GB914154A - Improvements in or relating to the production of uranium-carbon alloys - Google Patents

Improvements in or relating to the production of uranium-carbon alloys

Info

Publication number
GB914154A
GB914154A GB30711/59A GB3071159A GB914154A GB 914154 A GB914154 A GB 914154A GB 30711/59 A GB30711/59 A GB 30711/59A GB 3071159 A GB3071159 A GB 3071159A GB 914154 A GB914154 A GB 914154A
Authority
GB
United Kingdom
Prior art keywords
uranium
mixture
iron
ufe2
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30711/59A
Inventor
Jack Williams
Michael Colin Regan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UK Atomic Energy Authority
Original Assignee
UK Atomic Energy Authority
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UK Atomic Energy Authority filed Critical UK Atomic Energy Authority
Priority to GB30711/59A priority Critical patent/GB914154A/en
Priority to US53635A priority patent/US3136629A/en
Priority to FR838027A priority patent/FR1271772A/en
Publication of GB914154A publication Critical patent/GB914154A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21CNUCLEAR REACTORS
    • G21C3/00Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
    • G21C3/42Selection of substances for use as reactor fuel
    • G21C3/58Solid reactor fuel Pellets made of fissile material
    • G21C3/62Ceramic fuel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/90Carbides
    • C01B32/914Carbides of single elements
    • C01B32/928Carbides of actinides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/51Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on compounds of actinides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0047Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
    • C22C32/0052Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0084Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ carbon or graphite as the main non-metallic constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C43/00Alloys containing radioactive materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/10Solid density
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin
    • Y02E30/30Nuclear fission reactors

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Plasma & Fusion (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Inorganic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

A dense uranium-carbon compound, which may also contain plutonium, is produced by cold-compacting and sintering a mixture of uranium and carbon powders (with or without plutonium) containing also iron in the form of UFe2 or U6Fe, the iron forming 1 to 10% by weight of the mixture. It is stated that, when using UFe2, maximum density is obtained when the carbon and uncombined uranium contents of the starting mixture are in stoichiometric proportions to form uranium monocarbide. Specifications 821,287, 825,041 and 914,153 are referred to.ALSO:A dense uranium-carbon alloy, which may also contain plutonium, is produced by cold-compacting and then sintering at not less than 800 DEG C. a mixture of uranium and carbon powders (and, if desired, plutonium powder) containing also iron in the form of an intermetallic compound of uranium and iron, the iron forming 1-10% by weight of the mixture. The compound may be UFe2 or U6Fe, use of the latter being limited to iron contents of less than 3.8%. Heating of the compact is preferably carried out rapidly as described in Specification 914,153. In examples described uranium powder of less than 300 mesh was mixed with ultrafine graphite and the mixture then mixed with UFe2. The resultant mixture was cold-compacted at 60 tons/sq. inch, then passed rapidly into a vacuum furnace at 1100 DEG C. The compacts were estimated to reach a maximum temperature of 1200-1450 DEG C. within a few minutes, and were then heated at 1100 DEG F. for two hours. Specifications 821,287 and 825,041 are referred to.
GB30711/59A 1959-09-08 1959-09-08 Improvements in or relating to the production of uranium-carbon alloys Expired GB914154A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB30711/59A GB914154A (en) 1959-09-08 1959-09-08 Improvements in or relating to the production of uranium-carbon alloys
US53635A US3136629A (en) 1959-09-08 1960-09-02 Production of uranium-carbon alloys
FR838027A FR1271772A (en) 1959-09-08 1960-09-07 Manufacturing process of dense uranium and carbon alloys

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB30711/59A GB914154A (en) 1959-09-08 1959-09-08 Improvements in or relating to the production of uranium-carbon alloys

Publications (1)

Publication Number Publication Date
GB914154A true GB914154A (en) 1962-12-28

Family

ID=10311941

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30711/59A Expired GB914154A (en) 1959-09-08 1959-09-08 Improvements in or relating to the production of uranium-carbon alloys

Country Status (2)

Country Link
US (1) US3136629A (en)
GB (1) GB914154A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE633880A (en) * 1962-06-20
US3347749A (en) * 1965-09-07 1967-10-17 Westinghouse Electric Corp Modified carbide fuels
US3398098A (en) * 1967-06-09 1968-08-20 Atomic Energy Commission Usa Preparation of pure dense hypostoichiometric uranium carbide

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2526805A (en) * 1944-08-12 1950-10-24 James H Carter Method of forming uranium carbon alloys
US2569225A (en) * 1947-03-26 1951-09-25 James H Carter Method of forming uranium monocarbide
US2807542A (en) * 1955-07-08 1957-09-24 Thomas W Frank Method of making high density sintered alloys

Also Published As

Publication number Publication date
US3136629A (en) 1964-06-09

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