ES348007A1 - Thio-phosphoric (-phosphonic) and dithiophosphoric (-phosphonic) acid esters - Google Patents
Thio-phosphoric (-phosphonic) and dithiophosphoric (-phosphonic) acid estersInfo
- Publication number
- ES348007A1 ES348007A1 ES348007A ES348007A ES348007A1 ES 348007 A1 ES348007 A1 ES 348007A1 ES 348007 A ES348007 A ES 348007A ES 348007 A ES348007 A ES 348007A ES 348007 A1 ES348007 A1 ES 348007A1
- Authority
- ES
- Spain
- Prior art keywords
- alkyl
- phosphonic
- hal
- alkoxy
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title 1
- -1 C 1 -C 6 alkyl Chemical group 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical group 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 150000007530 organic bases Chemical group 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000003852 triazoles Chemical class 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
- A01N57/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34 containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
- C07F9/6518—Five-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention comprises compounds of general formula in which R 1 is straight or branched C 1 -C 6 alkyl or alkoxy or phenyl, R 2 is C 1 -C 6 alkyl, R 3 is H or C 1 -C 6 alkyl, R 4 is H or C 1 -C 6 alkyl or phenyl which may be substituted by halogen, nitro, C 1 -C 6 alkyl, alkoxy or alkylmercapto radicals, and X is oxygen or sulphur. They are prepared by reacting a halide of formula (R 1 )(R 2 O)P(X)Hal, wherein Hal is halogen, with an alkali metal salt or ammonium salt of a triazole derivative of general formula or with the free mercapto compound itself in the presence of an acid-binding agent such as an alkali metal hydroxide, carbonate or alcoholate or a tertiary organic base. The reaction is usually carried out in an inert solvent at a temperature between 20 to 80 C. The compounds have insecticidal properties.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0050874 | 1966-12-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES348007A1 true ES348007A1 (en) | 1969-03-01 |
Family
ID=7104143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES348007A Expired ES348007A1 (en) | 1966-12-08 | 1967-12-06 | Thio-phosphoric (-phosphonic) and dithiophosphoric (-phosphonic) acid esters |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE707499A (en) |
| CH (1) | CH488739A (en) |
| DE (1) | DE1670776A1 (en) |
| ES (1) | ES348007A1 (en) |
| FR (1) | FR1549674A (en) |
| GB (1) | GB1149159A (en) |
| NL (1) | NL6716035A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2150169A1 (en) * | 1970-10-22 | 1972-04-27 | Agripat Sa | New esters |
| US4082762A (en) * | 1975-08-25 | 1978-04-04 | Eli Lilly And Company | 4-(2-halophenyl)-1,2,4-triazole-3-thiol compounds |
-
1966
- 1966-12-08 DE DE19661670776 patent/DE1670776A1/en active Pending
-
1967
- 1967-10-31 CH CH1523267A patent/CH488739A/en not_active IP Right Cessation
- 1967-11-16 GB GB52161/67A patent/GB1149159A/en not_active Expired
- 1967-11-24 NL NL6716035A patent/NL6716035A/xx unknown
- 1967-12-04 BE BE707499D patent/BE707499A/xx unknown
- 1967-12-06 ES ES348007A patent/ES348007A1/en not_active Expired
- 1967-12-08 FR FR1549674D patent/FR1549674A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE707499A (en) | 1968-06-04 |
| GB1149159A (en) | 1969-04-16 |
| CH488739A (en) | 1970-04-15 |
| DE1670776A1 (en) | 1970-12-23 |
| FR1549674A (en) | 1968-12-13 |
| NL6716035A (en) | 1968-06-10 |
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