GB871525A - Polyhydroxyamino ethers and a process for their preparation - Google Patents
Polyhydroxyamino ethers and a process for their preparationInfo
- Publication number
- GB871525A GB871525A GB12537/58A GB1253758A GB871525A GB 871525 A GB871525 A GB 871525A GB 12537/58 A GB12537/58 A GB 12537/58A GB 1253758 A GB1253758 A GB 1253758A GB 871525 A GB871525 A GB 871525A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen
- amino
- cyh2y
- atoms
- polyhydric alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
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- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/12—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms
- C07D295/125—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/13—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
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- C10N2040/42—Flashing oils or marking oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/44—Super vacuum or supercritical use
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/50—Medical uses
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention comprises polyhydroxyamine ethers of formula: <FORM:0871525/IV (b)/1> where R is a hydroxyl-free residue of a hexitol, hexitan or a polyoxyalkylene derivative thereof, x is the number of hydroxyl groups in said polyhydric alcohol, n is 1-x, and each B is (a) -NHR1 (b) -NE-CyH2y-NE2 (c) -NECyH2y-NE-CyH2y-NE2 <FORM:0871525/IV (b)/2> , <FORM:0871525/IV (b)/3> , or <FORM:0871525/IV (b)/4> where R1 is hydrogen, alkyl, cycloalkyl, hydroxyalkyl or polyhydroxyalkyl, E is hydrogen or a hydroxyalkyl group having 2-4 carbon atoms, at least one E being hydrogen, and y is 2 or 3; and their preparation by condensing a suitable polyhydric alcohol with an epihalohydrin at 75-175 DEG C., reacting the condensation product with ammonia or a suitable reactive aliphatic amine containing not more than 3 amino nitrogen atoms and at least 2 amino hydrogen atoms, and liberating the resulting amino ether with an alkali. By "reactive amine" is meant one in which the carbon to which the amino nitrogen is attached carries at least one hydrogen atom. The first step may be carried out in the presence of "Lewis acid" catalysts or H2SO4 or p-toluene sulphonic acid; solvents may be used. Specified reactants are sorbitol, mannitol, dulcitol, 1,4-sorbitan, and their ethylene oxide and propylene oxide derivatives; monoalkylamines, cyclohexylamines, ethanolamine, propanolamine, 1-amino-2,3-dihydroxypropane, ethylene and propylene polyamines, N-aminoethylpiperazine, hydroxy-ethyldiethylene triamine and 3,31-imino-bis-propylamine.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US871525XA | 1957-04-23 | 1957-04-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB871525A true GB871525A (en) | 1961-06-28 |
Family
ID=22203410
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12537/58A Expired GB871525A (en) | 1957-04-23 | 1958-04-21 | Polyhydroxyamino ethers and a process for their preparation |
GB28496/60A Expired GB883861A (en) | 1957-04-23 | 1958-04-21 | Production of acylated polyhydroxyamino ethers |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB28496/60A Expired GB883861A (en) | 1957-04-23 | 1958-04-21 | Production of acylated polyhydroxyamino ethers |
Country Status (1)
Country | Link |
---|---|
GB (2) | GB871525A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4280915A (en) * | 1977-06-23 | 1981-07-28 | Nl Industries, Inc. | Salt stable lubricant for water base drilling fluids |
EP1408101A1 (en) * | 2002-10-04 | 2004-04-14 | Infineum International Limited | Additives and fuel oil compositions |
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1958
- 1958-04-21 GB GB12537/58A patent/GB871525A/en not_active Expired
- 1958-04-21 GB GB28496/60A patent/GB883861A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB883861A (en) | 1961-12-06 |
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