GB1391771A - Polymerisation process - Google Patents
Polymerisation processInfo
- Publication number
- GB1391771A GB1391771A GB294372A GB294372A GB1391771A GB 1391771 A GB1391771 A GB 1391771A GB 294372 A GB294372 A GB 294372A GB 294372 A GB294372 A GB 294372A GB 1391771 A GB1391771 A GB 1391771A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alumina
- silica
- titanium
- catalyst
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- -1 titanium alkoxide Chemical class 0.000 abstract 2
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 abstract 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 150000004761 hexafluorosilicates Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1391771 Polymerisation catalyst BP CHEMICALS INTERNATIONAL Ltd 13 March 1972 [26 Jan 1971 30 June 1971 (2) 23 Dec 1971] 3162/71 30621/71 30622/71 and 2943/72 Heading B1E [Also in Division C3] A catalyst for polymerizing ethylene or a mixture of ethylene and at least one other 1-olefin comprises chromium oxide supported on silica, alumina, zirconia or thoria or composites thereof (e.g. silica-alumina) which is activated by heating to 250 to 1200‹C in the presence of a tetravalent titanium alkoxide (e.g. titanium tetraisopropoxide or titanium tetraethoxide) and a salt in which the anion contains fluorine (e.g. ammonium tetrafluorborate or hexafluorosilicate) and preferably in the presence of air. Reference has been directed by the comptroller to Specification 927966.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB294372A GB1391771A (en) | 1971-01-26 | 1971-12-23 | Polymerisation process |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB316271 | 1971-01-26 | ||
GB3062271 | 1971-06-30 | ||
GB3062171 | 1971-06-30 | ||
GB294372A GB1391771A (en) | 1971-01-26 | 1971-12-23 | Polymerisation process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1391771A true GB1391771A (en) | 1975-04-23 |
Family
ID=27447258
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB294372A Expired GB1391771A (en) | 1971-01-26 | 1971-12-23 | Polymerisation process |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1391771A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2570381A1 (en) * | 1984-09-17 | 1986-03-21 | Bp Chimie Sa | PROCESS FOR THE POLYMERIZATION OF ETHYLENE OR OF THE COPOLYMERIZATION OF ETHYLENE AND ALPHA-OLEFIN IN A FLUIDIZED BED IN THE PRESENCE OF A CATALYST BASED ON CHROMIUM OXIDE |
US4596862A (en) * | 1984-12-24 | 1986-06-24 | Phillips Petroleum Company | Olefin polymerization using chromium on fluorided aluminophosphate |
US4727124A (en) * | 1986-05-30 | 1988-02-23 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of ethene by Phillips catalysis |
US4728703A (en) * | 1986-03-22 | 1988-03-01 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of ethene by Phillips catalysis |
-
1971
- 1971-12-23 GB GB294372A patent/GB1391771A/en not_active Expired
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2570381A1 (en) * | 1984-09-17 | 1986-03-21 | Bp Chimie Sa | PROCESS FOR THE POLYMERIZATION OF ETHYLENE OR OF THE COPOLYMERIZATION OF ETHYLENE AND ALPHA-OLEFIN IN A FLUIDIZED BED IN THE PRESENCE OF A CATALYST BASED ON CHROMIUM OXIDE |
EP0175532A1 (en) * | 1984-09-17 | 1986-03-26 | BP Chemicals Limited | Process for the polymerisation of ethylene or the copolymerisation of ethylene and alpha olefins in a fluidised bed in the presence of a chromium based catalyst |
US4910271A (en) * | 1984-09-17 | 1990-03-20 | Bp Chemicals Limited | Process for the polymerisation of ethylene or the copolymerisation of ethylene and alpha-olefins in a fluidised bed in the presence of a chromium based catalyst |
US5165998A (en) * | 1984-09-17 | 1992-11-24 | Bp Chemicals Limited | Prepolymers of olefins containing a chromiumoxide and a granular refractory oxide support |
USRE35324E (en) * | 1984-09-17 | 1996-09-03 | Bp Chemicals Limited | Prepolymers of olefins containing a chromium oxide and a granular refractory oxide support |
USRE35346E (en) * | 1984-09-17 | 1996-10-01 | Bp Chemicals Limited | Process for the polymerisation of ethylene or the copolymerisation of ethylene and alpha-olefins in a fluidised bed in the presence of a chromium based catalyst |
US4596862A (en) * | 1984-12-24 | 1986-06-24 | Phillips Petroleum Company | Olefin polymerization using chromium on fluorided aluminophosphate |
US4728703A (en) * | 1986-03-22 | 1988-03-01 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of ethene by Phillips catalysis |
US4727124A (en) * | 1986-05-30 | 1988-02-23 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of ethene by Phillips catalysis |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |