GB772491A - Improvements in and relating to insulating oils - Google Patents

Improvements in and relating to insulating oils

Info

Publication number
GB772491A
GB772491A GB9328/54A GB932854A GB772491A GB 772491 A GB772491 A GB 772491A GB 9328/54 A GB9328/54 A GB 9328/54A GB 932854 A GB932854 A GB 932854A GB 772491 A GB772491 A GB 772491A
Authority
GB
United Kingdom
Prior art keywords
naphthylamine
phenyl
oil
contain
mineral oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9328/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JAMES CAMPBELL WOOD MALLOCK
Manchester Oil Refinery Ltd
Original Assignee
JAMES CAMPBELL WOOD MALLOCK
Manchester Oil Refinery Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JAMES CAMPBELL WOOD MALLOCK, Manchester Oil Refinery Ltd filed Critical JAMES CAMPBELL WOOD MALLOCK
Publication of GB772491A publication Critical patent/GB772491A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/20—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils
    • H01B3/22—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/066—Arylene diamines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/16—Dielectric; Insulating oil or insulators
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/17—Electric or magnetic purposes for electric contacts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Lubricants (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Organic Insulating Materials (AREA)

Abstract

An insulating oil, such as a transformer oil, having a reduced tendency to oxidize, comprises a mineral base oil having incorporated therein (1) a metal deactivator which is an aromatic amine of the formula <FORM:0772491/III/1> wherein R1, R2, R3 and R4 are simila or dissimilar, are selected from H and alkyl radicles containing up to 12 carbon atoms and together do not contain more than 24 carbon atoms, and X is NH2 of COOH and (2) an antioxidant which is phenyl a - or b - naphthylamine. Suitable aromatic amines are o - phenylene diamine, anthranilic acid and their nuclear-substituted alkyl derivatives. In the examples, insulating oils are described which contain mineral oil, phenyl b - naphthylamine and o-phenylene diamine or anthranilic acid. For comparison purposes, insulating oils are described which contain mineral oil and phenyl b - naphthylamine or anthanilic acid only, or mineral oil, phenyl b - naphthylamine and one of disalicylal propylene diamine (added in toluene solution), di - salicylal ethylene diamine and zinc hexyl dithiophosphate.
GB9328/54A 1954-03-30 1954-03-30 Improvements in and relating to insulating oils Expired GB772491A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB337889X 1954-03-30

Publications (1)

Publication Number Publication Date
GB772491A true GB772491A (en) 1957-04-17

Family

ID=10357445

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9328/54A Expired GB772491A (en) 1954-03-30 1954-03-30 Improvements in and relating to insulating oils

Country Status (5)

Country Link
US (1) US2868730A (en)
CH (1) CH337889A (en)
DE (1) DE961917C (en)
GB (1) GB772491A (en)
NL (1) NL99014C (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3094583A (en) * 1959-03-24 1963-06-18 Anaconda Wire And Cabie Compan High voltage electric power cables
US3146201A (en) * 1960-07-22 1964-08-25 Lubrizol Corp Lubricant composition
US3282961A (en) * 1963-04-11 1966-11-01 Du Pont Sulfonium methylide compounds
US3446741A (en) * 1963-11-14 1969-05-27 Minnesota Mining & Mfg Insulating device,composition,and method
US3321854A (en) * 1964-06-12 1967-05-30 Faul Karl Indicator
US3513578A (en) * 1968-06-26 1970-05-26 Shaw & Slavsky Inc Price indicator
CN113454192B (en) 2019-03-05 2023-05-12 陶氏环球技术有限责任公司 Polyalkylene glycol lubricant compositions

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1973676A (en) * 1931-12-21 1934-09-11 Standard Oil Co Color-stabilized mineral oil
US1988299A (en) * 1932-04-23 1935-01-15 Gen Electric Oil for transformers and the like
US2354252A (en) * 1941-02-11 1944-07-25 Internat Lubricant Corp Lubricating composition
NL56251C (en) * 1941-03-15
US2369090A (en) * 1941-12-17 1945-02-06 Gulf Research Development Co Insulating oil compositions
US2573779A (en) * 1944-04-10 1951-11-06 Shell Dev Color stabilizers
US2451642A (en) * 1944-10-23 1948-10-19 Standard Oil Co Viscous mineral oil compositions
US2530650A (en) * 1947-04-16 1950-11-21 Universal Oil Prod Co Metal deactivator

Also Published As

Publication number Publication date
US2868730A (en) 1959-01-13
CH337889A (en) 1959-04-30
DE961917C (en) 1957-04-11
NL99014C (en)

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