GB701168A - Improvements in polyphosphate compositions - Google Patents
Improvements in polyphosphate compositionsInfo
- Publication number
- GB701168A GB701168A GB13612/51A GB1361251A GB701168A GB 701168 A GB701168 A GB 701168A GB 13612/51 A GB13612/51 A GB 13612/51A GB 1361251 A GB1361251 A GB 1361251A GB 701168 A GB701168 A GB 701168A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- compounds
- compositions
- salts
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3427—Organic compounds containing sulfur containing thiol, mercapto or sulfide groups, e.g. thioethers or mercaptales
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3481—Organic compounds containing sulfur containing sulfur in a heterocyclic ring, e.g. sultones or sulfolanes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Detergent compositions containing water-soluble polyphosphates are given an addition of a compound having in its molecule the structure <FORM:0701168/III/1> wherein X=O or S an Y=-NH2 or -SH, whereby the tendency of the compositions to tarnish metal articles is reduced. One valency of each of the two unattached carbon atoms may be utilized to form a double bond between these carbon atoms (i.e. the compounds may be thiazoles or oxazoles), or the unattached valencies may be linked to hydrogen atoms, carbonyloxygen, or alkyl or acyl radicals, or may form part of a condensed ring system, either saturated (as in 2-aminocyclohexyl oxazoline) or unsaturated (as in 2-mercapto benzothiazole). The condensed rings may bear substituents such as halogen atoms or amino, alkyl or aryl groups. A list of suitable compounds is given. Between 0.005 and 5 per cent., preferably 0.03 to 1 per cent., by weight of these compounds based on the weight of polyphosphate may be used. The 2-amino compounds may be used in the form of their salts with inorganic acids such as sulphuric, hydrochloric or phosphoric acid, or with organic acids such as acetic, formic or benzoic acid. The 2-mercapto compounds may be used in the form of their salts with metals, e.g. zinc, or with amines, e.g. hexamine, phenylbiguanide, tolylbiguanide or biphenylguanide. The water-soluble polyphosphates include those of the formulae A4 P2 O7, A5 P3 O10, A6 P4 O13 and (APO3)6, where A is an alkali metal. The detergents normally present in the compositions include alkyl aryl sulphonates, such as magnesium polypropylene benzene sulphonate, aliphatic sulphonic acids, acid sulphates of aliphatic alcohols of 10 - 18 carbon atoms, sulphonated castor oil, esters and ethers of isethionic acid, amides of taurine and N-alkyl taurines, long chain fatty esters and ethers of 1.2 dihydroxypropane-3-sulphonic acid, sulphates of mono glycerides and glycerol monoethers, polyethylene glycol ethers of alkyl phenols and alkyl thio phenols, polyethylene glycol esters of fatty acids, and polyethylene glycol ethers of fatty alcohols. The compositions may also contain other substances such as alkali metal and alkaline earth metal sulphates, chlorides, silicates, borates, carbonates, metaphosphates and orthophosphates, starch, polyethylene glycols, polyvinyl alcohols and salts of carboxy methyl cellulose. Specification 645,129 is referred to.ALSO:Water-soluble polyphosphate compositions for cleaning nickel and copper alloys, such as German silver, are given an addition of a compound having in its molecule the structure <FORM:0701168/II/1> wherein X=O or S and Y=-NH2 or -SH3, whereby the tendency of the compositions to tarnish the alloys is reduced. One valency of each of the two unattached carbon atoms may be utilized to form a double bond between these carbon atoms (i.e. the compounds may be thiazoles or oxazoles), or the unattached valencies may be linked to hydrogen atoms, carbonyl - oxygen, or alkyl or aryl radicals or may form part of a condensed ring system, either saturated (as in 2-aminocyclohexyl oxazoline) or unsaturated (as in 2-mercaptobenzthiazole). The condensed rings may carry substituents such as halogen atoms or amino, alkyl or aryl groups. A list of suitable compounds is given. The 2-amino compounds may be used in the form of their salts with inorganic acids such as sulphuric, hydrochloric or phosphoric acid, or with organic acids such as acetic, formic or benzoic acid. The 2-mercapto compounds may be used in the form of their salts with metals, e.g. zinc, or with amines. e.g. hexamine, phenylbiguanide, tolybiguanide or biphenylguanide. The water-soluble polyphosphates may be of the formulae A1P2O7, A5P3O10, A6P4O13 and (APO3)6, where A is an alkali metal. The inhibitor may be used in amounts of 0.005 to 5 per cent. by weight of the polyphosphates. Solutions containing 0.14 per cent. of the polyphosphate compositions should preferably have a pH of 7 to 10. The polyphosphate compositions may also contain detergents (see Group III), alkali metal and alkaline earth metal sulphate, chlorides, silicates, borates. carbonates, metaphosphates and orthophosphates, starch, polyethylene glycols, polyvinyl alcohols and salts of carboxymethyl cellulose. Specification 645,129, [Group III], is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US172776A US2861044A (en) | 1950-07-08 | 1950-07-08 | Polyphosphate composition containing tarnish inhibitor |
