-C00003.png) | 1959-12-15 |
| US3066126A (en) | 1962-11-27 |
| NL113827C (US07282526-20071016-C00003.png) | 1967-10-16 |
| NL6500176A (US07282526-20071016-C00003.png) | 1965-07-26 |
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