GB825805A - Improvements in or relating to metal soap driers suitable for use in coating compositions: and compositions containing such driers - Google Patents
Improvements in or relating to metal soap driers suitable for use in coating compositions: and compositions containing such driersInfo
- Publication number
- GB825805A GB825805A GB3461557A GB3461557A GB825805A GB 825805 A GB825805 A GB 825805A GB 3461557 A GB3461557 A GB 3461557A GB 3461557 A GB3461557 A GB 3461557A GB 825805 A GB825805 A GB 825805A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acids
- koch
- drying
- soaps
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; DRIERS (SICCATIVES); TURPENTINE
- C09F9/00—Compounds to be used as driers (siccatives)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
Abstract
Driers for use in surface coating compositions comprise the drying metal soaps of a mixture of petroleum naphthenic acids and one or more acids produced by the Koch process, i.e. by reacting olefines containing at least 4 carbon atoms with carbon monoxide or formic acid in the substantial absence of added water and in the presence of a concentrated acid as catalyst and thereafter reacting the resulting reaction mixture with water (see Specifications 743,597 and 798,065), [both in Group IV (b)]. The process may be operated at low temperatures (e.g. 30-40 DEG C.) and relatively low pressures (e.g. 30 atmos). Drying metals specified are cobalt, lead, iron, nickel, manganese, zinc, calcium and barium. The naphthenic acids preferably have an acid value below 200, and the preferred Koch acids are the C8-12 acids. The soaps may be prepared from the free acids by direct reaction with a suitable drying metal compound (e.g. an hydroxide, oxide or carbonate) or by a double decomposition process using e.g. an alkali metal salt of the Koch acid(s)/naphthenic acids mixture and a water-soluble salt of the drying metal(s) at elevated temperatures. The soaps may be extracted into a non-aqueous phase (e.g. white spirit).ALSO:The invention comprises the drying metal soaps of a mixture of petroleum naphthenic acids and one or more acids produced by the Koch process, i.e. by reacting olefines containing at least 4 carbon atoms with carbon monoxide or formic acid in the substantial absence of added water and in the presence of a concentrated acid as catalyst and thereafter reacting the resulting reaction mixture with water (see Specifications 743,597 and 798,065). The process may be operated at low temperatures (e.g. 30-40 DEG C.) and relatively low pressures (e.g. 30 atmos.). Drying metals specified are cobalt, lead, iron, nickel, manganese, zinc, calcium and barium. The naphthenic acids preferably have an acid value below 200, and the preferred Koch acids are the C8-12 acids. The soaps may be prepared from the free acids by direct reaction with a suitable drying metal compound (e.g. a hydroxide, oxide or carbonate) or by a double decomposition process using, e.g., an alkali metal salt of the Koch acid(s)/naphthenic acids mixture and a water-soluble salt of the drying metal(s) at elevated temperatures. The soaps may be extracted into a non-aqueous phase (e.g. white spirit).ALSO:Driers for surface coating compositions based on synthetic resins such as alkyd resins and "Epikote" (Registered Trade Mark) resins comprise the drying metal soaps of a mixture of petroleum naphthenic acids and one or more acids produced by the Koch process, i.e. by reacting olefines containing at least 4 carbon atoms with carbon monoxide or formic acid in the substantial absence of added water and in the presence of a concentrated acid as catalyst and thereafter reacting the resulting reaction mixture with water [see Specifications 743,597 and 798,065, [both in Group IV (b)]]. The process may be operated at low temperatures (e.g. 30-40 DEG C.) and relatively low pressures (e.g. 30 atmos.). Drying metals specified are cobalt, lead, iron, nickel, manganese, zinc, calcium and barium. The naphthenic acids preferably have an acid value below 200, and the preferred Koch acids are the C8-12 acids.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE572734D BE572734A (en) | 1957-11-06 | ||
GB3461557A GB825805A (en) | 1957-11-06 | 1957-11-06 | Improvements in or relating to metal soap driers suitable for use in coating compositions: and compositions containing such driers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3461557A GB825805A (en) | 1957-11-06 | 1957-11-06 | Improvements in or relating to metal soap driers suitable for use in coating compositions: and compositions containing such driers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB825805A true GB825805A (en) | 1959-12-23 |
Family
ID=10367856
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3461557A Expired GB825805A (en) | 1957-11-06 | 1957-11-06 | Improvements in or relating to metal soap driers suitable for use in coating compositions: and compositions containing such driers |
Country Status (2)
Country | Link |
---|---|
BE (1) | BE572734A (en) |
GB (1) | GB825805A (en) |
-
0
- BE BE572734D patent/BE572734A/xx unknown
-
1957
- 1957-11-06 GB GB3461557A patent/GB825805A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BE572734A (en) |
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