GB757351A - Improved method of production of stable resin emulsions of low viscosity - Google Patents
Improved method of production of stable resin emulsions of low viscosityInfo
- Publication number
- GB757351A GB757351A GB32631/53A GB3263153A GB757351A GB 757351 A GB757351 A GB 757351A GB 32631/53 A GB32631/53 A GB 32631/53A GB 3263153 A GB3263153 A GB 3263153A GB 757351 A GB757351 A GB 757351A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oils
- water
- resins
- mills
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011347 resin Substances 0.000 title abstract 9
- 229920005989 resin Polymers 0.000 title abstract 9
- 239000000839 emulsion Substances 0.000 title abstract 5
- 239000003921 oil Substances 0.000 abstract 10
- 235000019198 oils Nutrition 0.000 abstract 10
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract 8
- 239000003973 paint Substances 0.000 abstract 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 8
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 6
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 6
- 238000001035 drying Methods 0.000 abstract 6
- 229920000058 polyacrylate Polymers 0.000 abstract 6
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 4
- 239000000084 colloidal system Substances 0.000 abstract 4
- 239000002270 dispersing agent Substances 0.000 abstract 4
- -1 ester modified phenolic resin Chemical class 0.000 abstract 4
- 239000004014 plasticizer Substances 0.000 abstract 4
- 230000001681 protective effect Effects 0.000 abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 abstract 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 3
- 239000004141 Sodium laurylsulphate Substances 0.000 abstract 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 abstract 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 3
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 3
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 abstract 3
- 239000004606 Fillers/Extenders Substances 0.000 abstract 2
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 2
- 239000010775 animal oil Substances 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 239000005018 casein Substances 0.000 abstract 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 2
- 235000021240 caseins Nutrition 0.000 abstract 2
- 239000004359 castor oil Substances 0.000 abstract 2
- 235000019438 castor oil Nutrition 0.000 abstract 2
- 229920003086 cellulose ether Polymers 0.000 abstract 2
- 239000003292 glue Substances 0.000 abstract 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 2
- 239000000944 linseed oil Substances 0.000 abstract 2
- 235000021388 linseed oil Nutrition 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000012986 modification Methods 0.000 abstract 2
- 230000004048 modification Effects 0.000 abstract 2
- 239000000025 natural resin Substances 0.000 abstract 2
- 239000003208 petroleum Substances 0.000 abstract 2
- 239000000049 pigment Substances 0.000 abstract 2
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 2
- 239000000344 soap Substances 0.000 abstract 2
- 235000012424 soybean oil Nutrition 0.000 abstract 2
- 239000002383 tung oil Substances 0.000 abstract 2
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 abstract 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Resins, used in making emulsion paints, are dispersed by grinding with water in normal paint machinery, such as pebble mills, ball mills, roller mills and bar mills, with a suitable dispersing agent and are then converted to emulsions by addition of appropriate plasticizers and protective colloids. Resins includes natural resins, run and unrun, rosin and its esters, adducts and modifications, cumarone indene resins and rosin ester modified phenolic resin. Suitable dispersing agents are soaps, sulphated and sulphonated oils, alkyl-aryl sulphonates and mixtures of these, sodium lauryl sulphate, triethanolamine and ammonium polyacrylate. Plasticizers include dibutyl phthalate, tricresyl phosphate, dioctyl sebacate, treated or untreated drying oils such as tung oil, linseed oil, marine animal oils, semi-drying oils such as soya oil and non-drying oils such as castor oil and petroleum oils. Protective colloids include glue, casein, cellulose ethers and polyacrylates. Pigments and extenders normally used in the paint industry may be added in the grinding step. In examples: (1) a rosin ester is ground with water and sodium lauryl sulphate and mixed with tricresyl phosphate and sodium polyacrylate; (2) cumarone indene resin is ground with water and triethanolamine and dioctylsebacate and carboxymethyl cellulose solution added; (3) a resin ester modified phenol resin, rutile (titanium dioxide), barytes and a solution of ammonium polyacrylate are ground with water. Dibutyl phthalate polyvinyl alcohol and carboxymethyl cellulose are added and the paint adjusted to the desired consistency with water.ALSO:Resins, used in making emulsion paints, are dispersed by grinding with water in normal paint machinery, such as pebble mills, ball mills, roller mills and bar mills, with a suitable dispersing agent and are then converted to emulsions by addition of appropriate plasticizers and protective colloids. Resins includes natural resins, run and unrun, rosin and its esters adducts and modifications, cumarone indene resins and rosin ester modified phenolic resin. Suitable dispersing agents are soaps, sulphated and sulphonated oils, alkyl aryl sulphonates and mixtures of these, sodium lauryl sulphate, triethanolamine and ammonium polyacrylate. Plasticizers include dibutyl phthalate, tricresyl phosphate, dioctyl sebacate, treated or untreated drying oils such as tung oil, linseed oil, marine animal oils, semi-drying oils such as soya oil and non-drying oils such as castor oil and petroleum oils. Protective colloids include glue, casein, cellulose ethers and poly acrylates. Pigments and extenders normally used in the paint industry may be added in the grinding step. Thus a rosin ester modified phenolic resin, rutile and barytes are ground with water and ammonium polyacrylate solution in a ball mill for twenty four hours. Dibutyl phthalate and polyvinyl alcohol with carboxymethyl cellulose solutions are added and the paint adjusted to the desired consistency with water.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB32631/53A GB757351A (en) | 1953-11-24 | 1953-11-24 | Improved method of production of stable resin emulsions of low viscosity |
| BE533562A BE533562A (en) | 1953-11-24 | 1954-11-23 | Improved process for the preparation of stable, low viscosity emulsions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB32631/53A GB757351A (en) | 1953-11-24 | 1953-11-24 | Improved method of production of stable resin emulsions of low viscosity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB757351A true GB757351A (en) | 1956-09-19 |
Family
ID=10341641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB32631/53A Expired GB757351A (en) | 1953-11-24 | 1953-11-24 | Improved method of production of stable resin emulsions of low viscosity |
Country Status (2)
| Country | Link |
|---|---|
| BE (1) | BE533562A (en) |
| GB (1) | GB757351A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2406097A (en) * | 2003-09-18 | 2005-03-23 | Natural Building Technologies | A water-based polymer coating composition |
-
1953
- 1953-11-24 GB GB32631/53A patent/GB757351A/en not_active Expired
-
1954
- 1954-11-23 BE BE533562A patent/BE533562A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2406097A (en) * | 2003-09-18 | 2005-03-23 | Natural Building Technologies | A water-based polymer coating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| BE533562A (en) | 1954-12-15 |
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