GB849220A - New organic compounds of tin and a process for their manufacture - Google Patents
New organic compounds of tin and a process for their manufactureInfo
- Publication number
- GB849220A GB849220A GB39712/56A GB3971256A GB849220A GB 849220 A GB849220 A GB 849220A GB 39712/56 A GB39712/56 A GB 39712/56A GB 3971256 A GB3971256 A GB 3971256A GB 849220 A GB849220 A GB 849220A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- compounds
- tin
- organotin
- aliphatic radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 150000002894 organic compounds Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- -1 alkali metal salts Chemical class 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 abstract 2
- 229920000151 polyglycol Polymers 0.000 abstract 2
- 239000010695 polyglycol Substances 0.000 abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001413 amino acids Chemical class 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000001261 hydroxy acids Chemical class 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 abstract 1
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2224—Compounds having one or more tin-oxygen linkages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/08—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
- C10M2227/083—Sn compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Polyvinyl chloride compositions are stabilised by compounds of formula: <FORM:0849220/IV(a)/1> where R1 is a C1-C6 aliphatic radical or the cyclohexyl group, R11 is a C1-C6 aliphatic radical or the phenylene group, x is 1, 2 or 3 and Z represents a polyglycol chain of formula (CH2-CH2-O)n-CH2-CH2-OH linked to R11 by an oxygen, sulphur or nitrogen atom, n being a number from 1 to 49. Typical compounds are tributyl tin-salicylo-polyglycollic ether: <FORM:0849220/IV(a)/2> tributyl tin -o-di-polyglycollamino-benzoate <FORM:0849220/IV(a)/3> and tributyl tin-polyglycol-thioglycollate <FORM:0849220/IV(a)/4>ALSO:The invention comprises compounds of formula: <FORM:0849220/IV(b)/1> where R1 is a C2-C6 aliphatic radical or the cyclohexyl group R11 is a C2-C6 aliphatic radica or the phenylene group, x is 1, 2 or 3 and Z represents a polyglycol chain of formula (CH2-CH2-O)n-CH2-CH2-OH linked to R" by an oxygen, sulphur or nitrogen atom, n being a number from 1 to 49. They may be prepared by reacting a compound of formula: <FORM:0849220/IV(b)/2> where R1, R11, and x have the meanings above and Y is -OH, -NH2-SH,-COOH,-CONH2-SO2 NH2 or -CO,CH2,CO-, with up to 50 mols of ethylene oxide per mol of organotin compound preferably in the presence of catalysts such as sodium alcoholate, sodium or potassium hydroxide or tin tetrachloride. The organotin starting material may be prepared by reacting organotin halides with alkali metal salts of hydroxy acids, amino acids, mercapto acids, etc. The compounds of the invention may be used as fungicides or bactericides, as lubricant antioxidants and stabilisers for polyvinyl chloride compositions (see Group IV(a)).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1955F0019204 DE1072814C2 (en) | 1955-12-31 | 1955-12-31 | Process for the production of higher molecular weight, low metal organotin compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB849220A true GB849220A (en) | 1960-09-21 |
Family
ID=37433688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB39712/56A Expired GB849220A (en) | 1955-12-31 | 1956-12-31 | New organic compounds of tin and a process for their manufacture |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE553869A (en) |
| DE (1) | DE1072814C2 (en) |
| GB (1) | GB849220A (en) |
| NL (1) | NL96664C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3031483A (en) * | 1957-11-18 | 1962-04-24 | Philips Corp | Method of producing organic tin compounds and preparations containing such compoundsfor combating noxious micro-organisms |
| DE1288232B (en) * | 1963-12-14 | 1969-01-30 | Solvay Werke Gmbh | Preservatives for skins or pelts |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE694178C (en) * | 1930-11-30 | 1940-07-27 | I G Farbenindustrie Akt Ges | Process for the preparation of condensation products which are soluble or easily dispersible in water |
| BE445580A (en) * | 1941-05-20 | |||
| US2648650A (en) * | 1951-06-21 | 1953-08-11 | Metal & Thermit Corp | Organo tin compounds and compositions containing same |
| US2641596A (en) * | 1952-02-07 | 1953-06-09 | Argus Chemical Lab Inc | Organic derivatives of tetravalent tin |
-
0
- NL NL96664D patent/NL96664C/xx active
- BE BE553869D patent/BE553869A/xx unknown
-
1955
- 1955-12-31 DE DE1955F0019204 patent/DE1072814C2/en not_active Expired
-
1956
- 1956-12-31 GB GB39712/56A patent/GB849220A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL96664C (en) | 1900-01-01 |
| BE553869A (en) | 1900-01-01 |
| DE1072814B (en) | 1960-01-07 |
| DE1072814C2 (en) | 1960-06-30 |
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