Publications (1)
Publication Number | Publication Date |
---|---|
GB701168A true GB701168A (en) | 1953-12-16 |
Family
ID=22629184
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB13612/51A Expired GB701168A (en) | 1950-07-08 | 1951-06-08 | Improvements in polyphosphate compositions |
Country Status (7)
Country | Link |
---|---|
US (1) | US2861044A (en) |
BE (1) | BE504343A (en) |
CH (2) | CH306236A (en) |
DE (1) | DE890252C (en) |
FR (1) | FR1039160A (en) |
GB (1) | GB701168A (en) |
NL (1) | NL77796C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2912385A (en) * | 1954-06-14 | 1959-11-10 | Colgate Palmolive Co | Liquid soap composition |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE972388C (en) * | 1953-03-07 | 1959-07-09 | Basf Ag | Corrosion inhibitor for metals |
GB772493A (en) * | 1954-04-21 | 1957-04-17 | Unilever Ltd | Compositions containing tarnish inhibitors |
DE1102520B (en) * | 1954-04-22 | 1961-03-16 | Basf Ag | Means for protecting metals against stress corrosion |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2575576A (en) * | 1951-11-20 | Alkali metal salt-organic sulfoxt | ||
GB309314A (en) * | 1928-04-14 | 1929-04-11 | Ici Ltd | Improvements in the processes for the pickling of metals |
US2160293A (en) * | 1936-12-05 | 1939-05-30 | Standard Oil Co | Lubricant |
US2238651A (en) * | 1937-05-21 | 1941-04-15 | Du Pont | Inhibition of corrosion |
US2327323A (en) * | 1940-07-13 | 1943-08-17 | Du Pont | Water-treating agent |
US2419805A (en) * | 1943-05-06 | 1947-04-29 | Wyandotte Chemicals Corp | Inhibiting alkali dissolution of glass |
US2618605A (en) * | 1949-02-04 | 1952-11-18 | Procter & Gamble | Detergent compositions containing metal discoloration inhibitors |
US2618603A (en) * | 1949-02-04 | 1952-11-18 | Procter & Gamble | Detergent compositions containing metal discoloration inhibitors |
-
0
- NL NL77796D patent/NL77796C/xx active
- BE BE504343D patent/BE504343A/xx unknown
-
1950
- 1950-07-08 US US172776A patent/US2861044A/en not_active Expired - Lifetime
-
1951
- 1951-06-08 GB GB13612/51A patent/GB701168A/en not_active Expired
- 1951-06-20 CH CH306236D patent/CH306236A/en unknown
- 1951-06-20 CH CH300867D patent/CH300867A/en unknown
- 1951-06-28 FR FR1039160D patent/FR1039160A/en not_active Expired
- 1951-07-05 DE DEL9489A patent/DE890252C/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2912385A (en) * | 1954-06-14 | 1959-11-10 | Colgate Palmolive Co | Liquid soap composition |
Also Published As
Publication number | Publication date |
---|---|
NL77796C (en) | |
CH306236A (en) | 1955-03-31 |
FR1039160A (en) | 1953-10-05 |
CH300867A (en) | 1954-08-31 |
DE890252C (en) | 1953-09-17 |
BE504343A (en) | |
US2861044A (en) | 1958-11-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1503344A (en) | Liquid detergent compositions | |
GB1496805A (en) | Dithionite composition | |
GB1398422A (en) | Sulphosuccinate derivatives as detergent builders | |
GB1084061A (en) | ||
PH11493A (en) | Laundry detergent compositions in emulsion/suspension for | |
GB1380390A (en) | Detergent compositions | |
GB850531A (en) | Improvements in and relating to laundering compositions | |
GB701168A (en) | Improvements in polyphosphate compositions | |
US3377290A (en) | Liquid or paste detergent preparations having sulfofatty acid salts as viscosity reducing agents | |
US2731420A (en) | Nitrogen-containing tarnish inhibitors in detergent compositions | |
GB1462239A (en) | Liquid aqueous cleaning compositions | |
NL178800C (en) | METHOD AND EQUIPMENT FOR THE GALVANOPLASTIC MANUFACTURE OF IRON. | |
US2861954A (en) | Polyphosphate compositions containing soap and 2-mercaptothiazoline | |
ES356635A1 (en) | Detergent Compositions and the Manufacture thereof | |
GB1014058A (en) | Washing composition | |
NL292622A (en) | ||
GB848306A (en) | Antibacterial detergent compositions | |
US3617207A (en) | Alkaline solutions containing certain alkylbenzene sulfonate wetting agents | |
ES392801A1 (en) | Procedure for the preparation of a washing agent. (Machine-translation by Google Translate, not legally binding) | |
GB935649A (en) | Sulfated polyoxyethylated carbinamines | |
GB818158A (en) | Improvements relating to detergent compositions | |
US3414520A (en) | Detergent composition | |
GB714348A (en) | Improvements relating to detergent compositions | |
ES359618A1 (en) | Detergent compositions | |
US2870092A (en) | Polyphosphate compositions containing tallow methyl tauride and 2-mercaptothiazoline |