GB692953A - Organo-mercury compounds - Google Patents
Organo-mercury compoundsInfo
- Publication number
- GB692953A GB692953A GB30033/50A GB3003350A GB692953A GB 692953 A GB692953 A GB 692953A GB 30033/50 A GB30033/50 A GB 30033/50A GB 3003350 A GB3003350 A GB 3003350A GB 692953 A GB692953 A GB 692953A
- Authority
- GB
- United Kingdom
- Prior art keywords
- prepared
- allyl
- general formula
- compounds
- adipic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 9
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 6
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 abstract 4
- 239000001361 adipic acid Substances 0.000 abstract 4
- 235000011037 adipic acid Nutrition 0.000 abstract 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 3
- AXEUBXNTRJZUKG-UHFFFAOYSA-N 1-prop-2-enylpyrrolidine-2,5-dione Chemical compound C=CCN1C(=O)CCC1=O AXEUBXNTRJZUKG-UHFFFAOYSA-N 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 2
- 150000001408 amides Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- BRMYZIKAHFEUFJ-UHFFFAOYSA-L mercury diacetate Chemical compound CC(=O)O[Hg]OC(C)=O BRMYZIKAHFEUFJ-UHFFFAOYSA-L 0.000 abstract 2
- 239000001384 succinic acid Substances 0.000 abstract 2
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000002798 polar solvent Substances 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 229940014800 succinic anhydride Drugs 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
The invention comprises organo-mercury compounds of the general formula <FORM:0692953/IV (b)/1> where n is an integer less than 5 and R represents hydrogen or the allyl group, and a process for preparing the above compounds by reacting a compound of the general formula <FORM:0692953/IV (b)/2> where R and n have the significance indicated above, with an equimolar proportion of mercuric salt in a polar solvent medium, e.g. water or alcohol. Mercuric acetate is given as an example of a mercuric salt. In the examples compounds of the above general formula are prepared, wherein R represents allyl and hydrogen and n is 2 and 4, using mercuric acetate as the mercuric salt. The Specification also states that the first products in the examples are of the general formula HOOC(CH2)nCONRCH2CHOH CH2HgOCOCH3, where R has the significance indicated above and n is 2 or 4, which are unstable and eliminate acetic acid to form the desired compounds prepared in the examples. The said desired compounds dissolve in aqueous caustic soda to form compounds of the general formula NaOOC(CH2)nCONRCH2CHOHCH2Hg OH, where R has the significance indicated above and n is 2 or 4. Sodium salt of succinic acid N-monoallyl amide is prepared by treating N-allyl-succinimide with sodium hydroxide. Adipic acid N-monoallyl amide is prepared by reacting adipic acid methyl mono-ester chloride with allyl amine and hydrolysing the resulting adipic acid methyl mono-ester N-allyl amide with methanolic caustic soda. Succinic acid N-(diallyl)-monoamide is prepared by a similar method. Adipic acid N-(diallyl)-monoamide is prepared by saponifying the corresponding mono-methyl ester. N-allyl-succinimide is prepared by heating succinic anhydride and allyl amine.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE308683X | 1949-12-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB692953A true GB692953A (en) | 1953-06-17 |
Family
ID=6121784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB30033/50A Expired GB692953A (en) | 1949-12-07 | 1950-12-07 | Organo-mercury compounds |
Country Status (2)
| Country | Link |
|---|---|
| CH (1) | CH308683A (en) |
| GB (1) | GB692953A (en) |
-
1950
- 1950-11-21 CH CH308683D patent/CH308683A/en unknown
- 1950-12-07 GB GB30033/50A patent/GB692953A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CH308683A (en) | 1955-07-31 |
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