GB727467A - Improvements in or relating to capillary active compositions containing sodium alkylsulphates or alkylated aryl sulphonates - Google Patents

Improvements in or relating to capillary active compositions containing sodium alkylsulphates or alkylated aryl sulphonates

Info

Publication number
GB727467A
GB727467A GB1886851A GB1886851A GB727467A GB 727467 A GB727467 A GB 727467A GB 1886851 A GB1886851 A GB 1886851A GB 1886851 A GB1886851 A GB 1886851A GB 727467 A GB727467 A GB 727467A
Authority
GB
United Kingdom
Prior art keywords
sodium
alkyl
active material
clear
sulphate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1886851A
Inventor
Philip James Garner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Refining and Marketing Co Ltd
Original Assignee
Shell Refining and Marketing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Refining and Marketing Co Ltd filed Critical Shell Refining and Marketing Co Ltd
Priority to GB1886851A priority Critical patent/GB727467A/en
Publication of GB727467A publication Critical patent/GB727467A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2041Dihydric alcohols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Liquid capillary active compositions which remain clear at a temperature between -10 DEG C. and +10 DEG C. comprise an aqueous solution containing a sodium alkyl sulphate or a sodium alkyl aryl sulphonate and not more than 25 per cent by weight, based on the "active material" present in the composition, of a hydroxyl compound containing 5 to 12 carbon atoms in the molecule and which is either an aliphatic compound containing two free vicinal hydroxyl groups or an aromatic compound containing two free vicinal hydroxyl groups in the aromatic nucleus, which hydroxyl compound is mutually soluble in water at a temperature between -10 DEG C. and +10 DEG C. in conjunction with the other components of the composition. The sodium alkyl sulphates and alkyl aryl sulphonates may be used in conjunction with potassium or ammonium alkyl sulphates or alkyl aryl sulphonates and the total alkyl sulphate or alkyl aryl sulphonate present is referred to above as the "active material." Cations other than sodium may also be present to improve the stability of the surface-active solution. The aliphatic and aromatic hydroxy compounds may be utilized in aqueous solution containing 3 to 65 per cent of active material and inorganic salts usually sodium sulphate. Reference is made to stabilizing solutions containing 21 to 45 per cent active material, by replacing 5 to 10 per cent of the active material by hydroxyl compound. In examples: (1) solutions containing C8-18 sec.-alkyl sodium sulphates and sodium sulphate have their clear-point of 14.5 DEG C. reduced to 10 DEG C. or lower by means of the diols pentane diol-1 : 2 to octanediol-1 : 2 inclusive, decanediol- 1 : 2, undecanediol-1 : 2 or mono-sec.-butyl glyceryl ether; (2) similar solutions containing also potassium C8-18 sec.-alkyl sulphates of clear points from -1 DEG C. to 11.25 DEG C. have these clear points reduced to from -15 DEG C. to +5 DEG C. respectively by additions of hydroxyl compounds which include in addition to some of the above, catechol and n-butyl, n-octyl and n-iso-nonyl mono-glyceryl ethers; (3) a solution as in (1) containing also ammonium sulphate has its clear point reduced from 2.5 DEG C. to 1 DEG C. by means of undecane 1 : 2-diol. According to the Provisional Specification, the aqueous solutions of sodium alkyl sulphates or alkyl aryl sulphonates are caused to remain clear at low temperature by addition of any compound having two vicinal hydroxy groups, no upper limit of proportion being stated, and cycloaliphatic compounds of this type and styrene glycol are referred to. Specifications 629,139, [Group III], and 646,827, [Group IV (b)], are referred to.ALSO:Liquid capillary active compositions which remain clear at a temperature between -10 DEG and +10 DEG C. comprise an aqueous solution containing a sodium alkyl sulphate or a sodium alkyl aryl sulphonate and not more than 25 per cent by weight, based on the "active material" present in the composition, of a hydroxyl compound containing 5 to 12 carbon atoms in the molecule and which is either an aliphatic compound containing two free vicinal hydroxyl groups or an aromatic compound containing two free vicinal hydroxyl groups in the aromatic nucleus, which hydroxyl compound is mutually soluble in water at a temperature between -10 DEG C. and +10 DEG C. in conjunction with the other components of the composition. The sodium alkyl sulphates and alkyl aryl sulphonates may be used in conjunction with potassium or ammonium alkyl sulphates or alkyl aryl sulphonates and the total alkyl sulphate or alkyl aryl sulphonate present is referred to above as the "active material." Cations other than sodium may also be present to improve the stability of the surface-active solution. The aliphatic and aromatic hydroxy compounds may be utilized in aqueous solution containing 3 to 65 per cent of active material, and inorganic salts usually sodium sulphate. Reference is made to stabilizing solutions containing 21 to 45 per cent active material by replacing 5 to 10 per cent of the active material by hydroxyl compound. In examples: (1) solutions containing C8-18 sec.