GB690566A - Improvements in and relating to the production of regenerated keratin threads, fibres, filaments and the like - Google Patents
Improvements in and relating to the production of regenerated keratin threads, fibres, filaments and the likeInfo
- Publication number
- GB690566A GB690566A GB1675950A GB1675950A GB690566A GB 690566 A GB690566 A GB 690566A GB 1675950 A GB1675950 A GB 1675950A GB 1675950 A GB1675950 A GB 1675950A GB 690566 A GB690566 A GB 690566A
- Authority
- GB
- United Kingdom
- Prior art keywords
- keratin
- aqueous
- acid
- per cent
- wool
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F4/00—Monocomponent artificial filaments or the like of proteins; Manufacture thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Peptides Or Proteins (AREA)
Abstract
Regenerated keratin threads are produced by extruding an aqueous solution of keratin which has been pretreated with peracetic acid into an aquous coagulating bath, stretching the freshly extruded thread while it is still soluble in or swellable by water and then hardening it. The pretreated keratin may be dissolved in aqueous solutions of caustic soda, ammonium hydroxide or urea. The coagulating baths are preferably aqueous salt baths of pH 6.0-9.0, but may be acid; they are preferably used at 30-60 DEG C. The stretching should usually be at least 50 per cent and preferably 100-300 per cent. Stretching may be effected in air or in a coagulating bath free from hardening agents. Alternatively the threads may be stretch-spun. The hardening bath may be of the type usual for casein threads, e.g. aqueous formaldehyde alone or preferably with one or more metal salts such as sodium, magnesium or aluminium sulphate, calcium or zinc chloride, basic chromium sulphate or zirconyl sulphate. In an example degreased wool is agitated with an aqueous solution of peracetic acid, washed and squeezed free from acid, agitated with dilute aqueous ammonium hydroxide solution and precipitated by the addition of dilute sulphuric acid. The curd is filtered off, pressed and dissolved in concentrated ammonia, and the solution is extruded into a neutral aqueous solution of magnesium and sodium sulphates. The freshly extruded thread is stretched 200 per cent while wet with coagulating bath and hardened for 2 hours at 50 DEG C. in a bath containing formaldehyde, magnesium sulphate and sodium sulphate. The thread is then insolubilized by further treatment with an aqueous solution of formaldehyde, sodium sulphate and sulphuric acid, washed in water and dried. In the other example the pretreatment of the wool is effected by adding five portions of 100 volume hydrogen peroxide and five portions of acetic anhydride alternately at intervals to a stirred mixture of wool waste and 98 per cent formic acid, so that the peracetic acid is formed in situ in a number of steps. The pretreated wool is then further processed as in the first example. Specifications 502,710 and 549,642 are referred to.ALSO:Keratin for use in the production of artificial threads (see Group IV (a)) is treated with peracetic acid, which is preferably produced in situ in a number of steps by adding hydrogen peroxide and acetic anhydride step-wise to the keratin. Suitable solvents for the treated keratin are aqueous caustic soda, ammonium hydroxide and urea solutions. In one example degreased wool is agitated for 48 hours at 20 DEG C. with a 2 per cent aqueous solution of peracetic acid. In the other example, to a stirred mixture of wool waste and 98 per cent formic acid is added 100 vol. hydrogen peroxide and acetic anhydride alternately in five equal portions at half-hour intervals. After agitation for 18 hours water is added to precipitate a curd, which is separated and purified by dispersing it in aqueous ammonium hydroxide and then acidifying the mixture. The purified material is pressed and dissolved in 0.880 specific gravity ammonium hydroxide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1675950A GB690566A (en) | 1950-07-05 | 1950-07-05 | Improvements in and relating to the production of regenerated keratin threads, fibres, filaments and the like |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1675950A GB690566A (en) | 1950-07-05 | 1950-07-05 | Improvements in and relating to the production of regenerated keratin threads, fibres, filaments and the like |
Publications (1)
Publication Number | Publication Date |
---|---|
GB690566A true GB690566A (en) | 1953-04-22 |
Family
ID=10083123
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1675950A Expired GB690566A (en) | 1950-07-05 | 1950-07-05 | Improvements in and relating to the production of regenerated keratin threads, fibres, filaments and the like |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB690566A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11866519B2 (en) | 2018-09-18 | 2024-01-09 | Wool Research Organisation Of New Zealand Incorporated | Cellulose-containing materials |
-
1950
- 1950-07-05 GB GB1675950A patent/GB690566A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11866519B2 (en) | 2018-09-18 | 2024-01-09 | Wool Research Organisation Of New Zealand Incorporated | Cellulose-containing materials |
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