GB708823A - Contact mass for use in the preparation of organo halogenosilanes - Google Patents

Contact mass for use in the preparation of organo halogenosilanes

Info

Publication number
GB708823A
GB708823A GB11861/51A GB1186151A GB708823A GB 708823 A GB708823 A GB 708823A GB 11861/51 A GB11861/51 A GB 11861/51A GB 1186151 A GB1186151 A GB 1186151A GB 708823 A GB708823 A GB 708823A
Authority
GB
United Kingdom
Prior art keywords
calcium
silicon
copper
mass
titanium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11861/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB708823A publication Critical patent/GB708823A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/12Organo silicon halides
    • C07F7/16Preparation thereof from silicon and halogenated hydrocarbons direct synthesis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)

Abstract

Alkyl- or aryl-halogenosilanes are prepared by heating silicon in the presence of copper and calcium, magnesium, beryllium, strontium, barium, germanium, titanium, zirconium or cerium, or p any mixture of these metals, with an alkyl or aryl halide. The reaction gives rise mainly to the mono- and di-alkyl- or aryl-halogenosilanes. The silicon, copper and other metal may be employed in the form of an alloy. The calcium and silicon may be present as calcium silicide. In an example, methyl chloride is passed over a heated mass containing silicon, copper and calcium or titanium to form methyltrichloro- and dimethyldichloro-silane as the main products, and a minor amount of trimethylchlorosilane.ALSO:A contact mass, for reaction by heating with an alkyl or aryl halide to prepare alkyl or aryl halogenosilanes, contains silicon, copper and calcium, magnesium, beryllium, strontium, barium, germanium, titanium. zirconium or cerium or any mixture of these metals, e.g. in the form of an alloy. The calcium and silicon may be present as calcium silicide. The calcium, magnesium, beryllium, strontium, barium, germanium, titanium, zirconium or cerium or any mixture of these metals may be present in a proportion of 1 to 5 per cent. based on the total weight of mass. Preferably, the mass contains silicon, copper and calcium or silicon, copper and titanium. The mass may be prepared by fusing silicon with the metal other than copper, pulverizing the resulting mass and mixing it with copper preferably in the form of a powder and, if desired, a compound volatile at high temperatures such as an ammonium salt, and the powder thus obtained is wetted, moulded and heated in an atmosphere of oxygen free hydrogen. In an example, commercial silicon is fused with 3 per cent. of calcium silicide (containing 33 per cent. calcium) and with 5 per cent. titanium, the proportions being based on the total weight of the mass, the resulting alloys are pulverized and 90 parts of each of the powders are mixed with 10 parts each of copper powder and ammonium bicarbonate. The mixtures thus obtained are wetted, moulded, heated and sintered in a atmosphere of oxygen free hydrogen.
GB11861/51A 1950-05-19 1951-05-21 Contact mass for use in the preparation of organo halogenosilanes Expired GB708823A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE708823X 1950-05-19

Publications (1)

Publication Number Publication Date
GB708823A true GB708823A (en) 1954-05-12

Family

ID=6617699

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11861/51A Expired GB708823A (en) 1950-05-19 1951-05-21 Contact mass for use in the preparation of organo halogenosilanes

Country Status (1)

Country Link
GB (1) GB708823A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2877254A (en) * 1954-09-25 1959-03-10 Wacker Chemie Gmbh Process for preparing organohalosilanes
US2887501A (en) * 1956-12-26 1959-05-19 Gen Electric Preparation of higher alkylated alkyl halogenosilanes
US2888476A (en) * 1956-08-01 1959-05-26 Du Pont Preparation of long-chain alkylhalosilanes
US2888477A (en) * 1952-11-21 1959-05-26 Onera (Off Nat Aerospatiale) Methods of preparing synthetic organo silicon bromides
US2903473A (en) * 1954-03-19 1959-09-08 Takami Yasuo Process for the production of phenylchlorosilanes
US3155698A (en) * 1961-06-22 1964-11-03 Wacker Chemie Gmbh Method of preparing alkyl shlanes
FR2577929A1 (en) * 1985-02-22 1986-08-29 Rhone Poulenc Spec Chim METHOD AND CATALYST WITH BARIUM AND / OR STRONTIUM AS ADDITIVE FOR THE DIRECT SYNTHESIS OF DIMETHYLDICHLOROSILANE
FR2577930A1 (en) * 1985-02-22 1986-08-29 Rhone Poulenc Spec Chim PROCESS AND CATALYST WITH AN ALKALINE-EARTH METAL SELECTED AS ADDITIVE AMONG CALCIUM, MAGNESIUM AND BERYLLIUM FOR THE DIRECT SYNTHESIS OF DIMETHYLDICHLOROSILANE

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2888477A (en) * 1952-11-21 1959-05-26 Onera (Off Nat Aerospatiale) Methods of preparing synthetic organo silicon bromides
US2903473A (en) * 1954-03-19 1959-09-08 Takami Yasuo Process for the production of phenylchlorosilanes
US2877254A (en) * 1954-09-25 1959-03-10 Wacker Chemie Gmbh Process for preparing organohalosilanes
US2888476A (en) * 1956-08-01 1959-05-26 Du Pont Preparation of long-chain alkylhalosilanes
US2887501A (en) * 1956-12-26 1959-05-19 Gen Electric Preparation of higher alkylated alkyl halogenosilanes
US3155698A (en) * 1961-06-22 1964-11-03 Wacker Chemie Gmbh Method of preparing alkyl shlanes
FR2577929A1 (en) * 1985-02-22 1986-08-29 Rhone Poulenc Spec Chim METHOD AND CATALYST WITH BARIUM AND / OR STRONTIUM AS ADDITIVE FOR THE DIRECT SYNTHESIS OF DIMETHYLDICHLOROSILANE
FR2577930A1 (en) * 1985-02-22 1986-08-29 Rhone Poulenc Spec Chim PROCESS AND CATALYST WITH AN ALKALINE-EARTH METAL SELECTED AS ADDITIVE AMONG CALCIUM, MAGNESIUM AND BERYLLIUM FOR THE DIRECT SYNTHESIS OF DIMETHYLDICHLOROSILANE
EP0194214A1 (en) * 1985-02-22 1986-09-10 Rhone-Poulenc Chimie Process and catalyst containing calcium as an additive for the direct synthesis of dimethyldichlorosilane
EP0195728A1 (en) * 1985-02-22 1986-09-24 Rhone-Poulenc Chimie Process and catalyst containing barium and/or strontium as an additive for the direct synthesis of dimethyldichlorosilane

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