-alkyl sodium sulphates and sodium sulphate have their clear-point of 14.5 DEG C. reduced to 10 DEG C. or lower by means of the diols pentanediol-1 : 2 to octanediol-1 : 2 inclusive, decanediol-1 : 2, undecanediol-1 : 2 or mono-sec.-butyl glyceryl ether; (2) similar solutions containing also potassium C8-18 sec.-alkyl sulphates of clear points from -1 DEG C to 11.25 DEG C. have these clear points reduced to from -15 DEG C. to +5 DEG C. respectively, by additions of hydroxyl compounds which include in addition to some of the above, catechol and n-butyl, n-octyl and n-iso-nonyl mono-glyceryl ethers; (3) a solution as in (1) containing also ammonium sulphate has its clear point reduced from 2.5 DEG to 1 DEG C. by means of undecane 1 : 2-diol. According to the Provisional Specification, the aqueous solutions of sodium alkyl sulphates or alkyl aryl sulphonates are caused to remain clear at low temperature by addition of any compound having two vicinal hydroxy groups, no upper limit of proportion being stated, and cycloaliphatic compounds of this type and styrene glycol are referred to. Specifications 629,139, [Group III], and 646,827 are referred to.ALSO:Liquid cleansing compositions which remain clear at a temperature between -10 DEG C. and + 10 DEG C. comprise an aqueous solution containing a sodium alkyl sulphate or a sodium alkyl aryl sulphonate and not more than 25 per cent by weight, based on the "active material" present in the composition, of a hydroxyl compound containing 5 to 12 carbon atoms in the molecule and which is either an aliphatic compound containing two free vicinal hydroxyl groups or an aromatic compound containing two free vicinal hydroxyl groups in the aromatic nucleus, which hydroxyl compound is mutually soluble in water at a temperature between -10 DEG C. and + 10 DEG C. in conjunction with the other components of the composition. The sodium alkyl sulphates and alkyl aryl sulphonates may be used in conjunction with potassium or ammonium alkyl sulphates or alkyl aryl sulphonates and the total alkyl sulphate or alkyl aryl sulphonate present is referred to above as the "active material." Cations other than sodium may also be present to improve the stability of the surface-active solution. The aliphatic and aromatic hydroxy compounds may be utilized in aqueous solution containing 3 to 65 per cent of active material, and inorganic salts usually sodium sulphate. Reference is made to stabilizing solutions containing 21 to 45 per cent active material by replacing 5 to 10 per cent of the active material by hydroxyl compound. In Examples: (1) solutions containing C8-18 sec. alkyl sodium sulphates and sodium sulphate have their clear-point of 14.5 DEG C. reduced to 10 DEG C. or lower by means of the diols, pentane diol-1 : 2 to octanediol-1 : 2 inclusive, decanediol-1 : 2, undecanediol-1 : 2 or mono -sec.-butyl glyceryl ether; (2) similar solutions containing also potassium C8-18 sec.-alkyl sulphates of clear points from-1 DEG C. to 11.25 DEG C. have these clear points reduced to from -15 DEG C. to +5 DEG C. respectively by additions of hydroxyl compounds which include in addition to some of the above, catechol and n-butyl, n-octyl and n-iso-nonyl mono glyceryl ethers; (3) a solution as in (1) containing also ammonium sulphate has its clear point reduced from 2.5 DEG C. to 1 DEG C. by means of undecane 1 : 2-diol. According to the Provisional Specification, the aqueous solutions of sodium alkyl sulphates or alkyl aryl sulphonates are caused to remain clear at low temperature by addition of any compound having two vicinal hydroxy groups, no upper limit of proportion being stated, and cycloaliphatic compounds of this type and styrene glycol are referred to. Specifications 629,139 and 646,827, [Group IV (b)], are referred to.
GB1886851A 1951-08-10 1951-08-10 Improvements in or relating to capillary active compositions containing sodium alkylsulphates or alkylated aryl sulphonates Expired GB727467A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1886851A GB727467A (en) 1951-08-10 1951-08-10 Improvements in or relating to capillary active compositions containing sodium alkylsulphates or alkylated aryl sulphonates

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1886851A GB727467A (en) 1951-08-10 1951-08-10 Improvements in or relating to capillary active compositions containing sodium alkylsulphates or alkylated aryl sulphonates

Publications (1)

Publication Number Publication Date
GB727467A true GB727467A (en) 1955-04-06

Family

ID=10119798

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1886851A Expired GB727467A (en) 1951-08-10 1951-08-10 Improvements in or relating to capillary active compositions containing sodium alkylsulphates or alkylated aryl sulphonates

Country Status (1)

Country Link
GB (1) GB727467A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2900346A (en) * 1956-02-20 1959-08-18 Shell Dev Foaming detergent compositions
US2933451A (en) * 1955-09-16 1960-04-19 Shell Oil Co Process for producing a detergent mixture
US3000832A (en) * 1955-09-16 1961-09-19 Shell Oil Co Detergent compositions

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2933451A (en) * 1955-09-16 1960-04-19 Shell Oil Co Process for producing a detergent mixture
US3000832A (en) * 1955-09-16 1961-09-19 Shell Oil Co Detergent compositions
US2900346A (en) * 1956-02-20 1959-08-18 Shell Dev Foaming detergent compositions

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